A small angle neutron scattering and Mössbauer spectrometry study of magnetic structures in nanocrystalline Ni3Fe

Results are reported from small angle neutron scattering and Mössbauer spectrometry measurements on nanocrystalline Ni3Fe. The nanocrystalline materials were prepared by mechanical attrition and studied in the as-milled state, after annealing at 265 °C to relieve internal stress, and after annealing 600 °C to prepare a control sample comprising large crystals. The small angle neutron scattering (SANS) measurements were performed for a range of applied magnetic fields. Small differences were found in how the different samples reached magnetic saturation. From the SANS data obtained at magnetic saturation, we found little difference in the nuclear scattering of the as-milled material and the material annealed at 265 °C. Reductions in nuclear scattering and magnetic scattering were observed for the control sample, and this was interpreted as grain growth. The material annealed at 265 °C also showed a reduction in magnetic SANS compared to the as-milled material. This was interpreted as an increase in magnetic moments of atoms at the grain boundaries after a low temperature annealing. Both Mössbauer spectroscopy and small angle neutron scattering showed an increase in the grain boundary magnetic moments after the 265 °C annealing (0.2 and 0.4µB/atom, respectively), even though there was little change in the grain boundary atomic density

Macau\u27s Trade with the Portuguese Speaking World

Macau has boomed over the last decade as its gaming industry has provided the massive Chinese economy with the only legal casino gambling services in the nation. But, recent Chinese political changes have resulted in a sharp downturn in Macau’s gambling revenues despite a major expansion of its gaming facilities. This may negatively impact efforts to promote a relationship between Macau and the Portuguese Speaking World. Portugal with its former Ultramar, to which Brazil has been added, is now termed “Lusophonia.” Initiated by China in Macau in October 2003, the efforts to promote a Lusophone trade and economic relationship with China through Macau have not resulted in any significant trade or tourist links between Macau and Lusophonia. Despite China’s trade with Brazil booming following China’s entry into the World Trade Organization in 2001, its Brazilian trade is routed either through China itself or Hong Kong, not through Macau. Macau’s significantly weak links to Lusophonia, which were predictable from international trade theory that included the Gravity Model and Ghemawat’s CAGE analytical model, were not enhanced during Macau’s 10 year boom from 2004 to 2014, and may be forced to take a back seat to the re-positioning of its gaming industry over the next several years

Vibrational entropy and microstructural effects on the thermodynamics of partially disordered and ordered Ni3V

Samples of Ni3V were prepared with two microstructures: (1) with equilibrium D022 order, and (2) with partial disorder (having a large D022 chemical order parameter, but without the tetragonality of the unit cell). For both materials, we measured the difference in their heat capacities from 60 to 325 K, inelastic neutron-scattering spectra at four values of Q at 11 and at 300 K, and Young's moduli and coefficients of thermal expansion. The difference in heat capacity at low temperatures was consistent with a harmonic model using the phonon density of states (DOS) curves determined from the inelastic neutron-scattering spectra. In contrast, at temperatures greater than 160 K the difference in heat capacity did not approach zero, as expected of harmonic behavior. The temperature dependence of the phonon DOS can be used to approximately account for the anharmonic contributions to the differential heat capacity. We also argue that some of the anharmonic behavior should originate with a microstructural contribution to the heat capacity involving anisotropic thermal contractions of the D022 structure. We estimate the difference in vibrational entropy between partially disordered and ordered Ni3V to be Spdis -Sord =(+0.038±0.015)kB /atom at 300 K

Torts

Tort

Torts

Tort

Developing a Core Outcome Set for Prognostic Research in Palliative Cancer Care: Protocol for a Mixed Methods Study

Background: Studies exploring the impact of receiving end-of-life prognoses in patients with advanced cancer use a variety of different measures to evaluate the outcomes, and thus report often conflicting findings. The standardization of outcomes reported in studies of prognostication in palliative cancer care could enable uniform assessment and reporting, as well as intertrial comparisons. A core outcome set promotes consistency in outcome selection and reporting among studies within a particular population. We aim to develop a set of core outcomes to be used to measure the impact of end-of-life prognostication in palliative cancer care. Objective: This protocol outlines the proposed methodology to develop a core outcome set for measuring the impact of end-of-life prognostication in palliative cancer care. Methods: We will adopt a mixed methods approach consisting of 3 phases using methodology recommended by the Core Outcome Measure in Effectiveness Trials (COMET) initiative. In phase I, we will conduct a systematic review to identify existing outcomes that prognostic studies have previously used, so as to inform the development of items and domains for the proposed core outcome set. Phase II will consist of semistructured interviews with patients with advanced cancer who are receiving palliative care, informal caregivers, and clinicians, to explore their perceptions and experiences of end-of-life prognostication. Outcomes identified in the interviews will be combined with those found in existing literature and taken forward to phase III, a Delphi survey, in which we will ask patients, informal caregivers, clinicians, and relevant researchers to rate these outcomes until consensus is achieved as to which are considered to be the most important for inclusion in the core outcome set. The resulting, prioritized outcomes will be discussed in a consensus meeting to agree and endorse the final core outcome set. Results: Ethical approval was received for this study in September 2022. As of July 2023, we have completed and published the systematic review (phase I) and have started recruitment for phase II. Data analysis for phase II has not yet started. We expect to complete the study by October 2024. Conclusions: This protocol presents the stepwise approach that will be taken to develop a core outcome set for measuring the impact of end-of-life prognostication in palliative cancer care. The final core outcome set has the potential for translation into clinical practice, allowing for consistent evaluation of emerging prognostic algorithms and improving communication of end-of-life prognostication. This study will also potentially facilitate the design of future clinical trials of the impact of end-of-life prognostication in palliative care that are acceptable to key stakeholders

The Supersymmetric Origin of Matter

The Minimal Supersymmetric extension of the Standard Model (MSSM) can provide the correct neutralino relic abundance and baryon number asymmetry of the universe. Both may be efficiently generated in the presence of CP violating phases, light charginos and neutralinos, and a light top squark. Due to the coannihilation of the neutralino with the light stop, we find a large region of parameter space in which the neutralino relic density is consistent with WMAP and SDSS data. We perform a detailed study of the additional constraints induced when CP violating phases, consistent with the ones required for baryogenesis, are included. We explore the possible tests of this scenario from present and future electron Electric Dipole Moment (EDM) measurements, direct neutralino detection experiments, collider searches and the b -> s gamma decay rate. We find that the EDM constraints are quite severe and that electron EDM experiments, together with stop searches at the Tevatron and Higgs searches at the LHC, will provide a definite test of our scenario of electroweak baryogenesis in the next few years.Comment: 30 pages, 14 figure