6,199 research outputs found
Some combinatorial identities appearing in the calculation of the cohomology of Siegel modular varieties
In the computation of the intersection cohomology of Shimura varieties, or of
the cohomology of equal rank locally symmetric spaces, combinatorial
identities involving averaged discrete series characters of real reductive
groups play a large technical role. These identities can become very
complicated and are not always well-understood (see for example the appendix of
[8]). We propose a geometric approach to these identities in the case of Siegel
modular varieties using the combinatorial properties of the Coxeter complex of
the symmetric group. Apart from some introductory remarks about the origin of
the identities, our paper is entirely combinatorial and does not require any
knowledge of Shimura varieties or of representation theory.Comment: 17 pages, 1 figure; to appear in Algebraic Combinatoric
Modelling the kinetics of transesterification reaction of sunflower oil with ethanol in microreactors
Transesterification reaction of vegetable oil with ethanol leads to ethyl esters, used to date for applications principally in food and cosmetic industry. To open the application field to biofuels (to substitute current fuels resulting from fossil resources), the process efficiency has to be developed to be economically profitable. In this work, the sunflower oil ethanolysis was performed in a micro-scaled continuous device, inducing better control for heat and mass transfer in comparison with batch processes. Moreover, this device ensures kinetic data acquisition at the first seconds of the reaction, which was not feasible in a conventional batch process. These data were used to model occurring phenomena and to determine kinetic constants and mass transfer coefficients. A single set of these parameters is able to represent the evolution of the reaction media composition function of time for five ethanol to oil molar ratios (6.0, 9.0, 16.2, 22.7 and 45.4). The model was validated in reaction and diffusion mode. Finally, it was subsequently used to simulate reactions with other operational conditions and to propose other process implementation
Sleptons without Hadrons
Multilepton searches for electroweakino and slepton pair production at hadron
colliders remain some of the best means to test weak-scale supersymmetry.
Searches at the CERN Large Hadron Collider, however, are limited by large
diboson and top quark pair backgrounds, despite the application of traditional,
central jet vetoes. In this context, we report the impact of introducing
dynamic jet vetoes in searches for colorless superpartners. As a representative
scenario, we consider the Drell-Yan production of a pair of right-handed smuons
decaying into a dimuon system accompanied with missing transverse energy. As an
exploratory step, we consider several global and local measures of the leptonic
and hadronic activity to construct the veto. In most all cases, we find that
employing a dynamic jet veto improves the sensitivity, independently of the
integrated luminosity. The inclusion of non-perturbative multiple particle
interactions and next-to-leading order jet merging does not alter this picture.
Directions for further improvements are discussed.Comment: 18 pages; 7 figures; additional discussions added; journal version;
results unchange
Alien Registration- Richard, Sophie (Bangor, Penobscot County)
https://digitalmaine.com/alien_docs/11261/thumbnail.jp
Linear difference equations, frieze patterns and combinatorial Gale transform
We study the space of linear difference equations with periodic coefficients
and (anti)periodic solutions. We show that this space is isomorphic to the
space of tame frieze patterns and closely related to the moduli space of
configurations of points in the projective space. We define the notion of
combinatorial Gale transform which is a duality between periodic difference
equations of different orders. We describe periodic rational maps generalizing
the classical Gauss map
On-line monitoring of the transesterification reaction carried out in microreactors using near infrared spectroscopy
Biodiesel can be produced from vegetable oils, animal fats, and waste cooking oils by transesterification with ethanol (also called ethanolysis) in order to substitute fossil fuels. In this work, the batch ethanolysis of high oleic sunflower oil was transferred into a continuous microstructured device, which induces a better control of heat and mass transfers. Various parameters were studied, notably the initial ethanol to oil molar ratio. An innovative method using NIR spectroscopy was also developed to on-line monitor the transesterification reaction of high oleic sunflower oil with ethanol in microreactors (circular PFA tube 1/1600 OD, 0.0200 ID). The reactions were monitored directly in the microreactors through sequential scans of the reaction medium by the means of an adequate probe. The asset of the method is that no sample collection or preparation is necessary. Partial Least Squares regression was used to develop calibration and prediction models between NIR spectral data and analytical data obtained by a reference method (gas chromatography with flame ionization detection, GC–FID). This method is fast, safe, reliable, nondestructive and inexpensive contrary to conventional procedures, such as gas chromatography and high
performance liquid chromatography generally used to determine the composition of crude transesterification medium
Chronic dietary intake of enniatin B in broiler chickens has low impact on intestinal morphometry and hepatic histology, and shows limited transfer to liver tissue
The Fusarium mycotoxin enniatin B (ENN B) is a so-called emerging mycotoxin frequently contaminating poultry feed. To investigate the impact of chronic ENN B exposure on animal health, broiler chickens were fed either a diet naturally contaminated with ENN B (2352 mu g/kg) or a control diet (135 mu g/kg) for 2, 7, 14, or 21 days. ENN B concentrations were determined in plasma and liver using a validated ultra-high performance liquid chromatographytandem mass spectrometry UHPLC-MS/MS method. Liver was evaluated histologically, and the villus length and crypt depth of the duodenum, jejunum, and ileum were measured. Histopathology of the livers did not reveal major abnormalities. Feeding an ENN B-contaminated diet could possibly inhibit the proliferation of enterocytes in the duodenal crypts, but did not affect villus length, crypt depth, or villus length-crypt depth ratio of the jejunum and ileum. ENN B levels in plasma and liver were significantly higher in the ENN B-fed group and ranged between <25-264 pg/mL and <0.05-0.85 ng/g, respectively. ENN B carry-over rates from feed to liver tissue were 0.005-0.014% and 0.034-0.109% in the ENN B and control group, respectively. Carry-over rates were low and indicated a limited contribution of poultry tissue-derived products to the total dietary ENN B intake for humans. The above results support the opinion of the European Food Safety Authority stating that adverse health effects from ENN B in broiler chickens are unlikely
On-line monitoring of the transesterification reaction between triglycerides and ethanol using near infrared spectroscopy combined with gas chromatography
Many analytical procedures have been developed to determine the composition of reaction mixtures during transesterification of vegetable oils with alcohols. However, despite their accuracy, these methods are time consuming and cannot be easily used for on-line monitoring. In this work, a fast analytical method was developed to on-line monitor the transesterification reaction of high oleic sunflower oil with ethanol using Near InfraRed spectroscopy and a multivariate approach. The reactions were monitored through sequential scans of the reaction medium with a probe in a one-liter batch reactor without collecting and preparing samples. To calibrate the NIR analytical method, gas chromatography-flame ionization detection was used as a reference method. The method was validated by studying the kinetics of the EtONa-catalyzed transesterification reaction. Activation energy (51.0 kJ/mol) was also determined by considering a pseudo second order kinetics model
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