Multiproxy assessment of the western equatorial Pacific hydrography during the last 30 kyr

Sea surface temperature (SST) and salinity of the Western Pacific Warm Pool (WPWP) reflect global climate effects such as the El Niño–Southern Oscillation phenomenon. However, reconstructions of past changes in the WPWP from the geologic record vary depending on the specific proxy record used. Here we develop a multiproxy record of the last deglaciation from a radiocarbon-dated sediment core (MD97-2138) retrieved in the heart of the WPWP. SST reconstructions for the past 30,000 years based on planktonic foraminiferal Mg/Ca (Globigerinoides ruber and Globigerinoides sacculifer), alkenone unsaturation index, and foraminiferal transfer functions differ notably. Mg/Ca-based SST estimates from the surface dwelling species G. ruber in MD97-2138 indicate a larger surface cooling (3° ± 0.6°C) during the Last Glacial Maximum (LGM) than inferred from Mg/Ca ratios in G. sacculifer (2.3° ± 0.7°C), statistical transfer functions based on planktonic foraminiferal species assemblages, and Uk₃₇ 0 (1°–2°C). These estimates are consistent with estimates from other WPWP cores, thereby suggesting that the discrepancy is due to proxy compatibility rather than differences in cores qualitity. Postdepositional dissolution above the lysocline might have altered the Mg/Ca-based temperature estimates in our site, but this effect is insufficient to resolve discrepancies between Mg/Ca in G. ruber and the other proxies. We suggest that the lower estimates obtained from Mg/Ca in G. sacculifer, faunal transfer functions, and Uk₃₇ 0 might reflect subsurface temperature changes rather than strict surface estimates. Accounting for potential artefacts, including dissolution and bioturbation, we suggest that the glacial WPWP SST was about 2.5° ± 0.7°C cooler than during the Holocene, whereas the subsurface/upper thermocline temperature change was only about 1.8° ± 0.7°C. Interpreting variations in δ¹⁸OSW in terms of salinity changes suggests a possibly slight decrease in surface salinity at the site of MD97-2138 during the LGM. Though LGM freshening in MD97-2138 is not robust to postdeposition dissolution effects, this inferred freshening appears to be a general feature of the western equatorial Pacific

North Atlantic Midlatitude Surface-Circulation Changes Through the Plio-Pleistocene Intensification of Northern Hemisphere Glaciation

The North Atlantic Current (NAC) transports warm salty water to high northern latitudes, with important repercussions for ocean circulation and global climate. A southward displacement of the NAC and Subarctic Front, which separate subpolar and subtropical water masses, is widely suggested for the Last Glacial Maximum (LGM) and may have acted as a positive feedback in glacial expansion at this time. However, the role of the NAC during the intensification of Northern Hemisphere glaciation (iNHG) at ~3.5 to 2.5 Ma is less clear. Here we present new records from Integrated Ocean Drilling Program Site U1313 (41°N) spanning ~2.8–2.4 Ma to trace the influence of Subarctic Front waters above this mid‐latitude site. We reconstruct surface and permanent pycnocline temperatures and seawater δ18O using paired Mg/Ca‐δ18O measurements on the planktic foraminifers Globigerinoides ruber and Globorotalia crassaformis and determine abundances of the subpolar foraminifer Neogloboquadrina atlantica. We find that the first significant glacial incursions of Subarctic Front surface waters above Site U1313 did not occur until ~2.6 Ma. At no time during our study interval was (sub)surface reorganization in the midlatitude North Atlantic analogous to the LGM. Our findings suggest that LGM‐like processes sensu stricto cannot be invoked to explain interglacial‐glacial cycle amplification during iNHG. They also imply that increased glacial productivity at Site U1313 during iNHG was not only driven by southward deflections of the Subarctic Front. We suggest that nutrient injection from cold‐core eddies and enhanced glacial dust delivery may have played additional roles in increasing export productivity in the midlatitude North Atlantic from 2.7 Ma.t. Funding for this research was provided by IODP France (C. T. B.) and the German Research Foundation (DFG) (grant OF 2544/2 to O. F.). I. B. is grateful to the UK IODP for financial support for shipboard and post-cruise participation in IODP Exp. 306. C. T. B., K. T., T. D. G., L. V., C. S., and M. E. acknowledge OSU Pythéas. M. M. R. acknowledges support by the USGS Land Change Science Program

Improving memory effect correction to achieve high precision analysis of δ 17 O, δ 18 O δ 2 H, 17 O‐excess and d‐excess in water using cavity ring‐down laser spectroscopy

International audienceRationaleThe precision obtained in routine isotope analysis of water (δ17O, δ18O, δ2H, 17O‐excess and d‐excess values) by Cavity Ring‐Down Spectroscopy is usually below the instrument specifications provided by the manufacturer. This study aimed at reducing this discrepancy, with particular attention paid to mitigating the memory effect (ME).MethodsWe used a Picarro L2140i analyzer coupled with a high‐precision A0211 vaporizer and an A0325 autosampler. The magnitude and duration of the ME were estimated using 24 series of 50 successive injections of samples with contrasting compositions. Four memory correction methods were compared, and the instrument performance was evaluated over a 17‐month period of routine analysis, using two different run architectures.ResultsThe ME remains detectable after the 30th injection, implying that common corrections procedures only based on the last preceding sample need to be revised. We developed a new ME correction based on the composition of several successive samples, and designed a run architecture to minimize the magnitude of the ME. The standard deviation obtained from routine measurement of a QA water over a 7 months‐period was 0.015‰ for δ17O, 0.023‰ for δ18O, 0.078‰ for δ2H, 0.006‰ for 17O‐excess and 0.173‰ for d‐excess. In addition, we provided the first δ17O and 17O‐excess values for the GRESP certified reference material.ConclusionsThis study demonstrates the long‐term persistence of the ME, which is often overlooked in routine analysis of natural samples. As already evidenced when measuring labelled water, it calls for consideration of the compositions of several previous samples to obtain an appropriate correction, a prerequisite to achieve high precision data

Seasonal evolution of the isotopic composition of atmospheric water vapour above a tropical lake: Deuterium excess and implication for water recycling

We present an analysis of the rainfall-evaporation-atmospheric moisture cycle in a semi-arid tropical zone (southwestern Madagascar) to quantify the recycling and mixing processes that occur above an endorheic lake system (Lake Ihotry) during an annual cycle. The study combines an isotope mass balance with a detailed field investigation of the lake system and a previously established daily time-step lake water balance model. The mass balance and Craig-Gordon equations are used to calculate the isotopic composition of the evaporative flux from the lake surface (δE) and to derive a daily time series of the ambient atmospheric water vapour composition above the lake (δAL) during a 8-month dry season. Calculated δAL results from a mixing between regional moisture (δAR) and locally evaporated water (δE), the latter representing 50% of δAL at the end of the dry season. The contribution of recycled moisture to on-lake precipitation during the wet season is estimated to ⩾16%. We show that, as expected, the deuterium excess is high in recycled precipitation and low in evaporated precipitation, but also that the recycled moisture in an endorheic system may have a low deuterium excess resulting from the low deuterium excess in regional precipitation. In case of a long evaporative season, the atmospheric moisture is not in isotopic equilibrium with the annual composition of precipitation because of the contribution of the recycled vapour to the local atmospheric pool. Our approach demonstrates the importance of water recycling on the atmospheric moisture cycle and precipitation in a tropical semi-arid system, and can be applied to other natural systems, enlarging the potential range of investigation of the atmospheric vapour cycle and rainfall sources in tropical lands. It may also represent a valuable complement to direct water vapour sampling, in yielding the long-term evolution of the atmospheric vapour composition with spatially averaged values and smoothed temporal variations

Glacial/interglacial sea surface temperature changes in the Southwest Pacific ocean over the past 360 ka

International audienceThe phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal delta O-18, we determined the phase relationship between local sea surface temperature (SST) and global seawater delta O-18 changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater delta O-18 change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO2 rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of C-14-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation. (C) 2008 Elsevier Ltd. All rights reserved

A Science Festival for Pupils in Environmental Sciences: the Example of “La Fête de la Science de l’Arbois” in Aix en Provence

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A Science Festival for Pupils in Environmental Sciences: the Example of “La Fête de la Science de l’Arbois” in Aix en Provence

International audienc

Sea surface temperature and productivity records for the past 240 kyr in the Arabian Sea

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Identification of the parent bodies of micrometeorites with high-precision oxygen isotope ratios

Oxygen isotopic compositions allow identification of potential parent bodies of extraterrestrial materials. We measured oxygen isotope ratios of 33 large (diameter N500 μm) silicate melted micrometeorites (cosmic spherules) from Antarctica, using IR-laser fluorination coupled with mass spectrometry. It is the first time that this high-precision method is used on individual micrometeorites. The selected micrometeorites are representative of the influx of extraterrestrial materials to the Earth. Our results show that most micrometeorites are related to carbonaceous chondrites, which is consistent with previous studies. However, 20–50% of them seem to be related to CO/CV carbonaceous chondrites, whereas CM/CR carbonaceous chondrites were thought to be the main source for micrometeorites. Furthermore, ~30% of measured samples have oxygen isotope ratios lying above the terrestrial fractionation line, which relates them to ordinary chondrites or other, as yet, unsampled parent bodies