419 research outputs found
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Investigation of the Si(111) Surface in UHV: Oxidation and the Effect of Surface Phosphorus
We have studied the initial stages of oxidation, the segregation of phosphorus, and the effect of phosphorus on oxidation of the Si(111) 7 x 7 surface using optical second-harmonic generation. We have also observed a (..sqrt..3 x ..sqrt..3)R30/sup 0/ LEED pattern for P on Si(111)
Delocalization Transition of a Rough Adsorption-Reaction Interface
We introduce a new kinetic interface model suitable for simulating
adsorption-reaction processes which take place preferentially at surface
defects such as steps and vacancies. As the average interface velocity is taken
to zero, the self- affine interface with Kardar-Parisi-Zhang like scaling
behaviour undergoes a delocalization transition with critical exponents that
fall into a novel universality class. As the critical point is approached, the
interface becomes a multi-valued, multiply connected self-similar fractal set.
The scaling behaviour and critical exponents of the relevant correlation
functions are determined from Monte Carlo simulations and scaling arguments.Comment: 4 pages with 6 figures, new comment
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Silver ion mediated shape control of platinum nanoparticles: Removal of silver by selective etching leads to increased catalytic activity
A procedure has been developed for the selective etching of Ag from Pt nanoparticles of well-defined shape, resulting in the formation of elementally-pure Pt cubes, cuboctahedra, or octahedra, with a largest vertex-to-vertex distance of {approx}9.5 nm from Ag-modified Pt nanoparticles. A nitric acid etching process was applied Pt nanoparticles supported on mesoporous silica, as well as nanoparticles dispersed in aqueous solution. The characterization of the silica-supported particles by XRD, TEM, and N{sub 2} adsorption measurements demonstrated that the structure of the nanoparticles and the mesoporous support remained conserved during etching in concentrated nitric acid. Both elemental analysis and ethylene hydrogenation indicated etching of Ag is only effective when [HNO{sub 3}] {ge} 7 M; below this concentration, the removal of Ag is only {approx}10%. Ethylene hydrogenation activity increased by four orders of magnitude after the etching of Pt octahedra that contained the highest fraction of silver. High-resolution transmission electron microscopy of the unsupported particles after etching demonstrated that etching does not alter the surface structure of the Pt nanoparticles. High [HNO{sub 3}] led to the decomposition of the capping agent, polyvinylpyrollidone (PVP); infrared spectroscopy confirmed that many decomposition products were present on the surface during etching, including carbon monoxide
Distribution of reaction products in the koh initiated low temperature steam gasification of graphite
Insights into the function of silver as an oxidation catalyst by ab initio, atomistic thermodynamics
To help understand the high activity of silver as an oxidation catalyst,
e.g., for the oxidation of ethylene to epoxide and the dehydrogenation of
methanol to formaldehyde, the interaction and stability of oxygen species at
the Ag(111) surface has been studied for a wide range of coverages. Through
calculation of the free energy, as obtained from density-functional theory and
taking into account the temperature and pressure via the oxygen chemical
potential, we obtain the phase diagram of O/Ag(111). Our results reveal that a
thin surface-oxide structure is most stable for the temperature and pressure
range of ethylene epoxidation and we propose it (and possibly other similar
structures) contains the species actuating the catalysis. For higher
temperatures, low coverages of chemisorbed oxygen are most stable, which could
also play a role in oxidation reactions. For temperatures greater than about
775 K there are no stable oxygen species, except for the possibility of O atoms
adsorbed at under-coordinated surface sites Our calculations rule out thicker
oxide-like structures, as well as bulk dissolved oxygen and molecular
ozone-like species, as playing a role in the oxidation reactions.Comment: 15 pages including 9 figures, Related publications can be found at
http://www.fhi-berlin.mpg.de/th/paper.htm
The application of high resolution electron energy loss spectroscopy to the study of model supported metal catalysts
Scope for new applications for gold arising from the electrocatalytic behaviour of its metastable surface states
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THE CATALYTIC HYDROGENATION OF CARBON MONOXIDE. THE FORMATION OF C, HYDROCARBONS
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