EFECTO DE LOS IONES INORGÁNICOS SOBRE LA DEGRADACIÓN DE PLAGUICIDAS POR UN PROCESO FOTO-FENTON

Estudiar el efecto de varios iones inorgánicos en aguas contaminadas con plaguicidas mediante proceso foto-Fenton.Soler Escoda, JM. (2008). EFECTO DE LOS IONES INORGÁNICOS SOBRE LA DEGRADACIÓN DE PLAGUICIDAS POR UN PROCESO FOTO-FENTON. http://hdl.handle.net/10251/13048Archivo delegad

Chloride anion effect on the advanced oxidation processes of methidathion and dimethoate: role of Cl2(center dot-) radical

NOTICE: this is the author’s version of a work that was accepted for publication in Water Research. Changes resulting from the publishing process, such as peer review, editing, corrections,structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in WATER RESEARCH [VOL 47, ISSUE 1, (January 2013)] DOI 10.1016/j.watres.2012.10.018¨ IWA Publishing : Set statement to accompany deposit, "©IWA Publishing 2013. The definitive peer-reviewed and edited version of this article is published in Water Research 47 1 351-362 2013 DOI 10.1016/j.watres.2012.10.018 and is available at www.iwapublishing.com."The reaction of phosphor-containing pesticides such as methidathion (MT) and dimethoate (DM) with dichloride radical anions (Cl-2(center dot-)) was investigated. The second order rate constants (1.3 +/- 0.4) x 10(8) and (1.1 0.4) x 10(8) M-1 s(-1) were determined for the reaction of Cl-2(center dot-) with MT and DM, respectively. A reaction mechanism involving an initial charge transfer from the sulfide groups of the insecticides to Cl-2(center dot-) is proposed and supported by the identified transient intermediates and reaction products. The formation of chlorinated byproducts was determined. The unexpected consequences of an efficient Cl-2(center dot-) activity towards MT and DM on the degradation capacity by Advanced Oxidation Procedures applied to polluted waters containing the insecticides and Cl- anions is discussed. (C) 2012 Elsevier Ltd. All rights reserved.This research was financially supported by Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Agencia Nacional de Promocion Cientifica y Tecnologica (Argentina, project PICT 2007 number 00308), and Agencia Espanola de Cooperacion Internacional (project A/8199/07). MCG, JAR and PC are research members of Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Argentina. D.O.M. is a research member of CICPBA, Argentina. This research was supported by the grant PIP 112-200801-00356 from CONICET.Caregnato, P.; Rosso, JA.; Soler Escoda, JM.; Arques Sanz, A.; Martire, DO.; González, MC. (2013). Chloride anion effect on the advanced oxidation processes of methidathion and dimethoate: role of Cl2(center dot-) radical. Water Research. 47(1):351-362. https://doi.org/10.1016/j.watres.2012.10.018S35136247

Higher COVID-19 pneumonia risk associated with anti-IFN-α than with anti-IFN-ω auto-Abs in children

We found that 19 (10.4%) of 183 unvaccinated children hospitalized for COVID-19 pneumonia had autoantibodies (auto-Abs) neutralizing type I IFNs (IFN-alpha 2 in 10 patients: IFN-alpha 2 only in three, IFN-alpha 2 plus IFN-omega in five, and IFN-alpha 2, IFN-omega plus IFN-beta in two; IFN-omega only in nine patients). Seven children (3.8%) had Abs neutralizing at least 10 ng/ml of one IFN, whereas the other 12 (6.6%) had Abs neutralizing only 100 pg/ml. The auto-Abs neutralized both unglycosylated and glycosylated IFNs. We also detected auto-Abs neutralizing 100 pg/ml IFN-alpha 2 in 4 of 2,267 uninfected children (0.2%) and auto-Abs neutralizing IFN-omega in 45 children (2%). The odds ratios (ORs) for life-threatening COVID-19 pneumonia were, therefore, higher for auto-Abs neutralizing IFN-alpha 2 only (OR [95% CI] = 67.6 [5.7-9,196.6]) than for auto-Abs neutralizing IFN-. only (OR [95% CI] = 2.6 [1.2-5.3]). ORs were also higher for auto-Abs neutralizing high concentrations (OR [95% CI] = 12.9 [4.6-35.9]) than for those neutralizing low concentrations (OR [95% CI] = 5.5 [3.1-9.6]) of IFN-omega and/or IFN-alpha 2

Estudio técnico del proceso de diseño y fabricación de un cangilón por medio de inyección

Soler Escoda, JM. (2006). Estudio técnico del proceso de diseño y fabricación de un cangilón por medio de inyección. http://hdl.handle.net/10251/32098.Archivo delegad

Estudio de la procesabilidad del ABS en reciclados sucesivos

Soler Escoda, JM. (2007). Estudio de la procesabilidad del ABS en reciclados sucesivos. http://hdl.handle.net/10251/32063.Archivo delegad

Effect of organic species on the solar detoxification of water polluted with pesticides

The effect of organic species on a solar-driven photo-Fenton treatment of a mixture of pesticides (methyl-oxydemethon, methidathion, carbaryl and dimethoate) has been studied in this paper. Triethoxyisododecyl alcohol, acetophenone and ethylenediaminetetraacetic acid (EDTA) have been used as examples of surfactants, solvents and complexing agents, respectively. An inhibitory effect on mineralization as well as on the elimination of the pesticides was observed in the case of the aliphatic surfactants, most probably due to the competition between the pesticides and the added organic matter for reaction with the relatively unselective hydroxyl radical. A methodology combining chemical analyses and bioassays was tested in order to explore the applicability of coupling a photo-Fenton process with a biological treatment in the presence of the surfactant. Despite the complexity of the mixture under study, a reliable monitoring of the process was accomplished; the biocompatibility of the mixture was enhanced and the optimal irradiation intensity was achieved just after complete removal of the pesticides. © 2011 Elsevier B.V.We want to acknowledge the financial support of Spanish Ministerio de Ciencia y Tecnologia (Project CTQ2009-13459-C05-03), Generalitat Valenciana (Project GVPRE/2008/369), and Universidad Politecnica de Valencia (PAID 003-581).Soler Escoda, JM.; Santos-Juanes Jordá, L.; Miró Martínez, P.; Vicente Candela, R.; Arqués Sanz, A.; Amat Payá, AM. (2011). Effect of organic species on the solar detoxification of water polluted with pesticides. Journal of Hazardous Materials. 188(1-3):181-187. doi:10.1016/j.jhazmat.2011.01.089S1811871881-