1,610 research outputs found
The Potential Applications of Nanoporous Materials for the Adsorption, Separation, and Catalytic Conversion of Carbon Dioxide
Sustainable CO2 adsorbents prepared by coating chitosan onto mesoporous silicas for large-scale carbon capture technology
In this article, we report a new sustainable synthesis procedure for manufacturing chitosan/silica CO2 adsorbents. Chitosan is a naturally abundant material and contains amine functionality, which is essential for selective CO2 adsorptions. It is, therefore, ideally suited for manufacturing CO2 adsorbents on a large scale. By coating chitosan onto high-surface-area mesoporous silica supports, including commercial fumed silica (an economical and accessible reagent) and synthetic SBA-15 and MCF silicas, we have prepared a new family of CO2 adsorbents, which have been fully characterised with nitrogen adsorption isotherms, thermogravimetric analysis/differential scanning calorimetry, TEM, FTIR spectroscopy and Raman spectroscopy. These adsorbents have achieved a significant CO2 adsorption capacity of up to 0.98 mmol g−1 at ambient conditions (P=1 atm and T=25 °C). The materials can also be fully regenerated/recycled on demand at temperatures as low as 75 °C with a >85 % retention of the adsorption capacity after 4 cycles, which makes them promising candidates for advanced CO2 capture, storage and utilisation technology
Self-similar impulsive capillary waves on a ligament
We study the short-time dynamics of a liquid ligament, held between two solid
cylinders, when one is impulsively accelerated along its axis. A set of
one-dimensional equations in the slender-slope approximation is used to
describe the dynamics, including surface tension and viscous effects. An exact
self-similar solution to the linearized equations is successfully compared to
experiments made with millimetric ligaments. Another non-linear self-similar
solution of the full set of equations is found numerically. Both the linear and
non-linear solutions show that the axial depth at which the liquid is affected
by the motion of the cylinder scales like . The non-linear solution
presents the peculiar feature that there exists a maximum driving velocity
above which the solution disappears, a phenomenon probably related to
the de-pinning of the contact line observed in experiments for large pulling
velocities
Dynamical frictional phenomena in an incommensurate two-chain model
Dynamical frictional phenomena are studied theoretically in a two-chain model
with incommensurate structure. A perturbation theory with respect to the
interchain interaction reveals the contributions from phonons excited in each
chain to the kinetic frictional force. The validity of the theory is verified
in the case of weak interaction by comparing with numerical simulation. The
velocity and the interchain interaction dependences of the lattice structure
are also investigated. It is shown that peculiar breaking of analyticity states
appear, which is characteristic to the two-chain model. The range of the
parameters in which the two-chain model is reduced to the Frenkel-Kontorova
model is also discussed.Comment: RevTex, 9 pages, 7 PostScript figures, to appear in Phys. Rev.
Cognitive demands of face monitoring: Evidence for visuospatial overload
Young children perform difficult communication tasks better face to face than when they cannot see one another (e.g., Doherty-Sneddon & Kent, 1996). However, in recent studies, it was found that children aged 6 and 10 years, describing abstract shapes, showed evidence of face-to-face interference rather than facilitation. For some communication tasks, access to visual signals (such as facial expression and eye gaze) may hinder rather than help children’s communication. In new research we have pursued this interference effect. Five studies are described with adults and 10- and 6-year-old participants. It was found that looking at a face interfered with children’s abilities to listen to descriptions of abstract shapes. Children also performed visuospatial memory tasks worse when they looked at someone’s face prior to responding than when they looked at a visuospatial pattern or at the floor. It was concluded that performance on certain tasks was hindered by monitoring another person’s face. It is suggested that processing of visual communication signals shares certain processing resources with the processing of other visuospatial information
The catalytic Mitsunobu reaction: a critical analysis of the current state-of-the-art
The Mitsunobu reaction is widely regarded as the pre-eminent method for performing nucleophilic substitutions of alcohols with inversion of configuration. However, its applicability to large-scale synthesis is undermined by the fact that alcohol activation occurs at the expense of two stoichiometric reagents – a phosphine and an azodicarboxylate. The ideal Mitsunobu reaction would be sub-stoichiometric in the phosphine and azodicarboxylate species and employ innocuous terminal oxidants and reductants to achieve recycling. This Review article provides a summary and analysis of recent advances towards the development of such catalytic Mitsunobu reactions
Results from the third Scottish National Prevalence Survey: is a population health approach now needed to prevent healthcare-associated infections?
Summary Background Healthcare associated infections (HAI) are a major public health concern and a significant cause of morbidity and mortality. A robust and current evidence base that is specific to local, national and Europe-wide settings is necessary to inform the development of strategies to reduce HAI and contain antimicrobial resistance (AMR). Aim To measure the prevalence of HAI and antimicrobial prescribing and identify key priority areas for interventions to reduce the burden of infection. Methods A national rolling PPS in National Health Service (NHS) acute, NHS non-acute, NHS paediatric and independent hospitals was carried out between September and November 2016 using the European Centre for Disease Prevention and Control protocol designed for the European PPS. Findings The prevalence of HAI was 4.6%, 2.7% and 3.2% in acute adults, paediatric and non-acute patient groups, respectively. The most common HAI types reported in adult patients were urinary tract infection and pneumonia. The prevalence of antimicrobial prescribing was 35.7%, 29.3% and 13.8% in acute adults, paediatric and non-acute patient groups, respectively. Respiratory, skin and soft tissue, gastrointestinal and urinary tract infections were the most common infections being treated at the time of survey. Conclusion HAI continues to be a public health concern in Scotland. UTI and pneumonia continue to place a significant burden on patients and on healthcare delivery, including those that develop in the community and require hospital admission. A broader population health approach which focuses on reducing the risk of infection upstream would reduce these infections in both community and hospital settings
Selfdual 2-form formulation of gravity and classification of energy-momentum tensors
It is shown how the different irreducibility classes of the energy-momentum
tensor allow for a Lagrangian formulation of the gravity-matter system using a
selfdual 2-form as a basic variable. It is pointed out what kind of
difficulties arise when attempting to construct a pure spin-connection
formulation of the gravity-matter system. Ambiguities in the formulation
especially concerning the need for constraints are clarified.Comment: title changed, extended versio
Transversely Driven Charge Density Waves and Striped Phases of High-T Superconductors: The Current Effect Transistor
We show that a normal (single particle) current density {\em
transverse} to the ordering wavevector of a charge density
wave (CDW) has dramatic effects both above and {\em below} the CDW depinning
transition. It exponentially (in ) enhances CDW correlations, and
exponentially suppresses the longitudinal depinning field. The intermediate
longitudinal I-V relation also changes, acquiring a {\em linear} regime. We
propose a novel ``current effect transistor'' whose CDW channel is turned on by
a transverse current. Our results also have important implications for the
recently proposed ``striped phase'' of the high-T superconductors.Comment: change of title and minor corrections, 4 RevTeX pgs, to appear in
Phys. Rev. Lett., 81, 3711 (1998
Structure of hard-hypersphere fluids in odd dimensions
The structural properties of single component fluids of hard hyperspheres in
odd space dimensionalities are studied with an analytical approximation
method that generalizes the Rational Function Approximation earlier introduced
in the study of hard-sphere fluids [S. B. Yuste and A. Santos, Phys. Rev. A
{\bf 43}, 5418 (1991)]. The theory makes use of the exact form of the radial
distribution function to first order in density and extends it to finite
density by assuming a rational form for a function defined in Laplace space,
the coefficients being determined by simple physical requirements. Fourier
transform in terms of reverse Bessel polynomials constitute the mathematical
framework of this approximation, from which an analytical expression for the
static structure factor is obtained. In its most elementary form, the method
recovers the solution of the Percus-Yevick closure to the Ornstein-Zernike
equation for hyperspheres at odd dimension. The present formalism allows one to
go beyond by yielding solutions with thermodynamic consistency between the
virial and compressibility routes to any desired equation of state. Excellent
agreement with available computer simulation data at and is
obtained. As a byproduct of this study, an exact and explicit polynomial
expression for the intersection volume of two identical hyperspheres in
arbitrary odd dimensions is given.Comment: 18 pages, 7 figures; v2: new references added plus minor changes; to
be published in PR
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