Sustainable CO2 adsorbents prepared by coating chitosan onto mesoporous silicas for large-scale carbon capture technology

In this article, we report a new sustainable synthesis procedure for manufacturing chitosan/silica CO2 adsorbents. Chitosan is a naturally abundant material and contains amine functionality, which is essential for selective CO2 adsorptions. It is, therefore, ideally suited for manufacturing CO2 adsorbents on a large scale. By coating chitosan onto high-surface-area mesoporous silica supports, including commercial fumed silica (an economical and accessible reagent) and synthetic SBA-15 and MCF silicas, we have prepared a new family of CO2 adsorbents, which have been fully characterised with nitrogen adsorption isotherms, thermogravimetric analysis/differential scanning calorimetry, TEM, FTIR spectroscopy and Raman spectroscopy. These adsorbents have achieved a significant CO2 adsorption capacity of up to 0.98 mmol g−1 at ambient conditions (P=1 atm and T=25 °C). The materials can also be fully regenerated/recycled on demand at temperatures as low as 75 °C with a >85 % retention of the adsorption capacity after 4 cycles, which makes them promising candidates for advanced CO2 capture, storage and utilisation technology

Cognitive demands of face monitoring: Evidence for visuospatial overload

Young children perform difficult communication tasks better face to face than when they cannot see one another (e.g., Doherty-Sneddon & Kent, 1996). However, in recent studies, it was found that children aged 6 and 10 years, describing abstract shapes, showed evidence of face-to-face interference rather than facilitation. For some communication tasks, access to visual signals (such as facial expression and eye gaze) may hinder rather than help children’s communication. In new research we have pursued this interference effect. Five studies are described with adults and 10- and 6-year-old participants. It was found that looking at a face interfered with children’s abilities to listen to descriptions of abstract shapes. Children also performed visuospatial memory tasks worse when they looked at someone’s face prior to responding than when they looked at a visuospatial pattern or at the floor. It was concluded that performance on certain tasks was hindered by monitoring another person’s face. It is suggested that processing of visual communication signals shares certain processing resources with the processing of other visuospatial information

Dynamical frictional phenomena in an incommensurate two-chain model

Dynamical frictional phenomena are studied theoretically in a two-chain model with incommensurate structure. A perturbation theory with respect to the interchain interaction reveals the contributions from phonons excited in each chain to the kinetic frictional force. The validity of the theory is verified in the case of weak interaction by comparing with numerical simulation. The velocity and the interchain interaction dependences of the lattice structure are also investigated. It is shown that peculiar breaking of analyticity states appear, which is characteristic to the two-chain model. The range of the parameters in which the two-chain model is reduced to the Frenkel-Kontorova model is also discussed.Comment: RevTex, 9 pages, 7 PostScript figures, to appear in Phys. Rev.

Structure of hard-hypersphere fluids in odd dimensions

The structural properties of single component fluids of hard hyperspheres in odd space dimensionalities $d$ are studied with an analytical approximation method that generalizes the Rational Function Approximation earlier introduced in the study of hard-sphere fluids [S. B. Yuste and A. Santos, Phys. Rev. A {\bf 43}, 5418 (1991)]. The theory makes use of the exact form of the radial distribution function to first order in density and extends it to finite density by assuming a rational form for a function defined in Laplace space, the coefficients being determined by simple physical requirements. Fourier transform in terms of reverse Bessel polynomials constitute the mathematical framework of this approximation, from which an analytical expression for the static structure factor is obtained. In its most elementary form, the method recovers the solution of the Percus-Yevick closure to the Ornstein-Zernike equation for hyperspheres at odd dimension. The present formalism allows one to go beyond by yielding solutions with thermodynamic consistency between the virial and compressibility routes to any desired equation of state. Excellent agreement with available computer simulation data at $d=5$ and $d=7$ is obtained. As a byproduct of this study, an exact and explicit polynomial expression for the intersection volume of two identical hyperspheres in arbitrary odd dimensions is given.Comment: 18 pages, 7 figures; v2: new references added plus minor changes; to be published in PR

Realizations of Causal Manifolds by Quantum Fields

Quantum mechanical operators and quantum fields are interpreted as realizations of timespace manifolds. Such causal manifolds are parametrized by the classes of the positive unitary operations in all complex operations, i.e. by the homogenous spaces \D(n)=\GL(\C^n_\R)/\U(n) with $n=1$ for mechanics and $n=2$ for relativistic fields. The rank $n$ gives the number of both the discrete and continuous invariants used in the harmonic analysis, i.e. two characteristic masses in the relativistic case. 'Canonical' field theories with the familiar divergencies are inappropriate realizations of the real 4-dimensional causal manifold \D(2). Faithful timespace realizations do not lead to divergencies. In general they are reducible, but nondecomposable - in addition to representations with eigenvectors (states, particle) they incorporate principal vectors without a particle (eigenvector) basis as exemplified by the Coulomb field.Comment: 36 pages, latex, macros include

Selfdual 2-form formulation of gravity and classification of energy-momentum tensors

It is shown how the different irreducibility classes of the energy-momentum tensor allow for a Lagrangian formulation of the gravity-matter system using a selfdual 2-form as a basic variable. It is pointed out what kind of difficulties arise when attempting to construct a pure spin-connection formulation of the gravity-matter system. Ambiguities in the formulation especially concerning the need for constraints are clarified.Comment: title changed, extended versio

Transversely Driven Charge Density Waves and Striped Phases of High-Tc_c Superconductors: The Current Effect Transistor

We show that a normal (single particle) current density $J_x$ {\em transverse} to the ordering wavevector $2k_F{\bf\hat{z}}$ of a charge density wave (CDW) has dramatic effects both above and {\em below} the CDW depinning transition. It exponentially (in $J_x$) enhances CDW correlations, and exponentially suppresses the longitudinal depinning field. The intermediate longitudinal I-V relation also changes, acquiring a {\em linear} regime. We propose a novel ``current effect transistor'' whose CDW channel is turned on by a transverse current. Our results also have important implications for the recently proposed ``striped phase'' of the high-T$_c$ superconductors.Comment: change of title and minor corrections, 4 RevTeX pgs, to appear in Phys. Rev. Lett., 81, 3711 (1998

Thermal Rounding of the Charge Density Wave Depinning Transition

The rounding of the charge density wave depinning transition by thermal noise is examined. Hops by localized modes over small barriers trigger ``avalanches'', resulting in a creep velocity much larger than that expected from comparing thermal energies with typical barriers. For a field equal to the $T=0$ depinning field, the creep velocity is predicted to have a {\em power-law} dependence on the temperature $T$; numerical computations confirm this result. The predicted order of magnitude of the thermal rounding of the depinning transition is consistent with rounding seen in experiment.Comment: 12 pages + 3 Postscript figure

On the spectrum of Farey and Gauss maps

In this paper we introduce Hilbert spaces of holomorphic functions given by generalized Borel and Laplace transforms which are left invariant by the transfer operators of the Farey map and its induced version, the Gauss map, respectively. By means of a suitable operator-valued power series we are able to study simultaneously the spectrum of both these operators along with the analytic properties of the associated dynamical zeta functions.Comment: 23 page