816 research outputs found
Seasonal variation of cesium 134 and cesium 137 in semidomestic reindeer in Norway after the Chernobyl accident
The Chernobyl accident had a great impact on the semidomestic reindeer husbandry in central Norway. Seasonal differences in habitat and diet resulted in large variations in observed radiocesium concentrations in reindeer after the Chernobyl accident. In three areas with high values of cesium-134 and cesium-137 in lichens, the main feed for reindeer in winter, reindeer were sampled every second month to monitor the seasonal variation and the decrease rate of the radioactivity. The results are based on measurements of cesium-134 and cesium-137 content in meat and blood and by whole-body monitoring of live animals. In 1987 the increase of radiocesium content in reindeer in Vågå were 4x from August to January. The mean reductions in radiocesium content from the winter 1986/87 to the winter 1987/88 were 32%, 50% and 43% in the areas of Vågå, Østre-Namdal and Lom respectively
Effect of Prussian blue (ammonium-iron-hexacyanoferrate) in reducing the accumulation of radiocesium in reindeer
Spectroscopy of F
The structure of the weakly-bound F odd-odd nucleus,
produced from Na nuclei, has been investigated at GANIL by means of
the in-beam -ray spectroscopy technique. A single -line is
observed at 657(7) keV in F which has been ascribed to the decay of
the excited J= state to the J=1 ground state. The possible presence of
intruder negative parity states in F is also discussed.Comment: 3 pages, 1 figure, accepted for publication in Physical Review
Reactivity of Biarylazacyclooctynones in Copper-Free Click Chemistry
The 1,3-dipolar cycloaddition of cyclooctynes with azides, also called "copper-free click chemistry", is a bioorthogonal reaction with widespread applications in biological discovery. The kinetics of this reaction are of paramount importance for studies of dynamic processes, particularly in living subjects. Here we performed a systematic analysis of the effects of strain and electronics on the reactivity of cyclooctynes with azides through both experimental measurements and computational studies using a density functional theory (DFT) distortion/interaction transition state model. In particular, we focused on biarylazacyclooctynone (BARAC) because it reacts with azides faster than any other reported cyclooctyne and its modular synthesis facilitated rapid access to analogues. We found that substituents on BARAC's aryl rings can alter the calculated transition state interaction energy of the cycloaddition through electronic effects or the calculated distortion energy through steric effects. Experimental data confirmed that electronic perturbation of BARAC's aryl rings has a modest effect on reaction rate, whereas steric hindrance in the transition state can significantly retard the reaction. Drawing on these results, we analyzed the relationship between alkyne bond angles, which we determined using X-ray crystallography, and reactivity, quantified by experimental second-order rate constants, for a range of cyclooctynes. Our results suggest a correlation between decreased alkyne bond angle and increased cyclooctyne reactivity. Finally, we obtained structural and computational data that revealed the relationship between the conformation of BARAC's central lactam and compound reactivity. Collectively, these results indicate that the distortion/interaction model combined with bond angle analysis will enable predictions of cyclooctyne reactivity and the rational design of new reagents for copper-free click chemistry
A one-dimensional lattice model for a quantum mechanical free particle
Two types of particles, A and B with their corresponding antiparticles, are
defined in a one dimensional cyclic lattice with an odd number of sites. In
each step of time evolution, each particle acts as a source for the
polarization field of the other type of particle with nonlocal action but with
an effect decreasing with the distance: A -->...\bar{B} B \bar{B} B \bar{B} ...
; B --> A \bar{A} A \bar{A} A ... . It is shown that the combined distribution
of these particles obeys the time evolution of a free particle as given by
quantum mechanics.Comment: 8 pages. Revte
Quadrupole Moment Measurements of TSD1 and TSD2 Bands in \u3csup\u3e167\u3c/sup\u3eLu
The triaxial strongly deformed (TSD) bands in 167Lu were populated by the 123Sb(48Ca, 4n) reaction with a beam energy of 203 MeV. Gamma rays, requiring fivefold or more in prompt coincidence, were detected with the Gammasphere spectrometer. Of particular interests are TSD bands 1 and 2 which have previously been interpreted as zero phonon and one phonon wobbling bands, respectively. Using the Doppler shift attenuation method (DSAM), a preliminary transition quadrupole moment of 6.9+0.3−0.3 eb was extracted for the TSD1 band. Data analysis continues for TSD2 which is considerably more weakly populated
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