A simple variational method for calculating energy and quantum capacitance of an electron gas with screened interactions

We describe a variational procedure for calculating the energy of an electron gas in which the long-range Coulomb interaction is truncated by the screening effect of a nearby metallic gate. We use this procedure to compute the quantum capacitance of the system as a function of electron density and spin polarization. The accuracy of the method is verified against published Monte-Carlo data. The results compare favorably with a recent experiment.Comment: 4 pages, 3 figure

A Rich Population of X-ray Emitting Wolf-Rayet Stars in the Galactic Starburst Cluster Westerlund 1

Recent optical and IR studies have revealed that the heavily-reddened starburst cluster Westerlund 1 (Wd 1) contains at least 22 Wolf-Rayet (WR) stars, comprising the richest WR population of any galactic cluster. We present results of a senstive Chandra X-ray observation of Wd 1 which detected 12 of the 22 known WR stars and the mysterious emission line star W9. The fraction of detected WN stars is nearly identical to that of WC stars. The WN stars WR-A and WR-B as well as W9 are exceptionally luminous in X-rays and have similar hard heavily-absorbed spectra with strong Si XIII and S XV emission lines. The luminous high-temperature X-ray emission of these three stars is characteristic of colliding wind binary systems but their binary status remains to be determined. Spectral fits of the X-ray bright sources WR-A and W9 with isothermal plane-parallel shock models require high absorption column densities log N$_{H}$ = 22.56 (cm$^{-2}$) and yield characteristic shock temperatures kT_shock ~ 3 keV (T ~ 35 MK).Comment: ApJL, 2006, in press (3 figures, 1 table

Investigation of Graded La2NiO4+ Cathodes to Improve SOFC Electrochemical Performance

Mixed ionic and electronic conducting MIEC oxides are promising materials for use as cathodes in solid oxide fuel cells SOFCs due to their enhanced electrocatalytic activity compared with electronic conducting oxides. In this paper, the MIEC oxide La2NiO4+ was prepared by the sol-gel route. Graded cathodes were deposited onto yttria-stabilized zirconia YSZ pellets by dip-coating, and electrochemical impedance spectroscopy studies were performed to characterize the symmetrical cell performance. By adapting the slurries, cathode layers with different porosities and thicknesses were obtained. A ceria gadolinium oxide CGO barrier layer was introduced, avoiding insulating La2Zr2O7 phase formation and thus reducing resistance polarization of the cathode. A systematic correlation between microstructure, composition, and electrochemical performance of these cathodes has been performed. An improvement of the electrochemical performance has been demonstrated, and a reduction in the area specific resistance ASR by a factor of 4.5 has been achieved with a compact interlayer of La2NiO4+ between the dense electrolyte and the porous La2NiO4+ cathode layer. The lowest observed ASR of 0.11 cm2 at 800°C was obtained from a symmetrical cell composed of a YSZ electrolyte, a CGO interlayer, an intermediate compact La2NiO4+ layer, a porous La2NiO4+ electrode layer, and a current collection layer of platinum paste

Color infrared photography and thermal infrared imagery of selected locations along the Missouri River between Omaha and Blair, Nebraska

CER71-72MMS-JFR 49.June, 1972.Submitted to Department of the Army Omaha District, Corps of Engineers Omaha, Nebraska.Circulating copy deaccessioned 2020

Analysis of macrolide antibiotics

The following macrolide antibiotics have been covered in this review: erythromycin and its related substances, azithromycin, clarithromycin, dirithromycin, roxithromycin, flurithromycin, josamycin, rokitamycin, kitasamycin, mycinamycin, mirosamycin, oleandomycin, rosaramicin, spiramycin and tylosin. The application of various thin-layer chromatography, paper chromatography, gas chromatography, high-performance liquid chromatography and capillary zone electrophoresis procedures for their analysis are described. These techniques have been applied to the separation and quantitative analysis of the macrolides in fermentation media, purity assessment of raw materials, assay of pharmaceutical dosage forms and the measurement of clinically useful macrolide antibiotics in biological samples such as blood, plasma, serum, urine and tissues. Data relating to the chromatographic behaviour of some macrolide antibiotics as well as the various detection methods used, such as bioautography, UV spectrophotometry, fluorometry, electrochemical detection, chemiluminescence and mass spectrometry techniques are also included

A Persistent High-Energy Flux from the Heart of the Milky Way : Integral's view of the Galactic Center

The Ibis/Isgri imager on Integral detected for the first time a hard X-ray source, IGR J17456-2901, located within 1' of Sgr A* over the energy range 20-100 keV. Here we present the results of a detailed analysis of ~7 Ms of Integral observations of the GC. With an effective exposure of 4.7 Ms we have obtained more stringent positional constraints on this HE source and constructed its spectrum in the range 20-400 keV. Furthermore, by combining the Isgri spectrum with the total X-ray spectrum corresponding to the same physical region around SgrA* from XMM data, and collected during part of the Integral observations, we constructed and present the first accurate wide band HE spectrum for the central arcmins of the Galaxy. Our complete analysis of the emission properties of IGR shows that it is faint but persistent with no variability above 3 sigma contrary to what was alluded to in our first paper. This result, in conjunction with the spectral characteristics of the X-ray emission from this region, suggests that the source is most likely not point-like but, rather, that it is a compact, yet diffuse, non-thermal emission region. The centroid of IGR is estimated to be R.A.=17h45m42.5, decl.=-28deg59'28'', offset by 1' from the radio position of Sgr A* and with a positional uncertainty of 1'. Its 20-400 keV luminosity at 8 kpc is L=5.4x10^35 erg/sec. Very recently, Hess detected of a source of ~TeV g-rays also located within 1' of Sgr A*. We present arguments in favor of an interpretation according to which the photons detected by Integral and Hess arise from the same compact region of diffuse emission near the central BH and that the supernova remnant Sgr A East could play an important role as a contributor of very HE g-rays to the overall spectrum from this region.Comment: 14 pages, 11 figures, Accepted for publication in Ap

The problem of shot selection in basketball

In basketball, every time the offense produces a shot opportunity the player with the ball must decide whether the shot is worth taking. In this paper, I explore the question of when a team should shoot and when they should pass up the shot by considering a simple theoretical model of the shot selection process, in which the quality of shot opportunities generated by the offense is assumed to fall randomly within a uniform distribution. I derive an answer to the question "how likely must the shot be to go in before the player should take it?", and show that this "lower cutoff" for shot quality $f$ depends crucially on the number $n$ of shot opportunities remaining (say, before the shot clock expires), with larger $n$ demanding that only higher-quality shots should be taken. The function $f(n)$ is also derived in the presence of a finite turnover rate and used to predict the shooting rate of an optimal-shooting team as a function of time. This prediction is compared to observed shooting rates from the National Basketball Association (NBA), and the comparison suggests that NBA players tend to wait too long before shooting and undervalue the probability of committing a turnover.Comment: 7 pages, 2 figures; comparison to NBA data adde

Effect of bridge constriction on scour and backwater

CER60HKL22.February 1961.Includes bibliographical references (pages 56-57).Prepared for Bureau of Public Roads.Under contract CPR11-5480