68 research outputs found

    An accurate measurement of electron beam induced displacement cross sections for single-layer graphene

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    We present an accurate measurement and a quantitative analysis of electron-beam induced displacements of carbon atoms in single-layer graphene. We directly measure the atomic displacement ("knock-on") cross section by counting the lost atoms as a function of the electron beam energy and applied dose. Further, we separate knock-on damage (originating from the collision of the beam electrons with the nucleus of the target atom) from other radiation damage mechanisms (e.g. ionization damage or chemical etching) by the comparison of ordinary (12C) and heavy (13C) graphene. Our analysis shows that a static lattice approximation is not sufficient to describe knock-on damage in this material, while a very good agreement between calculated and experimental cross sections is obtained if lattice vibrations are taken into account.Comment: 10 pages including supplementary inf

    Direct transfer of CVD Grown Transparent SWCNT Networks from Growth Substrate to Polymer

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    Single-wall carbon nanotubes (SWCNTs) are one of the most interesting materials for transparent conductive films. In this work, we show our latest results on growth of transparent nanotube networks on quartz and silicon dioxide, and a new process to make a solid-tosolid direct transfer of these networks on a polycarbonate film to obtain, at room temperature, a conductive transparent material

    SWNT probed by multi-frequency EPR and microwave absorption

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    In addition to g = 2.00 signals seen frequently in EPR spectra of SWNT, signals at g = 2.07 of SWNT prepared by CVD were detected, exhibiting a Pauli susceptibility temperature dependence. This Pauli magnetism in combination with the large g shift is taken as evidence that these signals originate from itinerant electrons of metallic nanotubes. At temperatures below 150 K, a dominant narrow signal develops at g = 2.00. By applying multifrequency EPR up to 319 GHz, its inhomogeneous nature was confirmed. This signal is assigned to defects of the carbon network of the tubes. Comparing room temperature EPR spectra of CVD and arc-grown SWNT, we found a much lower concentration of metallic tubes in arc material. No g = 2.07 signals of itinerant spins could be observed, which might be also caused by the high amount of residing catalyst. A drastic increase in nonresonant microwave absorption is observed below 10 K for both types of samples, if a threshold microwave power level is passed. In the same temperature range a drop in EPR intensity is also detected. These observations are taken as evidence for a transition into a superconducting phase of part of the sample

    Chem. Phys. Lett.

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    Catalytic chemical vapour deposition growth of single wall carbon nanotubes films on different substrates for transparent electronic devices

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    In this work we present our results concerning the growth of transparent carbon nanotube networks. The networks have been successfully grown on both oxidized silicon and quartz-glass substrates. Conductive and optical properties of these transparent films are discussed and compared to those obtained with other approaches. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

    Supercond. Sci. Technol.

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