Particle-in-cell simulations of shock-driven reconnection in relativistic striped winds

By means of two- and three-dimensional particle-in-cell simulations, we investigate the process of driven magnetic reconnection at the termination shock of relativistic striped flows. In pulsar winds and in magnetar-powered relativistic jets, the flow consists of stripes of alternating magnetic field polarity, separated by current sheets of hot plasma. At the wind termination shock, the flow compresses and the alternating fields annihilate by driven magnetic reconnection. Irrespective of the stripe wavelength "lambda" or the wind magnetization "sigma" (in the regime sigma>>1 of magnetically-dominated flows), shock-driven reconnection transfers all the magnetic energy of alternating fields to the particles, whose average Lorentz factor increases by a factor of sigma with respect to the pre-shock value. In the limit lambda/(r_L*sigma)>>1, where r_L is the relativistic Larmor radius in the wind, the post-shock particle spectrum approaches a flat power-law tail with slope around -1.5, populated by particles accelerated by the reconnection electric field. The presence of a current-aligned "guide" magnetic field suppresses the acceleration of particles only when the guide field is stronger than the alternating component. Our findings place important constraints on the models of non-thermal radiation from Pulsar Wind Nebulae and relativistic jets.Comment: 25 pages, 14 figures, movies available at https://www.cfa.harvard.edu/~lsironi/sironi_movies.tar ; in press, special issue of Computational Science and Discovery on selected research from the 22nd International Conference on Numerical Simulation of Plasma

Expeditious Calibration Method for Quantification of Odorous Mixtures via GC

An odour sample is generally a complex matrix consisting of numerous molecules (mostly volatile organic compounds, VOCs) chemically different from each other, and which can be perceived by the human nose. In order to chemically characterize this complex gaseous matrix, gas-chromatography (GC) is commonly used. By this analytical technique, it is possible to obtain the resolution of odour gaseous mixtures in order to qualify and quantify the compounds. However, the quantification is a tricky operation based on the comparison of the sample under examination with purpose-made gas mixtures containing a compound, chosen as a standard, at known concentration. Commonly, these mixtures are obtained from cylinders of compressed gases, the use of which involves problems relating to their management, thermodynamic equilibrium feasibility, considerable economic outlay and not-negligible procurement times. This paper describes a method, proposed as a versatile and simple alternative to the use of such cylinders, for preparing gaseous calibration standards at known concentration. The method involves the continuous injection of VOC in liquid form, by means of a syringe pump, into a stream of neutral gas, such as air or nitrogen, which acts as diluent gas, controlled by a mass flow meter. Exploiting the volatility of the compounds used, it is possible to generate a continuous gas stream, exiting the system, containing the selected VOC at the desired concentration, which can be directly used as calibration standard

Separation of the Galactic Synchrotron Foreground and the CMB Polarization Measurements

The polarization of the CMBR represents a powerful test for modern cosmology. It allows to break the degeneracy of fundamental cosmological parameters, and also to observe the contribution of gravitational waves background to the CMBR anisotropy. To observe the CMBR polarization several experiments are either in progress or planned and SPOrt is one of the most promising planned by ESA. At the same time the observation of the CMBR polarization is a difficult task and one of the reasons is the presence of polarized foreground emission. For instance, galactic polarized synchrotron emission (according to some estimates) can completely mimic the polarization of the CMBR. Nevertheless, one can use mathematical properties of the spherical harmonics of the distribution of radiation over the sky to separate different contributions. In this paper the mathematical properties of the polarized synchrotron foreground and the physical mechanism that produces it are discussed. The separation of synchrotron polarization from the polarization generated by density cosmological perturbations is discussed as well.Comment: 10 LaTeX pages, acceptted to AIP Conference Proceedin

Analysis of Odorous VOCs using TD-GC-MS/FID/PFPD: Development and Applications to Real Samples

This work aims to present the applicability of a gas chromatograph equipped with three detectors for the analysis of odorous mixtures. An Agilent gas chromatograph (mod. 8890), equipped with a mass spectrometer (Agilent 5977B MSD), a Flame Ionization Detector (FID, Agilent) and a Pulsed Flame Photometric Detector (PFPD, OI Analytical mod. 5833) was adopted, obtaining simultaneous acquisition with MS, FID and PFPD detectors. The splitting of the sample into the three detectors was carried out at the end of the chromatographic column, by a capillary flow technology splitter (Agilent Splitter CFT). By using this system, it is, therefore, possible to achieve the specific detection and quantification of organic compounds by FID analysis, sulphur compounds by PFPD and the identification of the compounds by MS analysis, via comparison with mass spectra. Based on the preliminary outcomes obtained,the application of this system in the analysis of odour samples enabled the determination of specific classes, even in traces: by this, the subsequent identification of these compounds during a single chromatographic run is possible. This combination provides significant time and costs savings in the calibration and analysis of chromatographic data

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Halogen bonding in the framework of classical force fields: The case of chlorine

Halogen bonding is nowadays a consolidated tool in chemistry. Only recently, the importance of halogen bonding has been demonstrated also in biological systems, owing to the presence of halogens in drugs. This interaction is due to the anisotropy of the electron density around the halogen that leads to the formation of the \u2018\u3c3-hole\u2019, which is responsible for the interaction with a nucleophile site. Unfortunately, classical force fields used in the study of ligand-receptor systems are not able to describe the \u2018\u3c3-hole\u2019. Here, we propose a pseudo-atom based methodology able to correctly describe halogen bonding involving chlorine using classical force field

A valence bond description of the bromine halogen bond

A theoretical investigation on the nature of the halogen bond through a valence-bond approach has been carried out with two main goals: (a) finding further confirmations of already existing explanations on the physical origins of the halogen bond and (b) possibly enriching the current models with new details. To achieve these goals we have exploited the spin-coupled method and we have performed computations on RBr efNH3 dimers characterized by a different electron withdrawing power of substituent \uf8ffR to the bromine atom. The analysis of typical spin-coupled descriptors (eg, shapes and overlaps of the spin-coupled orbitals, weights of the spin-coupled structures) in the different cases and in function of the distance between the monomers allowed us to draw qualitative conclusions about the formation and the strength of the halogen bonds. In particular, the investigation not only confirmed the validity of already existing models (ie, \u3c3-hole and lump-hole models) but also highlighted interesting new features, such as the fact that the depletion of electron density around the bromine atom does not extend only toward the acceptor of the halogen bond, but also in the opposite direction (toward the substituent of the halogen), thus forming a sort of \u3c3-tunnel, rather than a simple \u3c3-hole

Sulphur Compounds: Comparison of Different Sorbent Tubes for their Detection

Different techniques have been developed for the analysis of gaseous sulphur pollutants, to maximize the analytical signals. In a complex matrix, such as odorous emissions, the detection of sulphur compounds can be critical in GC analysis, due to the lower concentration of these pollutants and the disturbing effect of co-eluting hydrocarbons. However, their detection is fundamental because they have a non-negligible odour impact. In the field of gaseous emissions analytics, it is common to use sorbent tubes for the sampling step. This technology uses different adsorbent materials, with different selectivity depending on the nature of the gas to be analysed. This work aims to evaluate the ability of three different sorbent tubes to collect different sulphur compounds, belonging to the classes of mercaptans, thioethers and aromatic heterocyclic compounds. A standard solution of 10 sulphur compounds was prepared by diluting in methanol 50 µL of each liquid standard into a 10 mL flask. Subsequently, this solution was diluted in methanol to obtain sulphur standards at five different concentrations (approximately 5-500 ng/µL). The tubes were loaded with the standard solutions with an aliquot of each solution, using a gas chromatograph packed column injector and subsequently analysed by TD-GC-MS. By the results obtained - average Response Factor (RF) and its Relative Standard Deviation (% RSD), it is possible to conduct a comparison among these tubes and evaluate their performance. From the comparison of the tubes, discussing % RSD, it is possible to highlight a slightly better performance, in terms of the number of compounds with % RSD ≤ 30%, for tubes specific for sulphur compounds. Focusing on RF values, multi-sorbent bed tubes show slightly higher RFs for very volatile sulphur compounds, but Sulphur tubes present higher RF values for 6 compounds out of 10 compounds considered. The performance of Tenax TA tubes, instead, appears strictly correlated with the compound’s volatility and therefore they don’t appear useful for sorption of very volatile compounds