55,078 research outputs found
Arsenic(III) remediation from contaminated water by oxidation and Fe/Al co-precipitation
Battery grade γ-MnO2 powder was investigated as an oxidant and an adsorbent in combination with Fe/Al coagulants for removal of arsenic from contaminated water. Simultaneous oxidation of As(III) and removal by coprecipitation/adsorption (one step process) was compared with pre-oxidation and subsequent removal by coprecipitation/adsorption (two step process). The rate of As(III) oxidation with MnO2 is completed in two stages: rapid initially followed by a first order reaction. As(III) is oxidised to As(V) by the MnO2 with a release of approximately 1:1 molar Mn(II) into the solution. No significant pH effect on oxidation of As(III) was observed in the pH range 4 - 6. The rate showed a decreasing trend above pH 6. The removal of As(V) by adsorption on the MnO2 decreased significantly with increasing pH from 4 to 8. The adsorption capacity of the γ-MnO2 with particle size 90% passing 10 µm was determined to be 1.5 mg/g at pH 7. MnO2 was found to be more effective as an oxidant for As(III) in the two step process than in the one step process
Constraint elimination in dynamical systems
Large space structures (LSSs) and other dynamical systems of current interest are often extremely complex assemblies of rigid and flexible bodies subjected to kinematical constraints. A formulation is presented for the governing equations of constrained multibody systems via the application of singular value decomposition (SVD). The resulting equations of motion are shown to be of minimum dimension
A characterization of the central shell-focusing singularity in spherical gravitational collapse
We give a characterization of the central shell-focusing curvature
singularity that can form in the spherical gravitational collapse of a bounded
matter distribution obeying the dominant energy condition. This
characterization is based on the limiting behaviour of the mass function in the
neighbourhood of the singularity. Depending on the rate of growth of the mass
as a function of the area radius R, the singularity may be either covered or
naked. The singularity is naked if this growth rate is slower than R, covered
if it is faster than R, and either naked or covered if the growth rate is same
as R.Comment: 12 pages, Latex, significantly revised version, including change of
title. Revised version to appear in Classical and Quantum Gravit
High-energy magnon dispersion and multi-magnon continuum in the two-dimensional Heisenberg antiferromagnet
We use quantum Monte Carlo simulations and numerical analytic continuation to
study high-energy spin excitations in the two-dimensional S=1/2 Heisenberg
antiferromagnet at low temperature. We present results for both the transverse
and longitudinal dynamic spin structure factor S(q,w) at q=(pi,0) and
(pi/2,pi/2). Linear spin-wave theory predicts no dispersion on the line
connecting these momenta. Our calculations show that in fact the magnon energy
at (pi,0) is 10% lower than at (pi/2,pi/2). We also discuss the transverse and
longitudinal multi-magnon continua and their relevance to neutron scattering
experiments.Comment: 4 page
Spin-charge and spin-orbital coupling effects on spin dynamics in ferromagnetic manganites
Correlation-induced spin-charge and spin-orbital coupling effects on spin
dynamics in ferromagnetic manganites are calculated with realistic parameters
in order to provide a quantitative comparison with experimental results for
spin stiffness, magnon dispersion, magnon damping, anomalous zone-boundary
magnon softening, and Curie temperature. The role of orbital degeneracy,
orbital ordering, and orbital correlations on spin dynamics in different doping
regimes is highlighted.Comment: 19 pages, 9 figure
Magnetocapacitance effect in perovskite-superlattice based multiferroics
We report the structural and magnetoelectrical properties of
LaCaMnO/BaTiO perovskite superlattices grown on
(001)-oriented SrTiO by the pulsed laser deposition technique. Magnetic
hysteresis loops together with temperature dependent magnetic properties
exhibit well-defined coercivity and magnetic transition temperature (T)
\symbol{126}140 K. electrical studies of films show that the
magnetoresistance (MR) is dependent on the BaTiO thickness and negative
as high as 30% at 100K are observed. The electrical studies reveal
that the impedance and capacitance in these films vary with the applied
magnetic field due to the magnetoelectrical coupling in these structures - a
key feature of multiferroics. A negative magnetocapacitance value in the film
as high as 3% per tesla at 1kHz and 100K is demonstrated, opening the route for
designing novel functional materials.Comment: To be published in Applied Physics Letter
Are naked singularites forbidden by the second law of thermodynamics?
By now, many examples of naked singularities in classical general relativity
are known. It may however be that a physical principle over and above the
general theory prevents the occurrence of such singularities in nature.
Assuming the validity of the Weyl curvature hypothesis, we propose that naked
singularities are forbidden by the second law of thermodynamics.Comment: 6 pages, Latex file. This essay was selected for honorable mention by
the Gravity Research Foundatio
The role of ferroelectric-ferromagnetic layers on the properties of superlattice-based multiferroics
A series of superlattices and trilayers composed of ferromagnetic and
ferroelectric or paraelectric layers were grown on (100) SrTiO3 by the pulsed
laser deposition technique. Their structural and magneto-electric properties
were examined. The superlattices made of ferromagnetic Pr0.85Ca0.15MnO3 (PCMO)
and a ferroelectric, namely Ba0.6Sr0.4TiO3 (BST) or BaTiO3, showed enhanced
magnetoresistance (MR) at high applied magnetic field, whereas such enhancement
was absent in Pr0.85Ca0.15MnO3/SrTiO3 superlattices, which clearly demonstrates
the preponderant role of the ferroelectric layers in this enhanced MR.
Furthermore, the absence of enhanced MR in trilayers of PCMO/BST indicates that
the magneto-electric coupling which is responsible for MR in these systems is
stronger in multilayers than in their trilayer counterparts.Comment: to be published in J. Appl. Phy
- …