Highly selective fluoride sensing via chromogenic aggregation of a silyloxy-functionalized tetraphenylethylene (TPE) derivative

Cataloged from PDF version of article.A silyloxy-functionalized tetraphenylethylene (TPE) derivative shows a remarkable change in the absorption spectrum on deprotection with fluoride ions. The reaction process is highly selective for fluoride and the resulting charge transfer band results in a bright green solution. A simple selective visual assay of aqueous fluoride ions was also obtained by the impregnation of cellulose strips with the TPE derivative

Static and vibration analysis of functionally graded beams using refined shear deformation theory

Static and vibration analysis of functionally graded beams using refined shear deformation theory is presented. The developed theory, which does not require shear correction factor, accounts for shear deformation effect and coupling coming from the material anisotropy. Governing equations of motion are derived from the Hamilton's principle. The resulting coupling is referred to as triply coupled axial-flexural response. A two-noded Hermite-cubic element with five degree-of-freedom per node is developed to solve the problem. Numerical results are obtained for functionally graded beams with simply-supported, cantilever-free and clamped-clamped boundary conditions to investigate effects of the power-law exponent and modulus ratio on the displacements, natural frequencies and corresponding mode shapes

Ferroelectric Based Photonic Crystal Cavity by Liquid Crystal Infiltration

Cataloged from PDF version of article.A novel type of two-dimensional photonic crystal is investigated for it optical properties as a core-shell-type ferroelectric nanorod infiltrated with nematic liquid crystals. Using the plane wave expansion method and finite-difference time-domain method, the photonic crystal structure, which is composed of a photonic crystal in a core-shell-type ferroelectric nanorod, is designed for the square lattice and the hexagonal lattice. It has been used 5CB as a photonic crystal core, and LiNbO3 as a ferroelectric material. The photonic crystal with a core-shell-type LiNbO3 nanorod infiltrated with nematic liquid crystals is compared with the photonic crystal with solid LiNbO3 rods and the photonic crystal with hollow LiNbO3 rods

Yield response of mushroom (Agaricus bisporus) on wheat straw and waste tea leaves based composts using supplements of some locally available peats and their mixture with some secondary casing materials

The study was conducted to investigate yields of mushroom (Agaricus bisporus) on wheat straw and waste tea leaves based composts. Mixtures (50:50, v/v) of some locally available peats including peat ofBolu (PB), peat of Agacbasi (PA), peat of Caykara (PC) and their mixture (80:20; v/v) with which piece of mosaic and sand were used. Also, some activator materials such as wheat bran, wheat chaff, chickenmanure, pigeon manure, and poplar leaves were used for A. bisporus cultivation. The results on wheat straw based composts provided the highest mushroom yield (23.01%) that was obtained on wheat strawand pigeon manure based compost using a mixture of PA with PC (50+50; v/v) as casing material. For waste tea leaves based composts, the highest mushroom yield (24.90%) were recorded on wheat straw and pigeon manure based compost using a mixture of PC with sand (80+20; v/v) as casing material

Cultivation of Agaricus bisporus on wheat straw and waste tea leaves based composts and locally available casing materials Part III: Dry matter, protein, and carbohydrate contents of Agaricus bisporus

This study was performed to determine the effects of composts and casing materials on dry matter, protein, and carbohydrate contents of the fruit bodies of Agaricus bisporus. Results showed that Agaricus bisporus cultivated on group I and group II casing soil groups showed remarkably higher dry matter and carbohydrate contents compared to other casing groups. No significant differences were found among casing soil groups in terms of protein content of Agaricus bisporus cultivated on wheatstraw. But, there were significant differences between casing soil groups in terms of protein content of Agaricus bisporus cultivated on waste tea leaves

Mitral regurgitation:when to intervene? A historical perspective

Although mitral regurgitation (MR) is the most common valvular heart disease, it should be regarded as a complex multifactorial disease that involves multiple entities. Optimal medical therapy alone does not hinder the progression of the disease, and in the 1980s it was already recognised that corrective surgery is indicated if MR is severe and patients are symptomatic (except for those with the most severe left ventricle dysfunction). Later on, asymptomatic patients with deterioration of the left ventricular ejection fraction were also operated on to avoid irreversible left ventricular dysfunction, heart failure and eventually death. However, a major drawback remains the fact that a significant group of patients is considered to have a high perioperative risk due to their advanced age or severe comorbidities. Since less invasive, percutaneous interventions have been developed and recently thoroughly investigated in the MITRA-FR and the COAPT studies, the type of intervention and also the timing have become more crucial. In this critical review of the literature, we describe what we should have learned from the past and which (haemodynamic) parameters can best predict the outcome in patients with MR

Transformational Leadership's Role in Promoting Corporate Entrepreneurship : Examining the CEO - TMT Interface

International audienceResearch about transformational CEOs' impact on firm-level outcomes, particularly corporate entrepreneurship, has been equivocal, partially because the underlying mechanisms remain largely unexplored. Given that the individuals most closely influenced by a firm's CEO are its top management team (TMT) members, we focus on the CEO-TMT interface as a salient intervening mechanism. We posit that transformational CEOs influence TMTs' behavioral integration, risk propensity, decentralization of responsibilities, and long-term compensation and that these TMT characteristics impact corporate entrepreneurship. Data from 152 firms supported most of our hypothesized links, underscoring how the CEO-TMT interface helps explain transformational CEOs' role in promoting corporate entrepreneurship.<br/

An investigation on pin head formation time of Agaricus bisporus on wheat straw and waste tea leaves based composts using some locally available peat materials and secondary casing materials

This study was designed to determine pin head formation time of Agaricus bisporus on wheat straw and waste tea leaves based composts. Locally available peat materials such as peat of Bolu (PB), peat of Agacbasi (PA), peat of Caykara (PC), and their mixture (80:20; v:v) with piece of mosaic (PM), perlite (P), and sand (S) were used as secondary casing materials. Also, some activator materials such aswheat bran, chicken manure, and pigeon manure were used for A. bisporus cultivation. For wheat straw based composts, the fastest pin head formation times were observed with a mixture of PA with PMcasing material on wheat straw and chicken manure based compost and with PA casing material on wheat straw and pigeon manure based compost. For waste tea leaves based composts, the fastest pinhead formation times were obtained with a mixture of PA with PM and PC with PM on waste tea leaves and chicken manure based compost. Generally, when peat materials were used in combination witheach other, the period of pin head formation times shortened compared to their individual use. A mixture of forest soil with sand (80 + 20; in volume) gave the worst results in terms of pin head formation times for both composts. In secondary casing materials, PM gave the best results in terms of pin head formation time for both composts

Cultivation of Agaricus bisporus on some compost formulas and locally available casing materials. Part II: Waste tea leaves based compost formulas and locally available casing materials

Three compost formulas (formula I, formula II, and formula III) based waste tea leaves and using some activator materials such as wheat bran, chicken manure and pigeon manure were studied for Agaricusbisporus cultivation. Some locally available peats such as peat of Bolu, peat of Agacbasi, peat of Caykara and theirs mixture (80:20; volume : volume) with perlite were used. Temperature values of allcompost formulas during composting process were measured to determine the compostability level. According to results, compost temparature steadily increased until the 8th, 9th, and 9th day ofcomposting for formula I, formula II, and formula III, respectively. The maximum compost temperature values were measured for all compost formulas at the second turning stage of composting process.The highest compost temperature values were measured prepared from a mixture of waste tea leaves and wheat bran (formula I). The best mushroom yield was obtained by a mixture of waste tea leaves andpigeon manure with the peat of Caykara and perlite mixture as casing material. Peat of Caykara gave higher mushroom yield than those of other peats