1,543 research outputs found
Interpretation of shallow electromagnetic instruments resistivity and magnetic susceptibility measurements using rapid 1D/3D inversion
International audienceWe have developed an inversion process of electromagnetic induction (EMI) data based on a two-step approach with 1D inversion of the entire studied surface and a fast 3D inversion applied over limited areas. This process is similar to that formerly used in resistivity prospection. For the study of soil (environmental, engineering, or archaeological explorations), low-frequency electromagnetic instruments (referred to as Slingram EMI) have highly useful specificities. They are light, are easy to move in the field, and can simultaneously measure the ground’s electric conductivity and magnetic susceptibility; they have thus been used to map these properties over large surface areas, within relatively short periods of time, and at reasonable expense. The possibility of combining several coil geometries has opened up the potential for multidepth techniques and systematic 1D inversion, which are found to be sufficiently revealing to allow larger portions of surveyed areas to be analyzed. In the “targeted areas” selected for 3D inversion, the geometries of the 3D features and the resistivity and/or susceptibility contrasts are determined. This step is based on the method of moments, where only 3D heterogeneities are meshed, and only a small number of major characteristics, such as contrast, thickness, width, etc., are sought. We first applied this process to synthetic data, then to data acquired at an experimental test site, and finally to field cases. The rapid 3D inversion complements the 1D inversion by solving a series of issues: correction for the apparent anisotropy generated by the instrument configuration, multiarched anomalies, precise location of lateral changes, and determination of the properties contrasts. Our inversion results highlighted the importance of the instrument geometry. We also have determined that apparent magnetic susceptibility data can be more appropriate for the determination of the volume of man-made features and can be highly complementary to conductivity data
3DMCD/1DLCI inversion of an FD-EMI dataset: the case study of the paleolandscape of Bourbourg/Loon-Plage (France)
An electromagnetic survey supports the archaeological field evaluation. Data calibration with electric sounding is necessary before inversion. The 1D LCI inversion is accurate enough if the horizontal variation is smooth. The 3D MCD inversion considerably reduces lateral effects. To date, the 3D/pseudo-3D is not required in the field evaluation phase
Lack of efflux mediated quinolone resistance in Salmonella enterica serovars Typhi and Paratyphi A.
International audienceSalmonella enterica serovars Typhi and Paratyphi A isolates from human patients in France displaying different levels of resistance to quinolones or fluoroquinolones were studied for resistance mechanisms to these antimicrobial agents. All resistant isolates carried either single or multiple target gene mutations (i.e., in gyrA, gyrB, or parC) correlating with the resistance levels observed. Active efflux, through upregulation of multipartite efflux systems, has also been previously reported as contributing mechanism for other serovars. Therefore, we investigated also the occurrence of non-target gene mutations in regulatory regions affecting efflux pump expression. However, no mutation was detected in these regions in both Typhi and Paratyphi isolates of this study. Besides, no overexpression of the major efflux systems was observed for these isolates. Nevertheless, a large deletion of 2334 bp was identified in the acrS-acrE region of all S. Typhi strains but which did not affect the resistance phenotype. As being specific to S. Typhi, this deletion could be used for specific molecular detection purposes. In conclusion, the different levels of quinolone or FQ resistance in both S. Typhi and S. Paratyphi A seem to rely only on target modifications
GPR on city roadways: two case studies with feedback from trial trenching
GPR surveys were performed in dense urban areas in France. Underground utilities and the narrow width of the streets can make GPR really challenging for archaeological features detection. The relevance of GPR compared to trial trenching is discussed
Magnetic signal prospecting using multi parameter measurements
The magnetic signal of soils The magnetic signal of soils is divided between remanent (Jr) and induced magnetization (Ji) The former has diverse origins (heating, magnetic viscosity, slow deposition of magnetic bulk in a magnetic field) and is proof of the undisturbed state of features. The other, Ji, is acquired in the terrestrial magnetic field and is governed by magnetic susceptibility (κ). But the behavior of this property can be complex when the gain or loss of induced magnetization is d..
Modifications in lower leg muscle activation when walking barefoot or in minimalist shoes across different age-groups
Ageing is associated with a decline in muscle strength and impaired sensory mechanisms which contribute to an increased risk of falls. Walking barefooted has been suggested to promote increased muscle strength and improved proprioceptive sensibility through better activation of foot and ankle musculature. Minimalist footwear has been marketed as a method of reaping the suggested benefits of barefoot walking whilst still providing a protective surface. The aim of this study was to investigate if walking barefoot or in minimalist footwear provokes increased muscle activation compared to walking in conventional footwear. Seventy healthy adults (age range 20-87) volunteered for this study. All participants walked along a 7 m walking lane five times in four different footwear conditions (barefoot (BF), minimalist shoes (MSH), their own shoes (SH) and control shoes (CON)). Muscle activity of their tibialis anterior (TA), gastrocnemius medialis (GCM) and peroneus longus (PL) were recorded simultaneously and normalised to the BF condition. MSH are intermediate in terms of ankle kinematics and muscle activation patterns. Walking BF or in MSH results in a decrease in TA activity at initial stance due to a flatter foot at contact in comparison to conventional footwear. Walking BF reduces PL activity at initial stance in the young and middle age but not the old. Walking in supportive footwear appears to reduce the balance modulation role of the GCM in the young and middle age but not the old, possibly as a result of slower walking speed when BF
Magnetic signal prospecting using multi parameter measurements
The magnetic signal of soils The magnetic signal of soils is divided between remanent (Jr) and induced magnetization (Ji) The former has diverse origins (heating, magnetic viscosity, slow deposition of magnetic bulk in a magnetic field) and is proof of the undisturbed state of features. The other, Ji, is acquired in the terrestrial magnetic field and is governed by magnetic susceptibility (κ). But the behavior of this property can be complex when the gain or loss of induced magnetization is d..
Rich Polymorphism of a Metal–Organic Framework in Pressure–Temperature Space
International audienceWe present an in situ powder X-ray diffraction study on the phase stability and polymorphism of the metal–organic framework ZIF-4, Zn(imidazolate)2, at simultaneous high pressure and high temperature, up to 8 GPa and 600 °C. The resulting pressure–temperature phase diagram reveals four, previously unknown, high-pressure–high-temperature ZIF phases. The crystal structures of two new phases—ZIF-4-cp-II and ZIF-hPT-II—were solved by powder diffraction methods. The total energy of ZIF-4-cp-II was evaluated using density functional theory calculations and was found to lie in between that of ZIF-4 and the most thermodynamically stable polymorph, ZIF-zni. ZIF-hPT-II was found to possess a doubly interpenetrated diamondoid topology and is isostructural with previously reported Cd(Imidazolate)2 and Hg(Imidazolate)2 phases. This phase exhibited extreme resistance to both temperature and pressure. The other two new phases could be assigned with a unit cell and space group, although their structures remain unknown. The pressure–temperature phase diagram of ZIF-4 is strikingly complicated when compared with that of the previously investigated, closely related ZIF-62 and demonstrates the ability to traverse complex energy landscapes of metal–organic systems using the combined application of pressure and temperature
O inventário das curiosidades botânicas da Nouvelle France de Pierre-François-Xavier de Charlevoix (1744)
Rich Polymorphism of a Metal-Organic Framework in Pressure-Temperature Space.
We present an in situ powder X-ray diffraction study on the phase stability and polymorphism of the metal-organic framework ZIF-4, Zn(imidazolate)2, at simultaneous high pressure and high temperature, up to 8 GPa and 600 °C. The resulting pressure-temperature phase diagram reveals four, previously unknown, high-pressure-high-temperature ZIF phases. The crystal structures of two new phases-ZIF-4-cp-II and ZIF-hPT-II-were solved by powder diffraction methods. The total energy of ZIF-4-cp-II was evaluated using density functional theory calculations and was found to lie in between that of ZIF-4 and the most thermodynamically stable polymorph, ZIF- zni. ZIF-hPT-II was found to possess a doubly interpenetrated diamondoid topology and is isostructural with previously reported Cd(Imidazolate)2 and Hg(Imidazolate)2 phases. This phase exhibited extreme resistance to both temperature and pressure. The other two new phases could be assigned with a unit cell and space group, although their structures remain unknown. The pressure-temperature phase diagram of ZIF-4 is strikingly complicated when compared with that of the previously investigated, closely related ZIF-62 and demonstrates the ability to traverse complex energy landscapes of metal-organic systems using the combined application of pressure and temperature
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