281 research outputs found
Spatial Variation of Genetic Diversity in Drosophila Species from Two Different South American Environments
Theoretical determination of the properties of Methanesulfinic and Methanesulfonic acids
Solid-liquid phase behavior of eutectic solvents containing sugar alcohols
Mixtures of carbohydrates are often reported in the literature as deep eutectic solvents yet, in most cases, their solid–liquid phase diagrams are poorly characterized and no evidence is available to validate this classification. In this work, the phase diagrams of the binary systems composed of the sugar alcohols mannitol or maltitol and meso-erythritol, xylitol, or sorbitol, were experimentally determined. The results obtained reveal that these systems have a thermodynamic ideal behavior, questioning their classification as deep eutectic solvents and showing that intermolecular hydrogen bonding between the components of a mixture is not a sufficient condition to prepare deep eutectic solvents. The phase diagrams of the systems composed of mannitol or maltitol and cholinium chloride were also measured in this work. In sharp contrast to the mixtures composed solely by sugar alcohols, and unlike numerous other choline-based eutectic systems reported in the literature, these systems revealed significant deviations to thermodynamic ideality, leading to significant melting temperature depressions. The Cl-OH interaction between cholinium chloride and the sugar alcohols is identified as the main reason for these deviations to ideality, paving the way for the rational choice of hydrogen bond acceptors to prepare deep eutectic solvents.This work was developed within the scope of the project
CICECO-Aveiro Institute of Materials, UIDB/50011/2020 & UIDP/50011/2020, and CIMO-Mountain Research Center,
UIDB/00690/2020, both financed by national funds through the
Portuguese Foundation for Science and Technology(FCT)/MCTES.
L.P.S. acknowledges FCT for her PhD grant (SFRH/BD/135976/2018).info:eu-repo/semantics/publishedVersio
Tetraalkylammonium Chlorides as Melting Point Depressants of Ionic Liquids
With the (re)advent of eutectic mixtures within the field of deep eutectic solvents, special attention has been given to the measurement of solid–liquid equilibrium (SLE) phase diagrams, supported by the relevant information they can provide on the molecular interactions and melting temperature depression of any given system. As such, this work investigates the SLE phase diagrams of mixtures between ionic liquids and tetraalkylammonium chlorides (methyl, ethyl, and propyl), with the goal of decreasing the melting temperature of ionic liquids and ammonium salts, thus, expanding their application scope. Results show that tetraalkylammonium salts exhibit negative deviations from thermodynamic ideality when mixed with ionic liquids, which are increased by increasing their alkyl chain length and are interpreted in terms of anion exchange mechanisms. In turn, this nonideality contributes greatly to depression of the melting point of the ionic liquids examined. Overall, this work demonstrates that the correct combination of tetraalkylammonium/ILs anions and cations can lead to significant melting point depressions in both species, thus creating new ionic liquid mixtures using an approach akin to that used to form deep eutectic solvents.This work was developed within the scope of the project CICECO-Aveiro Institute
of Materials, UIDB/50011/2020, UIDP/50011/2020 and LA/P/0006/2020, and CIMO (UIDB/00690/2020
and UIDP/00690/2020) and SusTEC (LA/P/0007/2021), financed by national funds through the FCT/MEC
(PIDDAC). L.P.S. acknowledges FCT for her Ph.D. Grant (SFRH/BD/135976/2018).info:eu-repo/semantics/publishedVersio
Eutectic mixtures based on polyalcohols as sustainable solvents: screening and characterization
Despite some promising potential applications of eutectic systems containing choline chloride ([Ch]Cl) and a polyalcohol, a detailed investigation of the thermodynamic behavior of these systems is still missing. In this work, the solid-liquid equilibria phase diagrams of binary systems containing [Ch]Cl and one from six different polyalcohols (ethylene glycol (EG), 1,3-propanediol, glycerol (Gly), meso-erythritol, xylitol, and sorbitol) were measured in the full composition. Except for the mixtures with Gly or EG, a quasi-ideal behavior in the [Ch]Cl solubility curve is observed. In the polyalcohol solubility curve, the mixtures present small negative deviations from ideality, except for [Ch]Cl + EG, which is slightly positive. The solid-liquid phase diagrams show a large liquid composition window, and not a fixed stoichiometry for the eutectic points, where the mixtures can be used as solvents close to, or below, room temperature. Aiming at their application, viscosities and densities were measured at the eutectic point in the temperature range from 278.15 to 373.15 K. All systems present densities and viscosities higher than water, which is directly related to the strong interactions between the components. Solvatochromic parameters were measured to characterize the solvents, and they show that solvent tunability can be achieved by varying the polyalcohol mole fraction.This work was developed within the scope of the project CICECO-Aveiro Institute of
Materials, UIDB/50011/2020 & UIDP/50011/2020, and CIMO-Mountain Research Center,
UIDB/00690/2020, both financed by national funds through the Portuguese Foundation for
Science and Technology/MCTES. The NMR spectrometers are part of the National NMR
Network (PTNMR) and are partially supported by Infrastructure Project Nº 022161 (cofinanced
by FEDER through COMPETE 2020, POCI and PORL and FCT through PIDDAC).
L.P.S. acknowledges FCT for her PhD grant (SFRH/BD/135976/2018).info:eu-repo/semantics/publishedVersio
Terpenes solubility in water and their environmental distribution
Terpenes and terpenoids belong to the largest and most diverse class of natural products. Due to the increasing importance of their applications and the emerging perception of their impact on the environment, the available physico-chemical characterization is insufficient. In this work the water solubility of geraniol, linalool, DL-citronellol, thymol, eugenol, carvacrol and p-cymene, in the temperature range from (298.15 to 323.15) K, and at atmospheric pressure, is studied. Due to the low solubility of these compounds a novel technique was adopted for their measurements and validated using the aqueous solubility data for sparingly soluble aromatic compounds. The thermodynamic properties of solution were derived from the experimental data at infinite dilution. It is shown that the solubility of terpenes in water is an endothermic process confirming the existence of UCST phase diagrams, and only for carvacrol and eugenol is entropically driven. The experimental information is shown in a two-dimensional chemical space diagram providing indications to their probable distribution in the environment once released.Thisworkwas developed in the scope of the project CICECO - Aveiro
Institute ofMaterials, POCI-01-0145-FEDER-007679, and Associate Laboratory
LSRE-LCM, POCI-01-0145-FEDER-006984, both funded by
FEDER under the PT2020 Partnership Agreement - Programa
Operacional Competitividade e Internacionalização (POCI) - and by national
funds through FCT - Fundação para a Ciência e a Tecnologia.
M.A.R.M acknowledges FCT for her PhD grant (SFRH/BD/87084/2012).info:eu-repo/semantics/publishedVersio
Mobile laboratories as an alternative to conventional remote laboratories
Remote laboratories have been playing an important role on the improvement of flexibility and the extent of
practical activities in teaching and learning activities in engineering and technology. However, the current remote laboratories model does not consider dynamic scenarios including collaboration, peer-to-peer labs and mobile labs. This paper presents a set of tools for creating collaborative online mobile laboratories that allow students to develop their own labs and share them with classmates and teachers. The approach used is compatible with the machine and network configurations that the target user has in schools and at home, and provides the retrieval of information for learning evaluation.info:eu-repo/semantics/publishedVersio
The role of the anion in imidazolium-based ionic liquids for fuel and terpenes processing
Abstract: The potentialities of methylimidazolium-based ionic liquids (ILs) as solvents were evaluated
for some relevant separation problems—terpene fractionation and fuel processing—studying
selectivities, capacities, and solvent performance indices. The activity coefficients at infinite dilution
of the solute (1) in the IL (3), g¥ 13, of 52 organic solutes were measured by inverse gas chromatography
over a temperature range of 333.2–453.2 K. The selected ILs are 1-butyl-3-methylimidazolium
hexafluorophosphate, [C4mim][PF6], and the equimolar mixture of [C4mim][PF6] and
1-butyl-3-methylimidazolium chloride, [C4mim]Cl. Generally, low polar solutes follow
g¥ 1,[C4mim]Cl > g¥ 1,[C4mim][PF6]+[C4mim]Cl > g¥ 1,[C4mim][PF6] while the opposite behavior is observed for alcohols and water. For citrus essential oil deterpenation, the results suggest that cations with long
alkyl chains, such as [C12mim]+, promote capacity, while selectivity depends on the solute polarity.
Promising results were obtained for the separation of several model mixtures relevant to fuel
industries using the equimolar mixture of [C4mim][PF6] and [C4mim]Cl. This work demonstrates
the importance of tailoring the polarity of the solvents, suggesting the use of ILs with mixed anions
as alternative solvents for the removal of aliphatic hydrocarbons and contaminants from fuels.This research was funded by the European Regional Development Fund (ERDF) through
the Regional Operational Program North 2020, within the scope of Project GreenHealth—Digital
strategies in biological assets to improve well-being and promote green health, Norte-01-0145-FEDER-
000042, to which A. Zambom is thankful for her grant. S. M. Vilas-Boas thanks FCT and the European
Social Fund (ESF) for his Ph.D. grant (SFRH/BD/138149/2018 and COVID/BD/152936/2022).
L.P.Silva acknowledges FCT for her Ph.D. grant (SFRH/BD/135976/2018).info:eu-repo/semantics/publishedVersio
Can cholinium chloride form eutectic solvents with organic chloride-based salts?
The high melting point of a large number of organic salts with potential ionic liquid-like properties,
hinders their applicability as solvents. Considering the success of cholinium chloride on lowering the
melting temperature of several substances and its success on forming deep eutectic solvents, this work
studies its mixing with organic chlorides to lower their melting points producing eutectic ionic liquids.
The solid-liquid phase diagrams for binary mixtures composed of cholinium chloride and ten organic
halides were experimentally measured. Surprisingly, cholinium chloride presented, for all these systems,
significant positive deviations from ideal liquid behaviour that restricted its ability to lower the melting
points of these mixtures. Only for mixtures with ammonium chloride, tetramethylammonium chloride,
bis(2-hydroxyethyl)dimethylammonium chloride or cholinium bromide was cholinium chloride able to
significantly lower the melting point of the mixture, but without reaching values close to room temperature
(298 K). For a better understanding of the results obtained, the solid-liquid phase diagrams of
four alkylammonium chloride-based mixtures were experimentally assessed and used to show that
these compounds are better than cholinium chloride at inducing negative deviations from ideality,
leading to greater melting point depressions.This work was developed in the scope of the project CICECO e
Aveiro Institute of Materials, POCI-01-0145-FEDER-007679
(Ref. FCT UID/CTM/50011/2013) and Associate Laboratory LSRELCM,
POCI-01-0145-FEDER-006984 (Ref. FCT UID/EQU/50020/2019), and project MultiBiorefinery (POCI-01-0145-FEDER-016403), all financed by national funds through the FCT/MCTES (PIDDAC) and when appropriate co-financed by FEDER under the
PT2020 Partnership Agreement. FCT is also acknowledged for
funding the project DeepBiorefinery (PTDC/AGRTEC/1191/2014).
The authors acknowledge the European Research Council under the
European Union's Seventh Framework Programme (FP7/
2007 e 2013)/ERC grant agreement no. 337753. M.A.R.M. acknowledges
financial support from NORTE-01-0145-FEDER-000006 -
funded by NORTE2020 through PT2020 and ERDF. L.P.S. acknowledges
FCT for her PhD grant (SFRH/BD/135976/2018).info:eu-repo/semantics/publishedVersio
Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: The quest for type v des
Mixtures of non-ionic compounds have been reported as DES but most are just ideal mixtures. In the thymol-menthol system, an abnormal strong interaction was identified stemming from the acidity difference of the phenolic and aliphatic hydroxyl groups. This type of interaction is found to be the key to prepare non-ionic DES, that may be classified as type V.This work was developed in the scope of the project CICECO –
Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (Ref.
FCT UID/CTM/50011/2019) and Associate Laboratory LSRE-LCM,
POCI-01-0145-FEDER-006984 (Ref. FCT UID/EQU/50020/2019),
and project MultiBiorefinery (POCI-01-0145-FEDER-016403), all
financed by national funds through the FCT/MCTES (PIDDAC)
and when appropriate co-financed by FEDER under the PT2020
Partnership Agreement.info:eu-repo/semantics/publishedVersio
- …