CO2 storage potential of basaltic rocks in Iceland and the oceanic ridges

AbstractIceland is the largest landmass found above sea level at the mid-ocean ridges, about 103,000 km2 mostly made of basaltic rocks (∼90%). Theoretically much of Iceland could be used for injection of CO2, fully dissolved in water. Most of the pore space in the older rocks is filled with secondary minerals, thus the young and porous basaltic formations, found within the active rift zone and covering about one third of Iceland, are the most feasible for carbon storage onshore.Studies on mineral storage of CO2 in basaltic rocks are still at an early stage. Therefore, natural analogues are important for gaining a better understanding of CO2 fixation in basaltic rocks. Volcanic geothermal systems serve as an applicable analogue since the systems receive considerable amounts of CO2 from magma in the roots of the systems. Wiese et al. [1] quantified the amount and spatial distribution of CO2 stored as calcite within the bedrock of three active geothermal systems in Iceland. The results from this study reveal a large storage potential of basaltic rocks and can be used as a guideline for the theoretical potential of CO2 storage in basaltic formations. The largest storage potential lies offshore, with long-term advantages for safe and secure CO2 storage in the mid-ocean ridges. The theoretical mineral CO2 storage capacity of the ocean ridges, using the Icelandic analogue, is orders of magnitude larger than the anticipated release of CO2 caused by burning of all fossil fuel on Earth

The chemistry and saturation states of subsurface fluids during the in situ mineralisation of CO2 and H2S at the CarbFix site in SW-Iceland

In situ carbonation of basaltic rocks could provide a long-term carbon storage solution, which is essential for the success and public acceptance of carbon storage. To demonstrate the viability of this carbon storage solution, 175 tonnes (t) of pure CO2 and 73 tonnes (t) of a 75% CO2-24% H2S-1% H2-gas mixture were sequentially injected into basaltic rocks at the CarbFix site at Hellisheidi, SW-Iceland from January to August 2012. This paper reports the chemistry and saturation states with respect to potential secondary minerals of sub-surface fluids sampled prior to, during, and after the injections. All gases were dissolved in water during their injection into permeable basalts located at 500–800 m depth with temperatures ranging from 20 to 50 °C. A pH decrease and dissolved inorganic carbon (DIC) increase was observed in the first monitoring well, HN-04, about two weeks after each injection began. At storage reservoir target depth, this diverted monitoring well is located ∼125 m downstream from the injection well. A significant increase in H2S concentration, however, was not observed after the second injection. Sampled fluids from the HN-04 well show a rapid increase in Ca, Mg, and Fe concentration during the injections with a gradual decline in the following months. Calculations indicate that the sampled fluids are saturated with respect to siderite about four weeks after the injections began, and these fluids attained calcite saturation about three months after each injection. Pyrite is supersaturated prior to and during the mixed gas injection and in the following months. In July 2013, the HN-04 fluid sampling pump broke down due to calcite precipitation, verifying the carbonation of the injected CO2. Mass balance calculations, based on the recovery of non-reactive tracers co-injected into the subsurface together with the acid-gases, confirm that more than 95% of the CO2 injected into the subsurface was mineralised within a year, and essentially all of the injected H2S was mineralised within four months of its injection. These results demonstrate the viability of the in situ mineralisation of these gases in basaltic rocks as a long-term and safe storage solution for CO2 and H2S

Rapid solubility and mineral storage of CO2 in basalt

The long-term security of geologic carbon storage is critical to its success and public acceptance. Much of the security risk associated with geological carbon storage stems from its buoyancy. Gaseous and supercritical CO2 are less dense than formation waters, providing a driving force for it to escape back to the surface. This buoyancy can be eliminated by the dissolution of CO2 into water prior to, or during its injection into the subsurface. The dissolution makes it possible to inject into fractured rocks and further enhance mineral storage of CO2 especially if injected into silicate rocks rich in divalent metal cations such as basalts and ultra-mafic rocks. We have demonstrated the dissolution of CO2 into water during its injection into basalt leading to its geologic solubility storage in less than five minutes and potential geologic mineral storage within few years after injection [1–3]. The storage potential of CO2 within basaltic rocks is enormous. All the carbon released from burning of all fossil fuel on Earth, 5000 GtC, can theoretically be stored in basaltic rocks [4]

Mineral carbonation of CO2

A survey of the global carbon reservoirs suggests that the most stable, long-term storage mechanism for atmospheric CO2 is the formation of carbonate minerals such as calcite, dolomite and magnesite. The feasibility is demonstrated by the proportion of terrestrial carbon bound in these minerals: at least 40,000 times more carbon is present in carbonate rocks than in the atmosphere. Atmospheric carbon can be transformed into carbonate minerals either ex situ, as part of an industrial process, or in situ, by injection into geological formations where the elements required for carbonate-mineral formation are present. Many challenges in mineral carbonation remain to be resolved. They include overcoming the slow kinetics of mineral-fluid reactions, dealing with the large volume of source material required and reducing the energy needed to hasten the carbonation process. To address these challenges, several pilot studies have been launched, including the CarbFix program in Iceland. The aim of CarbFix is to inject CO2 into permeable basaltic rocks in an attempt to form carbonate minerals directly through a coupled dissolution-precipitation process

Role of river-suspended material in the global carbon cycle

International audienceThe reaction of Ca derived from silicate weathering with CO2 in the world's oceans to form carbonate minerals is a critical step in long-term climate moderation. Ca is delivered to the oceans primarily via rivers, where it is transported either as dissolved species or within suspended material. The relative importance for climate moderation of riverine dissolved Ca vs. suspended Ca transport stems from the total Ca flux and its climate dependence. Data in the literature suggest that, within uncertainty, global riverine dissolved Ca flux is equal to suspended material Ca flux. To determine how these fluxes depend on temperature and rainfall, a 40 yr field study was performed on 4 catchments in northeastern Iceland: Jökulsá á Fjöllum at Grímsstadir, Jökulsá á Dal at Brú, Jökulsá á Dal at Hjardarhagi, and Jökulsá í Fljótsdal at Hóll. Suspended material Ca flux depends more on seasonal and annual temperatures and rainfall variation than does dissolved Ca flux in all four catchments. For example, the average difference between the annual maximum and minimum daily suspended Ca flux for the Jökulsá á Dal at Brú is four orders of magnitude, whereas the difference for dissolved Ca flux is only approximately one order of magnitude. Similarly, the annual dissolved Ca flux for this river varies by a factor of 2.6, whereas its annual suspended Ca flux varies by a factor of 7.1. Because suspended material Ca flux is more dependent on climate, it provides a stronger negative feedback for stabilizing Earth's temperature through the greenhouse effect

Vitesses d'altération expérimentales des silicates d'aluminium

TOULOUSE3-BU Sciences (315552104) / SudocSudocFranceF

The effect of crystallinity on dissolution rates and CO2 consumption capacity of silicates

International audienceComparison of measured far-from-equilibrium dissolution rates of natural glasses and silicate minerals at 25 °C and pH 4 reveals the systematic effects of crystallinity and elemental composition on these rates. Rates for both minerals and glasses decrease with increasing Si:O ratio, but glass dissolution rates are faster than corresponding mineral rates. The difference between glass and mineral dissolution rates increases with increasing Si:O ratio; ultra-mafic glasses (Si:O ? 0.28) dissolve at similar rates as correspondingly compositioned minerals, but Si-rich glasses such as rhyolite (Si:O ? 0.40) dissolve ?1.6 orders of magnitude faster than corresponding minerals. This behaviour is interpreted to stem from the effect of Si O polymerisation on silicate dissolution rates. The rate controlling step of dissolution for silicate minerals and glasses for which Si:O > 0.28 is the breaking of Si O bonds. Owing to rapid quenching, natural glasses will exhibit less polymerisation and less ordering of Si O bonds than minerals, making them less resistant to dissolution. Dissolution rates summarized in this study are used to determine the Ca release rates of natural rocks at far-from-equilibrium conditions, which in turn are used to estimate their CO2 consumption capacity. Results indicate that Ca release rates for glasses are faster than those of corresponding rocks. This difference is, however, significantly less than the corresponding difference between glass and mineral bulk dissolution rates. This is due to the presence of Ca in relatively reactive minerals. In both cases, Ca release rates increase by ?two orders of magnitude from high to low Si:O ratios (e.g., from granite to gabbro or from rhyolitic to basaltic glass), illustrating the important role of Si-poor silicates in the long-term global CO2 cycle