Electronic Tuning of Mixed Quinoidal‐Aromatic Conjugated Polyelectrolytes: Direct Ionic Substitution on Polymer Main‐Chains

The synthesis of conjugated polymers with ionic substituents directly bound to their main chain repeat units is a strategy for generating strongly electron-accepting conjugated polyelectrolytes, as demonstrated through the synthesis of a series of ionic azaquinodimethane (iAQM) compounds. The introduction of cationic substituents onto the quinoidal para-azaquinodimethane (AQM) core gives rise to a strongly electron-accepting building block, which can be employed in the synthesis of ionic small molecules and conjugated polyelectrolytes (CPEs). Electrochemical measurements alongside theoretical calculations indicate notably low-lying LUMO values for the iAQMs. The optical band gaps measured for these compounds are highly tunable based on structure, ranging from 2.30 eV in small molecules down to 1.22 eV in polymers. The iAQM small molecules and CPEs showcase the band gap reduction effects of combining the donor-acceptor strategy with the bond-length alternation reduction strategy. As a demonstration of their utility, the iAQM CPEs so generated were used as active agents in photothermal therapy

Direct CP Violation in Angular Distribution of B→J/ψK∗B\to J/\psi K^{*} Decays

We show that the study of certain observables in the angular distribution in $B\to J/\psi K^*$ provide clear test for CP vioaltion beyond the Standard Model. These observables vanish in SM, but in models beyond SM some of them can be large enough to be measured at B factories.Comment: 7 pages, Revte

Group-Based Parent Training Interventions for Parents of Children with Autism Spectrum Disorders: a Literature Review

© 2018, Springer Science+Business Media, LLC, part of Springer Nature. Parents of children with autism spectrum disorders should have access to interventions to help them understand and support their child. This literature review examines the existing evidence for group-based parent training interventions that support parents of children with autism. From the literature, core intervention processes and outcomes are identified and include parenting and parent behaviour, parent health, child behaviour and peer and social support. Results show a positive trend for intervention effectiveness, but findings are limited by low-quality studies and heterogeneity of intervention content, outcomes and outcome measurement. Future research should focus on specifying effective intervention ingredients and modes of delivery, consistent and reliable outcome measurement, and improving methodological rigour to build a more robust evidence base

Study of the beam profile and position instability of a post-accelerated pseudospark-sourced electron beam

A pseudospark-sourced electron beam is a promising candidate for driving a THz millimeter wave radiation source. However, the physics governing the electron beam density profile and the beam center deviation from the axis of the structure, which may be caused by the randomness in the pseudospark discharge process, remains still unclear especially for the high energy component of the pseudospark-sourced electron beam which is usually non-mono-energetic. It is essential to study the electron beam density profile and the beam center position distribution for optimizing the pseudospark discharge configuration. In this paper, images of some single-shot electron beam pulses have been captured using a 50 μm thickness stopping copper foil and a phosphor screen coated with P47 scintillator to study the electron beam density profile and the beam center position distribution of the high energy component of the electron beam. The experiments have been carried out on two pseudospark discharge configurations with two different size hollow cathode cavities. The influence of the cathode aperture of each configuration has also been studied according to the beam images. Experimental results show that the beam profile of the high energy component has a Lorentzian distribution and is much smaller than the axial aperture size with the beam centers dispersing within a certain range around the axis of the discharge structure. The pseudospark-sourced electron beam with the larger hollow cathode cavity shows smaller full width at half maximum (FWHM) radius and a more concentrated beam center distribution

Influence of the electrode gap separation on the pseudospark-sourced electron beam generation

Pseudospark-sourced electron beam is a self-focused intense electron beam which can propagate without any external focusing magnetic field. This electron beam can drive a beam-wave interaction directly or after being post-accelerated. It is especially suitable for terahertz (THz) radiation generation due to the ability of a pseudospark discharge to produce small size in the micron range and very high current density and bright electron beams. In this paper, a single-gap pseudospark discharge chamber has been built and tested with several electrode gap separations to explore the dependence of the pseudospark-sourced electron beam current on the discharge voltage and the electrode gap separation. Experimental results show that the beam pulses have similar pulse width and delay time from the distinct drop of the applied voltage for smaller electrode gap separations but longer delay time for the largest gap separation used in the experiment. It has been found that the electron beam only starts to occur when the charging voltage is above a certain value, which is defined as the starting voltage of the electron beam. The starting voltage is different for different electrode gap separations and decreases with increasing electrode gap separation in our pseudospark discharge configuration. The electron beam current increases with the increasing discharge voltage following two tendencies. Under the same discharge voltage, the configuration with the larger electrode gap separation will generate higher electron beam current. When the discharge voltage is higher than 10 kV, the beam current generated at the electrode gap separation of 17.0 mm, is much higher than that generated at smaller gap separations. The ionization of the neutral gas in the main gap is inferred to contribute more to the current increase with increasing electrode gap separation

Advanced post-acceleration methodology for pseudospark-sourced electron beam

During its conductive phase, a pseudospark discharge is able to generate a low energy electron beam with a higher combined current density and brightness compared with electron beams formed from any other known type of electron source. In this paper, a configuration is proposed to post-accelerate an electron beam extracted from a single-gap pseudospark discharge cavity in order to achieve high quality high energy intense electron beams. The major advancement is that the triggering of the pseudospark discharge, the pseudospark discharge itself, and the post-accelerating of the electron beam are all driven by a single high voltage pulse. An electron beam with a beam current of ∼20 A, beam voltage of 40 kV, and duration of ∼180 ns has been generated using this structure. The beam energy can be adjusted through adjusting the amplitude of the voltage pulse and the operating voltage of the whole structure, which can be varied from 24 to 50 kV with an efficient triggering method under fixed gas pressure below ∼10 Pa

The seismic performance of end-perforated RC frame beams strengthened with CFRP sheets

This paperpresents eight tests on the end-perforated RC frame beams with the different sizes of perforations and arrangement styles of strengthening carbon fibre(CFRP) sheetssubjected to hybrid load-displacement control loading condition. The research focuseson the assessment of beams’ seismic performance. The ultimate load resistance, hysteretic performance, energy dissipation capability, ductility and stiffness degradation of the end-perforated RC frame beams with and without strengthening CFRPsheets have been investigated. The test results show that the beams strengthened with CFRP sheets can effectively improve their seismic performances. The perforation size of abeam has significant influence on itsseismic behaviour. With the increase of hole diameter, the hysteresis performance, energy dissipation capacity and ductility of beams are decreased considerably.This research was supported by the Jiangsu Collaborative Innovation Centre for Building Energy Saving and Construction Technology (NO. SJXTQ 1613), Natural Science Foundation of Jiangsu Province (Grant No. BK20170282) and the Research Fund for Doctoral Program of Higher Education of China (Grant No. 2016M601911). The authors gratefully appreciate the supports