High Uptake and Fast Transportation of LiPF6 in Porous Aromatic Framework for Solid‐State Li‐Ion Batteries

Solid‐state Li‐ion batteries (SSLIBs) have recently attracted substantial attention from scientists for the advantages of better safety performance. However, there are still several key challenges in SSLIBs that need to be addressed, such as low energy density, poor thermal stability or cycle stability, and large interface resistance. This contribution introduces a novel SSLIB with a porous aromatic framework (PAF‐1) accommodating LiPF6 that was used as the solid‐state electrolyte (SSE) replacing the liquid electrolyte and diaphragm of traditional Li‐ion batteries. The charge, discharge capacity, rate performance and cycle stability of the SSLIB were remarkably enhanced

High Uptake and Fast Transportation of LiPF6 in a Porous Aromatic Framework for Solid-State Li-Ion Batteries

Solid-state Li-ion batteries (SSLIBs) have recently attracted substantial attention from scientists for the advantages of better safety performance. However, there are still several key challenges in SSLIBs that need to be addressed, such as low energy density, poor thermal stability or cycle stability, and large interface resistance. This contribution introduces a novel SSLIB with a porous aromatic framework (PAF-1) accommodating LiPF6 that was used as the solid-state electrolyte (SSE) replacing the liquid electrolyte and diaphragm of traditional Li-ion batteries. The charge, discharge capacity, rate performance and cycle stability of the SSLIB were remarkably enhanced

A 3D Organically Synthesised Porous Carbon Material for Lithium Ion Batteries

We report the first organically synthesized sp–sp3 hybridized porous carbon, OSPC‐1. This new carbon shows electron conductivity, high porosity, the highest uptake of lithium ions of any carbon material to‐date, and the ability to inhibit dangerous lithium dendrite formation. The new carbon exhibits exceptional potential as anode material for lithium‐ion batteries (LIBs) with high capacity, excellent rate capability, long cycle life, and potential for improved safety performance

Targeted synthesis of an electroactive organic framework

A new strategy for targeted design and synthesis of an electroactive microporous organic molecular sieve (JUC-Z2) is described. Experiment demonstrated that such a targeted synthesis approach to achieve phenyl-phenyl coupling was a controllable process and predominately generated two-dimensional polymer sheets, significantly different from the traditional chemical or electrochemical oxidation methods to prepare conducting polymers. Successive self-assembly leads to a lamellar organic framework comprised of stacked polymer sheets with an hcb topology. JUC-Z2 was found to have a well-defined uniform micropore distribution (similar to 1.2 nm), a large surface area (BET = 2081 m(2) g(-1)) and high physicochemical stability (> 440 degrees C). After doping with I(2), JUC-Z2 exhibits typical p-type semiconductive properties. As the first example of an electroactive organic framework, JUC-Z2 possesses a unique ability of electrochemical ion recognition, arising from the synergistic function of the uniform micropores and the N-atom redox site.State Basic Research Project[2011CB808703]; NSFC[91022030, 20771041, 20773101, 20833005]; "111'' project[B07016]; Ministry of Science and Technology[2006DFA41190]; Jilin Science and Technology Department[20106021

The Influence of Audio-Visual Interactions on Psychological Responses of Young People in Urban Green Areas: A Case Study in Two Parks in China

Audio-visual interactions in green spaces are important for mental health and wellbeing. However, the influence of audio-visual interactions on psychological responses is still less clear. This study introduced a new method, namely the audio-visual walk (AV-walk), to obtain data on the audio-visual context, audio-visual experiences, and psychological responses in two typical parks, namely Cloves Park and Music Park in Harbin, China. Some interesting results are as follows: First, based on Pearson’s correlation analysis, sound pressure level and roughness were significantly correlated with psychological responses in Cloves Park (p < 0.05). Second, the results of stepwise regression models showed the impact intensity of acoustic comfort was 1.64−1.68 times higher than that of visual comfort on psychological responses of emotion dimension, while visual comfort was 1.35−1.37 times higher than acoustic comfort on psychological responses of cognition dimension in Music Park. In addition, an orthogonal analysis diagram explained the influence of audio-visual interactions on psychological responses of young people. The audio-visual context located beside the waterscape with a relatively higher level of acoustic and visual comfort was the most cheerful (2.60), relaxed (2.45), and energetic (2.05), while the audio-visual context close to an urban built environment tended to be both acoustically and visually uncomfortable, and the psychological state was decreased to the most depressed (−0.25), anxious (−0.75), fatigued (−1.13) and distracted (−1.13)

Porous Organic Materials:Strategic Design and Structure-Function Correlation

Porous organic materials have garnered colossal interest with the scientific fraternity due to their excellent gas sorption performances, catalytic abilities, energy storage capacities, and other intriguing applications. This review encompasses the recent significant breakthroughs and the conventional functions and practices in the field of porous organic materials to find useful applications and imparts a comprehensive understanding of the strategic evolution of the design and synthetic approaches of porous organic materials with tunable characteristics. We present an exhaustive analysis of the design strategies with special emphasis on the topologies of crystalline and amorphous porous organic materials. In addition to elucidating the structure–function correlation and state-of-the-art applications of porous organic materials, we address the challenges and restrictions that prevent us from realizing porous organic materials with tailored structures and properties for useful applications

Two-Dimensional COF–Three-Dimensional MOF Dual-Layer Membranes with Unprecedentedly High H 2 /CO 2 Selectivity and Ultrahigh Gas Permeabilities

International audienceComposite membranes embodying multilayered architecture have been on an uptrend to tap the synergy between different materials to attain new heights in gas separation performance. In the light of sustainable materials research, covalent organic frameworks (COFs) and metal–organic frameworks (MOFs) have emerged as cutting-edge platforms for molecular-sieving membranes owing to their phenomenal surface areas, ultrahigh porosities, and precise control over chemical functionalities. In this study, we report for the first time a three-dimensional (3D) MOF-mediated strategy where a specially designed MOF film provides the binding sites along the vertical direction to anchor the two-dimensional (2D) COF structural building units. The strong chemical bonding between the 3D MOF and 2D COF provides a new outlook to fabricate 2D COF-based composite membranes. The π-stacked columns of 2D H2P-DHPh COF that can contribute to direct pathways for gas transport render the resulting membrane incredibly promising for high-flux gas separation. Besides, the chemical synergy between the MOF and COF endows the thus-developed H2P-DHPh COF–UiO-66 composite membrane with unprecedented H2/CO2 gas mixture selectivity (32.9) as well as ultrahigh H2 (108 341.3 Barrer) and CO2 permeabilities, which significantly outperform the present Robeson upper bound and polymer membranes hitherto reporte

Aligned High Density Semi‐Conductive Ultra‐Small Single‐Walled Carbon Nanotubes

International audienc