5,883 research outputs found

    Onset of slow dynamics in difluorotetrachloroethane glassy crystal

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    Complementary Neutron Spin Echo and X-ray experiments and Molecular Dynamics simulations have been performed on difluorotetrachloroethane (CFCl2-CFCl2) glassy crystal. Static, single-molecule reorientational dynamics and collective dynamics properties are investigated. The orientational disorder is characterized at different temperatures and a change in nature of rotational dynamics is observed. We show that dynamics can be described by some scaling predictions of the Mode Coupling Theory (MCT) and a critical temperature TcT_{c} is determined. Our results also confirm the strong analogy between molecular liquids and plastic crystals for which α\alpha-relaxation times and non-ergodicity parameters are controlled by the non trivial static correlations as predicted by MCT

    Longitudinal patterns in an Arkansas River Valley stream: an Application of the River Continuum Concept

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    The River Continuum Concept (RCC) provides the framework for studying how lotic ecosystems vary from headwater streams to large rivers. The RCC was developed in streams in eastern deciduous forests of North America, but watershed characteristics and land uses differ across ecoregions, presenting unique opportunities to study how predictions of the RCC may differ across regions. Additionally, RCC predictions may vary due to the influence of fishes, but few studies have used fish taxa as a metric for evaluating predictions of the RCC. Our goal was to determine if RCC predictions for stream orders 1 through 5 were supported by primary producer, macroinvertebrate, and fish communities in Cadron Creek of the Arkansas River Valley. We sampled chlorophyll a, macroinvertebrates, and fishes at five stream reaches across a gradient of watershed size. Contrary to RCC predictions, chlorophyll a did not increase in concentration with catchment size. As the RCC predicts, fish and macroinvertebrate diversity increased with catchment size. Shredding and collecting macroinvertebrate taxa supported RCC predictions, respectively decreasing and increasing in composition as catchment area increased. Herbivorous and predaceous fish did not follow RCC predictions; however, surface-water column feeding fish were abundant at all sites as predicted. We hypothesize some predictions of the RCC were not supported in headwater reaches of this system due to regional differences in watershed characteristics and altered resource availability due to land use surrounding sampling sites

    Estuary environmental flows assessment methodology for Victoria

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    This report sets out a method to determine the environmental water requirements of estuaries in Victoria. The estuary environmental flows assessment method (EEFAM) is a standard methodology which can be applied consistently across Victorian estuaries.The primary objective of EEFAM is to define a flow regime to maintain or enhance the ecological health of an estuary. The method is used to inform Victorian water resource planning processes.The output of EEFAM is a recommended flow regime for estuaries. This recommendation is developed from the known dependence of the estuary’s flora, fauna, biogeochemical and geomorphological features on the flow regime. EEFAM is an evidence-based methodology. This bottom-up or ‘building block’ approach conforms to the asset-based approach of the Victorian River Health Strategy and regional river health strategies.EEFAM is based on and expands on FLOWS, the Victorian method for determining environmental water requirements in rivers. The list of tasks has been modified and re-ordered in EEFAM to reflect environmental and management issues specific to estuaries. EEFAM and FLOWS can be appliedsimultaneously to a river and its estuary as part of a whole-of-system approach to environmental flow requirements. Like the FLOWS method, EEFAM is modular, and additional components can be readily incorporated

    Estuary environmental flows assessment methodology : final specification report

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    This report provides a consistent and systematic approach to the determination of environmental water requirements for estuaries in Victoria.Victoria&rsquo;s limited water resources are subject to competing demands. These demands, including town water supplies and irrigation requirements, often deplete the flow entering estuaries and put their environmental values at risk.The Estuary Environmental Flows Assessment Methodology (EEFAM) is a standard methodology which can be applied in a consistent manner across all Victorian estuaries, according to their priority. It is not anticipated that this method would be used for the Gippsland Lakes or Port Phillip or Western Port Bay.<br /

    Random Sequential Adsorption: From Continuum to Lattice and Pre-Patterned Substrates

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    The random sequential adsorption (RSA) model has served as a paradigm for diverse phenomena in physical chemistry, as well as in other areas such as biology, ecology, and sociology. In the present work, we survey aspects of the RSA model with emphasis on the approach to and properties of jammed states obtained for large times in continuum deposition versus that on lattice substrates, and on pre-patterned surfaces. The latter model has been of recent interest in the context of efforts to use pre-patterning as a tool to improve selfassembly in micro- and nanoscale surface structure engineering

    Realization of logically labeled effective pure states for bulk quantum computation

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    We report the first use of "logical labeling" to perform a quantum computation with a room-temperature bulk system. This method entails the selection of a subsystem which behaves as if it were at zero temperature - except for a decrease in signal strength - conditioned upon the state of the remaining system. No averaging over differently prepared molecules is required. In order to test this concept, we execute a quantum search algorithm in a subspace of two nuclear spins, labeled by a third spin, using solution nuclear magnetic resonance (NMR), and employing a novel choice of reference frame to uncouple nuclei.Comment: PRL 83, 3085 (1999). Small changes made to improve readability and remove ambiguitie

    Experimental Realization of A Two Bit Phase Damping Quantum Code

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    Using nuclear magnetic resonance techniques, we experimentally investigated the effects of applying a two bit phase error detection code to preserve quantum information in nuclear spin systems. Input states were stored with and without coding, and the resulting output states were compared with the originals and with each other. The theoretically expected result, net reduction of distortion and conditional error probabilities to second order, was indeed observed, despite imperfect coding operations which increased the error probabilities by approximately 5%. Systematic study of the deviations from the ideal behavior provided quantitative measures of different sources of error, and good agreement was found with a numerical model. Theoretical questions in quantum error correction in bulk nuclear spin systems including fidelity measures, signal strength and syndrome measurements are discussed.Comment: 21 pages, 17 figures, mypsfig2, revtex. Minor changes made to appear in PR
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