Simulation of emission spectra of transition-metal dichalcogenide monolayers with the multimode Brownian oscillator model

The multimode Brownian oscillator model is employed to simulate the emission spectra of transition metal dichalcogenide monolayers. Good agreement is obtained between measured and simulated photoluminescence spectra of WSe2, WS2, MoSe2 and MoS2 at various temperatures. The Huang-Rhys factor extracted from the model can be associated with that from the modified semi-empirical Varshni equation at high temperatures. Individual mechanisms leading to the unique temperature-dependent emission spectra of those TMDs are validated by the MBO fitting, while it is in turn confirmed that the MBO analysis is an effective method for studying the optical properties of TMD monolayers. Parameters extractd from the MBO fitting can be used to explore exciton-photon-phonon dynamics of TMDs in a more comprehensive model

MEMS 411: Portable Bridge Crane with Pulleys

The bridge crane demonstrates dynamics behavior that the flexible mode has a natural frequency depending on the string length. In this project, a portable bridge crane is designed and made to demonstrate this dynamical phenomena by changing speed and string length. The portable bridge crane requires a light mass and a small size. At the same time, because it needs to be observed in a two-dimensional plane, the trolley must be able to move horizontally on a bridge with tracks, and the speed of the trolley needs to be controlled by a speed controllable motor. The crane needs to suspend a weight of 1 kg to demonstrate the change in natural frequency. The length of the rope needs to be adjustable. In addition, in order to ensure the stability of the instrument, it is necessary to reduce the impact force of the collision when the trolley hits the ends of the rail. Therefore, a soft stop is necessary to stop the motion of the cart before the collision at the end. In this way, the stability of the structure can be guaranteed in order to avoid tipping due to collision. Our portable bridge crane will demonstrate the effect of changing the speed and the string length on the natural frequency

Exciton Dynamics and Time-Resolved Fluorescence in Nanocavity-Integrated Monolayers of Transition-Metal Dichalcogenides

We have developed an ab-initio-based fully-quantum numerically-accurate methodology for the simulation of the exciton dynamics and time- and frequency-resolved fluorescence spectra of the cavity-controlled two-dimensional materials at finite temperature and applied this methodology to the single-layer WSe2 system. This allowed us to establish dynamical and spectroscopic signatures of the polaronic and polaritonic effects as well as uncover their characteristic timescales in the relevant range of temperatures

Expansion dynamics of a spherical Bose-Einstein condensate

We experimentally and theoretically observe the expansion behaviors of a spherical Bose-Einstein condensate. A rubidium condensate is produced in an isotropic optical dipole trap with an asphericity of 0.037. We measure the variation of the condensate size during the expansion process. The free expansion of the condensate is isotropic, which is different from that of the condensate usually produced in the anisotropic trap. The expansion in the short time is speeding and then after a long time the expansion velocity asymptotically approaches a constant value. We derive an analytic solution of the expansion behavior based on the spherical symmetry, allowing a quantitative comparison with the experimental measurement. The interaction energy of the condensate is gradually converted into the kinetic energy at the beginning of the expansion and the kinetic energy dominates after a long-time expansion. We obtain the interaction energy of the condensate in the trap by probing the expansion velocity, which is consistent with the theoretical prediction.Comment: 6 pages, 5 figure

In Situ Assembly of Ultrathin PtRh Nanowires to Graphene Nanosheets as Highly Efficient Electrocatalysts for the Oxidation of Ethanol

One-dimensional (1D) anisotropic platinum-based nanowires are promising electrocatalysts in polymer electrolyte membrane fuel cells owing to the inherent structural merits. Herein, we report an in situ growth of ultrathin PtRh nanowires (diameters of 2–3 nm) on graphene nanosheets via the oriented attachment pathway. Mechanistic studies reveal that graphene nanosheets play a critical role in the nucleation and growth of PtRh nanowires. The resulting hybrid of PtRh nanowire decorated graphene nanosheets shows outstanding activity and durability toward ethanol electro-oxidation. It exhibits a specific current density of 2.8 mA cm^–2 and a mass-normalized current density of 1 A mg^–1 metal, which are 5.4 and 3.1 times those of the state-of-the-art Pt/C catalyst, respectively. After 2000 cyclic tests, it maintains 86% of the initial electrochemically active surface area, which is larger than that of 63% obtained from the Pt/C catalyst. The superior performance is attributed to the combination of the advantageous 1D morphological motif with the synergistic effects of PtRh alloys and graphene nanosheet support