Large magnetocrystalline anisotropy in tetragonally distorted Heuslers: a systematic study

With a view to the design of hard magnets without rare earths we explore the possibility of large magnetocrystalline anisotropy energies in Heusler compounds that are unstable with respect to a tetragonal distortion. We consider the Heusler compounds Fe$_2$YZ with Y = (Ni, Co, Pt), and Co$_2$YZ with Y = (Ni, Fe, Pt) where, in both cases, Z = (Al, Ga, Ge, In, Sn). We find that for the Co$_2$NiZ, Co$_2$PtZ, and Fe$_2$PtZ families the cubic phase is always, at $T=0$, unstable with respect to a tetragonal distortion, while, in contrast, for the Fe$_2$NiZ and Fe$_2$CoZ families this is the case for only 2 compounds -- Fe$_2$CoGe and Fe$_2$CoSn. For all compounds in which a tetragonal distortion occurs we calculate the MAE finding remarkably large values for the Pt containing Heuslers, but also large values for a number of the other compounds (e.g. Co$_2$NiGa has an MAE of -2.11~MJ/m$^3$). The tendency to a tetragonal distortion we find to be strongly correlated with a high density of states at the Fermi level in the cubic phase. As a corollary to this fact we observe that upon doping compounds for which the cubic structure is stable such that the Fermi level enters a region of high DOS, a tetragonal distortion is induced and a correspondingly large value of the MAE is then observed.Comment: 8 pages, 5 figure

Ce(IV)-induced Reduction of Tl(III) by Hydrogen Peroxide

243-24

Thermoelectric Amplification of Phonons in Graphene

Amplification of acoustic phonons due to an external temperature gredient ($\nabla T$) in Graphene was studied theoretically. The threshold temperature gradient $(\nabla T)_0^{g}$ at which absorption switches over to amplification in Graphene was evaluated at various frequencies $\omega_q$ and temperatures $T$. For $T = 77K$ and frequency $\omega_q = 12THz$, $(\nabla T)_0^{g} = 0.37Km^{-1}$. The calculation was done in the regime at $ql >> 1$. The dependence of the normalized ($\Gamma/\Gamma_0$) on the frequency $\omega_q$ and the temperature gradient $(\nabla T/T)$ are evaluated numerically and presented graphically. The calculated $(\nabla T)_0^{g}$ for Graphene is lower than that obtained for homogeneous semiconductors ($n-InSb$) $(\nabla T)_0^{hom} \approx 10^3Kcm^{-1}$, Superlattices $(\nabla T)_0^{SL} = 384Kcm^{-1}$, Cylindrical Quantum Wire $(\nabla T)_0^{cqw} \approx 10^2Kcm^{-1}$. This makes Graphene a much better material for thermoelectric phonon amplifier.Comment: 12 Pages, 6 figure

High-soft to low-hard state transition in black hole X-ray binaries with GRMHD simulations

To understand the decaying phase of outbursts in the black hole (BH) X-ray binaries (BH-XRBs), we performed very long general relativistic magneto-hydrodynamic (GRMHD) simulations of a geometrically thin accretion disk around a Kerr BH with slowly rotating matter injected from outside. We thoroughly studied the flow properties, dynamical behavior of the accretion rate, magnetic flux rate, and jet properties during the temporal evolution. Due to the interaction between the thin disk and injected matter, the accretion flow near the BH goes through different phases. The sequence of phases is: soft state $\rightarrow$ soft-intermediate state $\rightarrow$ hard-intermediate state $\rightarrow$ hard state $\rightarrow$ quiescent state. For the accretion rate (and hence the luminosity) to decrease (as observed) in our model, the mass injection should not decay slower than angular momentum injection. We also observed quasi-periodic oscillations (QPOs) in the accretion flow. Throughout the evolution, we observed low-frequency QPOs (~10Hz) and high-frequency QPOs (\sim 200Hz). Our simple unified accretion flow model for state transitions is able to describe outbursts in BH-XRBs.Comment: 13 pages, 11 figures, Accepted for publication on Ap

Nuclear Breathing Mode in the Relativistic Mean Field Theory

The breathing-mode giant monopole resonance is studied within the framework of the relativistic mean-field (RMF) theory. Using a broad range of parameter sets, an analysis of constrained incompressibility and excitation energy of isoscalar monopole states in finite nuclei is performed. It is shown that the non-linear scalar self-interaction and the resulting surface properties influence the breathing-mode considerably. It is observed that dynamical surface properties respond differently in the RMF theory than in the Skyrme approach. A comparison is made with the incompressibility derived from the semi-infinite nuclear matter and with constrained nonrelativistic Skyrme Hartree-Fock calculaions.Comment: Latex (12 pages) and 3 figures (available upon request) J. Phys. G (in press

Modulating the water behavior, microstructure, and viscoelasticity of plasma-derived hydrogels by adding silica nanoparticles with tailored chemical and colloidal properties

The viscoelastic properties of hydrogels depend on the tridimensional polymeric structure and the behavior of the liquid confined in their pores. The objective here is to modulate these characteristics in plasma-derived hydrogels by the addition of glycidoxypropyl-silica nanoparticles. These nanoparticles exhibited a hydrodynamic average size between 105.4 − 151.0 nm and surface coverage with (3-Glycidoxypropyl) trimethoxysilane of 0–96 %. The reinforced hydrogels are porous networks with spherical nanoparticles homogeneously distributed into their walls. The silanol groups of silica increase four-fold humidity retention compared with the native hydrogel. This correlates with bound water &gt; 45 % on these reinforced hydrogels, in contrast with 75 % of free water on the native one (calculated from DSC in frozen hydrogels). The humidity stability can be also achieved in the hydrogel prepared with nanoparticles exhibiting 96 % organic coverage. Furthermore, this organic content promotes the microstructure chemical crosslinking, resulting in 3.9 and 1.6 higher Young's modulus compared with native and silica-reinforced hydrogels, respectively. The presence of glycidoxypropyl-silica nanoparticles in reinforced hydrogels modulated its viscoelasticity behavior, decreasing stress relaxation, which was explained using the generalized Maxwell-Wiechert model. In conclusion, novel organic-inorganic hybrid hydrogels based on plasma-derived ones and glycidoxypropyl-silica nanoparticles were developed. These nanoparticles are versatile and allow the production of hydrogels with improved viscoelastic behavior that also exhibits high water retention and morphological stability.</p