Synthesis and electronic properties of Ruddlesden-Popper strontium iridate epitaxial thin films stabilized by control of growth kinetics

We report on the selective fabrication of high-quality Sr$_2$IrO$_4$ and SrIrO$_3$ epitaxial thin films from a single polycrystalline Sr$_2$IrO$_4$ target by pulsed laser deposition. Using a combination of X-ray diffraction and photoemission spectroscopy characterizations, we discover that within a relatively narrow range of substrate temperature, the oxygen partial pressure plays a critical role in the cation stoichiometric ratio of the films, and triggers the stabilization of different Ruddlesden-Popper (RP) phases. Resonant X-ray absorption spectroscopy measurements taken at the Ir $L$-edge and the O $K$-edge demonstrate the presence of strong spin-orbit coupling, and reveal the electronic and orbital structures of both compounds. These results suggest that in addition to the conventional thermodynamics consideration, higher members of the Sr$_{n+1}$Ir$_n$O$_{3n+1}$ series can possibly be achieved by kinetic control away from the thermodynamic limit. These findings offer a new approach to the synthesis of ultra-thin films of the RP series of iridates and can be extended to other complex oxides with layered structure.Comment: 7 pages, 6 figure

Interface-engineered hole doping in Sr2IrO4/LaNiO3 heterostructure

The relativistic Mott insulator Sr2IrO4 driven by large spin-orbit interaction is known for the Jeff = 1/2 antiferromagnetic state which closely resembles the electronic structure of parent compounds of superconducting cuprates. Here, we report the realization of hole-doped Sr2IrO4 by means of interfacial charge transfer in Sr2IrO4/LaNiO3 heterostructures. X-ray photoelectron spectroscopy on Ir 4f edge along with the X-ray absorption spectroscopy at Ni L2 edge confirmed that 5d electrons from Ir sites are transferred onto Ni sites, leading to markedly electronic reconstruction at the interface. Although the Sr2IrO4/LaNiO3 heterostructure remains non-metallic, we reveal that the transport behavior is no longer described by the Mott variable range hopping mode, but by the Efros-Shklovskii model. These findings highlight a powerful utility of interfaces to realize emerging electronic states of the Ruddlesden-Popper phases of Ir-based oxides.Comment: 9 pages including 3 figures and reference

Royal Coachman (41CM111) An Early Middle Archaic Site along Cordova Creek in Comal County, Texas

The Royal Coachman site, 41CM111, is bisected by FM 306 near the highway’s eastern crossing of the Guadalupe River. Archeologists from the Texas Department of Transportation conducted extensive excavations at the site in 1980 and the Center for Archaeological Research carried out fieldwork related to geomorphic assessment of the deposits in 2002. The site contains at least three archeological components, an upper zone that may be of late Middle Archaic age and two commingled lower zones that are early Middle Archaic in age and contain a mix of Nolan/ Pandale and Bell-Andice/Early Triangular points. The deeper, more strongly manifested archeological components are associated with a dense burned rock sheet midden composed of two in situ features among a dense scatter of highly disturbed burned rock. Radiocarbon assays place this zone at between 5320–5880 years BP. The lithic assemblage is suggestive of tool manufacture and retooling activities and the projectile point collection is dominated by Early Triangular points and preforms. It is the recommendation of CAR that site 41CM111 warrants designation as a State Archeological Landmark and is eligible for listing on the National Register of Historic Places because of its significant contribution to a better understanding of the regional archeological record. We believe that these investigations have resulted in an appropriate level of work to evaluate the archeological property within the highway ROW and no further work is currently recommended. We also recommend that TxDOT consider avoidance as an option during future construction activities to avert impact to remaining deposits. In addition, if new ROW is acquired, additional work is warranted to determine the extent and significance of currently unidentified material. This work was conducted under Texas Antiquities Committee Permit No. 2807

Dynamics & Predictions in the Co-Event Interpretation

Sorkin has introduced a new, observer independent, interpretation of quantum mechanics that can give a successful realist account of the 'quantum microworld' as well as explaining how classicality emerges at the level of observable events for a range of systems including single time 'Copenhagen measurements'. This 'co-event interpretation' presents us with a new ontology, in which a single 'co-event' is real. A new ontology necessitates a review of the dynamical & predictive mechanism of a theory, and in this paper we begin the process by exploring means of expressing the dynamical and predictive content of histories theories in terms of co-events.Comment: 35 pages. Revised after refereein

Bayesian Conditioning, the Reflection Principle, and Quantum Decoherence

The probabilities a Bayesian agent assigns to a set of events typically change with time, for instance when the agent updates them in the light of new data. In this paper we address the question of how an agent's probabilities at different times are constrained by Dutch-book coherence. We review and attempt to clarify the argument that, although an agent is not forced by coherence to use the usual Bayesian conditioning rule to update his probabilities, coherence does require the agent's probabilities to satisfy van Fraassen's [1984] reflection principle (which entails a related constraint pointed out by Goldstein [1983]). We then exhibit the specialized assumption needed to recover Bayesian conditioning from an analogous reflection-style consideration. Bringing the argument to the context of quantum measurement theory, we show that "quantum decoherence" can be understood in purely personalist terms---quantum decoherence (as supposed in a von Neumann chain) is not a physical process at all, but an application of the reflection principle. From this point of view, the decoherence theory of Zeh, Zurek, and others as a story of quantum measurement has the plot turned exactly backward.Comment: 14 pages, written in memory of Itamar Pitowsk

Reasons and Means to Model Preferences as Incomplete

Literature involving preferences of artificial agents or human beings often assume their preferences can be represented using a complete transitive binary relation. Much has been written however on different models of preferences. We review some of the reasons that have been put forward to justify more complex modeling, and review some of the techniques that have been proposed to obtain models of such preferences

Coherent Control of Isotope Separation in HD+ Photodissociation by Strong Fields

The photodissociation of the HD+ molecular ion in intense short- pulsed linearly polarized laser fields is studied using a time- dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent superposition of the fundamental radiation with its second harmonic can lead to asymmetries in the fragment angular distributions, with significant differences between the hydrogen and deuterium distributions in the long wavelength domain where the permanent dipole is most efficient. This effect is used to induce an appreciable isotope separation.Comment: Physical Review Letters, 1995 (in press). 4 pages in revtex format, 3 uuencoded figures. Full postcript version available at: http://chemphys.weizmann.ac.il/~charron/prl.ps or ftp://scipion.ppm.u-psud.fr/coherent.control/prl.p

Non-additive probabilities and quantum logic in finite quantum systems

YesA quantum system Σ(d) with variables in Z(d) and with Hilbert space H(d), is considered. It is shown that the additivity relation of Kolmogorov probabilities, is not valid in the Birkhoff-von Neumann orthocomplemented modular lattice of subspaces L(d). A second lattice Λ(d) which is distributive and contains the subsystems of Σ(d) is also considered. It is shown that in this case also, the additivity relation of Kolmogorov probabilities is not valid. This suggests that a more general (than Kolmogorov) probability theory is needed, and here we adopt the Dempster-Shafer probability theory. In both of these lattices, there are sublattices which are Boolean algebras, and within these 'islands' quantum probabilities are additive