113 research outputs found
Antisite Domains in Double Perovskite Ferromagnets: Impact on Magnetotransport and Half-metallicity
Several double perovskite materials of the form A_2BB'O_6 exhibit high
ferromagnetic T_c, and significant low field magnetoresistance. They are also a
candidate source of spin polarized electrons. The potential usefulness of these
materials is, however, frustrated by mislocation of the B and B' ions, which do
not organise themselves in the ideal alternating structure. The result is a
strong dependence of physical properties on preparative conditions, reducing
the magnetization and destroying the half-metallicity. We provide the first
results on the impact of spatially correlated antisite disorder, as observed
experimentally, on the ferromagnetic double perovskites. The antisite domains
suppress magnetism and half-metallicity, as expected, but lead to a dramatic
enhancement of the low field magnetoresistance.Comment: 6 pages, pdflatex, EPL styl
Optimized Effective Potential Model for the Double Perovskites Sr2-xYxVMoO6 and Sr2-xYxVTcO6
In attempt to explore half-metallic properties of the double perovskites
Sr2-xYxVMoO6 and Sr2-xYxVTcO6, we construct an effective low-energy model,
which describes the behavior of the t2g-states of these compounds. All
parameters of such model are derived rigorously on the basis of
first-principles electronic structure calculations. In order to solve this
model we employ the optimized effective potential method and treat the
correlation interactions in the random phase approximation. Although
correlation interactions considerably reduce the intraatomic exchange splitting
in comparison with the Hartree-Fock method, this splitting still substantially
exceeds the typical values obtained in the local-spin-density approximation
(LSDA), which alters many predictions based on the LSDA. Our main results are
summarized as follows: (i) all ferromagnetic states are expected to be
half-metallic. However, their energies are generally higher than those of the
ferrimagnetic ordering between V- and Mo/Tc-sites (except Sr2VMoO6); (ii) all
ferrimagnetic states are metallic (except fully insulating Y2VTcO6) and no
half-metallic antiferromagnetism has been found; (iii) moreover, many of the
ferrimagnetic structures appear to be unstable with respect to the spin-spiral
alignment. Thus, the true magnetic ground state of the most of these systems is
expected to be more complex. In addition, we discuss several methodological
issues related to the nonuniqueness of the effective potential for the magnetic
half-metallic and insulating states.Comment: 15 pages, 9 figure
Spin-sensitive shape asymmetry of adatoms on noncollinear magnetic substrates
The spin-resolved density of states of Co atoms on a noncollinear magnetic support displays a distinct shape contrast, which is superimposed on the regular height contrast in spin-polarized scanning tunneling microscopy. The apparent atom height follows the well-known cosine dependence on the angle formed by the tip and adatom local magnetization directions, whereas the shape contrast exhibits a sine dependence. We explain this effect in terms of a noncollinear spin density induced by the substrate, which in our case is the spin spiral of the Mn monolayer on W(110). The two independent contrast channels, apparent height and shape, are identified with the Co magnetization projections onto two orthogonal axes. As a result, all components of the overall atom magnetic moment vector can be determined with a single spin-sensitive tip in the absence of an external magnetic field. This result should be general for any atom deposited on noncollinear magnetic layers
Scaling Development Finance for Our Common Future
The G-20 and the broader world community has committed to ambitious goals to close global infrastructure gaps, mitigate climate change, and advance the 2030 Agenda for development. We call on G20 leaders to task development finance institutions (DFIs) such as the development banks in member countries and the Multilateral Development Banks (MDBs) of which G-20 countries are members, to commit to scaling up resources by 25 percent, to calibrate new financing to international commitments to mitigate climate change and the 2030 agenda, and to work together as an inclusive system toward achieving those shared goals
Quantifying the leading role of the surface state in the Kondo effect of Co/Ag(111)
Using a combination of scanning tunneling spectroscopy and atomic lateral manipulation, we obtained a systematic variation of the Kondo temperature TK of Co atoms on Ag(111) as a function of the surface-state contribution to the total density of states at the atom adsorption site ρs. By sampling the TK of a Co atom on positions where ρs was spatially resolved beforehand, we obtain a nearly linear relationship between the magnitudes. We interpret the data on the basis of an Anderson model including orbital and spin degrees of freedom [SU(4)] in good agreement with the experimental findings. The fact that the onset of the surface band is near the Fermi level is crucial to finding the observed linear behavior. In light of this model, the quantitative analysis of the experimental data evidences that at least a quarter of the coupling of Co impurities with extended states takes place through the hybridization to surface states. This result is of fundamental relevance in the understanding of Kondo screening of magnetic impurities on noble-metal surfaces, where bulk and surface electronic states coexist.Fil: Moro Lagares, M.. Biology Centre of the Academy of Sciences of the Czech Republic; República Checa. Palacky University; República Checa. Universidad de Zaragoza. Instituto de Nanociencia de Aragón; EspañaFil: Fernández, Joaquín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Roura Bas, Pablo Gines. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Ibarra, M.R.. Universidad de Zaragoza; EspañaFil: Aligia, Armando Ángel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Serrate, D.. Universidad de Zaragoza; Españ
Effect of band-filling and structural distortions on the Curie temperature of Fe-Mo double perovkites
By means of high resolution neutron powder diffraction at low temperature we
have characterized the structural details of
() and () series of compounds. This study reveals a similar variation of the mean
bond-angle \FeOMo in both series. In contrast, the mean bond-distance \FeMoO\
increases with La but not with Ca substitution. Both series also present a
different evolution of the Curie temperature (), which raises in the La
series and slightly decreases in the Ca one. We thus conclude that the
enhancement of in the La series is due to the electron filling of the
conduction band and a concomitant rising of the density of states at the Fermi
level.Comment: Revtex, 4 Journal pages, 2 figures, 1 tabl
Direct epitaxial growth of polar Hf0.5 Zr0.5 O2 films on corundum
Single-phase epitaxial Hf0.5 Zr0.5 O2 films with non-centrosymmetric orthorhombic structure have been grown directly on electrode-free corundum (a-Al2 O3) substrates by pulsed laser deposition. A combination of high-resolution X-ray diffraction and X-ray absorption spectroscopy confirms the epitaxial growth of high-quality films belonging to the Pca21 space group, with 111] out-of-plane orientation. The surface of a 7-nm-thick sample exhibits an atomic step-terrace structure with a corrugation of the order of one atomic layer, as proved by atomic force microscopy. Scanning transmission electron microscopy reveals that it consists of grains with around 10 nm lateral size. The polar nature of this film has been corroborated by pyroelectric measurements. These results shed light on the mechanisms of the epitaxial stabilization of the ferroelectric phase of hafnia. © 2022 by the authors. Licensee MDPI, Basel, Switzerland
Effect of B-site Dopants on Magnetic and Transport Properties of LaSrCoRuO
Effect of Co, Ru and Cu substitution at B and B' sites on the magnetic and
transport properties of LaSrCoRuO have been investigated. All the doped
compositions crystallize in the monoclinic structure in the space group
indicating a double perovskite structure. While the magnetization and
conductivity increase in Co and Ru doped compounds, antiferromagnetism is seen
to strengthen in the Cu doped samples. These results are explained on the basis
of a competition between linear Co-O-Ru-O-Co and perpendicular Co-O-O-Co
antiferromagnetic interactions and due to formation of Ru-O-Ru ferromagnetic
networks
Phase diagram and influence of defects in the double perovskites
The phase diagram of the double perovskites of the type Sr_{2-x} La_x Fe Mo
O_6 is analyzed, with and without disorder due to antisites. In addition to an
homogeneous half metallic ferrimagnetic phase in the absence of doping and
disorder, we find antiferromagnetic phases at large dopings, and other
ferrimagnetic phases with lower saturation magnetization, in the presence of
disorder.Comment: 4 pages, 3 postscript figures, some errata correcte
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