5,146 research outputs found
Chemical and thermal structure of protoplanetary disks as observed with ALMA
We predict how protoplanetary disks around low-mass young stars would appear
in molecular lines observed with the ALMA interferometer. Our goal is to
identify those molecules and transitions that can be used to probe and
distinguish between chemical and physical disk structure and to define
necessary requirements for ALMA observations. Disk models with and without
vertical temperature gradient as well as with uniform abundances and those from
a chemical network are considered. As an example, we show the channel maps of
HCO(4-3) synthesized with a non-LTE line radiative transfer code and used
as an input to the GILDAS ALMA simulator to produce noise-added realistic
images. The channel maps reveal complex asymmetric patterns even for the model
with uniform abundances and no vertical thermal gradient. We find that a
spatial resolution of 0.2-0.5\arcsec and 0.5--10 hours of integration time
will be needed to disentangle large-scale temperature gradients and the
chemical stratification in disks in lines of abundant molecules.Comment: 4 pages, 3 figures, 1 table, accepted for publication to ApJ Letter
Block Copolymer at Nano-Patterned Surfaces
We present numerical calculations of lamellar phases of block copolymers at
patterned surfaces. We model symmetric di-block copolymer films forming
lamellar phases and the effect of geometrical and chemical surface patterning
on the alignment and orientation of lamellar phases. The calculations are done
within self-consistent field theory (SCFT), where the semi-implicit relaxation
scheme is used to solve the diffusion equation. Two specific set-ups, motivated
by recent experiments, are investigated. In the first, the film is placed on
top of a surface imprinted with long chemical stripes. The stripes interact
more favorably with one of the two blocks and induce a perpendicular
orientation in a large range of system parameters. However, the system is found
to be sensitive to its initial conditions, and sometimes gets trapped into a
metastable mixed state composed of domains in parallel and perpendicular
orientations. In a second set-up, we study the film structure and orientation
when it is pressed against a hard grooved mold. The mold surface prefers one of
the two components and this set-up is found to be superior for inducing a
perfect perpendicular lamellar orientation for a wide range of system
parameters
Active suppression of dephasing in Josephson-junction qubits
Simple majority code correcting dephasing errors by encoding a qubit of
information into physical qubits is studied quantitatively. We derive an
equation for quasicontinuous evolution of the density matrix of encoded quantum
information under the error correction procedure in the presence of dephasing
noise that in general can be correlated at different qubits. Specific design of
the Josephson-junction circuit implementing this scheme is suggested.Comment: 4 pages, 1 figur
On the Influence of Uncertainties in Chemical Reaction Rates on Results of the Astrochemical Modelling
With the chemical reaction rate database UMIST95 (Millar et al. 1997) we
analyze how uncertainties in rate constants of gas-phase chemical reactions
influence the modelling of molecular abundances in the interstellar medium.
Random variations are introduced into the rate constants to estimate the
scatter in theoretical abundances. Calculations are performed for dark and
translucent molecular clouds where gas phase chemistry is adequate. Similar
approach was used by Pineau des Forets & Roueff (2000) for the study of
chemical bistability. All the species are divided into 6 sensitivity groups
according to the value of the scatter in their model abundances computed with
varied rate constants. It is shown that the distribution of species within
these groups depends on the number of atoms in a molecule and on the adopted
physical conditions. The simple method is suggested which allows to single out
reactions that are most important for the evolution of a given species.Comment: 4 pages. To appear in the proceedings of the 4th Cologne-Bonn Zermatt
Symposiu
Molecular line radiative transfer in protoplanetary disks: Monte Carlo simulations versus approximate methods
We analyze the line radiative transfer in protoplanetary disks using several
approximate methods and a well-tested Accelerated Monte Carlo code. A low-mass
flaring disk model with uniform as well as stratified molecular abundances is
adopted. Radiative transfer in low and high rotational lines of CO, C18O, HCO+,
DCO+, HCN, CS, and H2CO is simulated. The corresponding excitation
temperatures, synthetic spectra, and channel maps are derived and compared to
the results of the Monte Carlo calculations. A simple scheme that describes the
conditions of the line excitation for a chosen molecular transition is
elaborated. We find that the simple LTE approach can safely be applied for the
low molecular transitions only, while it significantly overestimates the
intensities of the upper lines. In contrast, the Full Escape Probability (FEP)
approximation can safely be used for the upper transitions (J_{\rm up} \ga 3)
but it is not appropriate for the lowest transitions because of the maser
effect. In general, the molecular lines in protoplanetary disks are partly
subthermally excited and require more sophisticated approximate line radiative
transfer methods. We analyze a number of approximate methods, namely, LVG, VEP
(Vertical Escape Probability) and VOR (Vertical One Ray) and discuss their
algorithms in detail. In addition, two modifications to the canonical Monte
Carlo algorithm that allow a significant speed up of the line radiative
transfer modeling in rotating configurations by a factor of 10--50 are
described.Comment: 47 pages, 12 figures, accepted for publication in Ap
Entropy-induced smectic phases in rod-coil copolymers
We present a self-consistent field theory (SCFT) of semiflexible (wormlike)
diblock copolymers, each consisting of a rigid and a flexible part. The
segments of the polymers are otherwise identical, in particular with regard to
their interactions, which are taken to be of an Onsager excluded-volume type.
The theory is developed in a general three-dimensional form, as well as in a
simpler one-dimensional version. Using the latter, we demonstrate that the
theory predicts the formation of a partial-bilayer smectic-A phase in this
system, as shown by profiles of the local density and orientational
distribution functions. The phase diagram of the system, which includes the
isotropic and nematic phases, is obtained in terms of the mean density and
rigid-rod fraction of each molecule. The nematic-smectic transition is found to
be second order. Since the smectic phase is induced solely by the difference in
the rigidities, the onset of smectic ordering is shown to be an entropic effect
and therefore does not have to rely on additional Flory-Huggins-type repulsive
interactions between unlike chain segments. These findings are compared with
other recent SCFT studies of similar copolymer models and with computer
simulations of several molecular models.Comment: 13 pages, 8 figure
Climate change and water resources in arid regions : uncertainty of the baseline time period
Recent climate change studies have given a lot of attention to the uncertainty that stems from general circulation models (GCM), greenhouse gas emission scenarios, hydrological models and downscaling approaches. Yet, the uncertainty that stems from the selection of the baseline period has not been studied. Accordingly, the main research question is as follows: What would be the differences and/or the similarities in the evaluation of climate change impacts between the GCM and the delta perturbation scenarios using different baseline periods? This article addresses this issue through comparison of the results of two different baseline periods, investigating the uncertainties in evaluating climate change impact on the hydrological characteristics of arid regions. The Lower Zab River Basin (Northern Iraq) has been selected as a representative case study. The research outcomes show that the considered baseline periods suggest increases and decreases in the temperature and precipitation (P), respectively, over the 2020, 2050 and 2080 periods. The two climatic scenarios are likely to lead to similar reductions in the reservoir mean monthly flows, and subsequently, their maximum discharge is approximately identical. The predicted reduction in the inflow for the 2080–2099 time period fluctuates between 31 and 49% based on SRA1B and SRA2 scenarios, respectively. The delta perturbation scenario permits the sensitivity of the climatic models to be clearly determined compared to the GCM. The former allows for a wide variety of likely climate change scenarios at the regional level and are easier to generate and apply so that they could complement the latter
Interfaces of Modulated Phases
Numerically minimizing a continuous free-energy functional which yields
several modulated phases, we obtain the order-parameter profiles and
interfacial free energies of symmetric and non-symmetric tilt boundaries within
the lamellar phase, and of interfaces between coexisting lamellar, hexagonal,
and disordered phases. Our findings agree well with chevron, omega, and
T-junction tilt-boundary morphologies observed in diblock copolymers and
magnetic garnet films.Comment: 4 page
Elastic Spin Relaxation Processes in Semiconductor Quantum Dots
Electron spin decoherence caused by elastic spin-phonon processes is
investigated comprehensively in a zero-dimensional environment. Specifically, a
theoretical treatment is developed for the processes associated with the
fluctuations in the phonon potential as well as in the electron procession
frequency through the spin-orbit and hyperfine interactions in the
semiconductor quantum dots. The analysis identifies the conditions (magnetic
field, temperature, etc.) in which the elastic spin-phonon processes can
dominate over the inelastic counterparts with the electron spin-flip
transitions. Particularly, the calculation results illustrate the potential
significance of an elastic decoherence mechanism originating from the
intervalley transitions in semiconductor quantum dots with multiple equivalent
energy minima (e.g., the X valleys in SiGe). The role of lattice anharmonicity
and phonon decay in spin relaxation is also examined along with that of the
local effective field fluctuations caused by the stochastic electronic
transitions between the orbital states. Numerical estimations are provided for
typical GaAs and Si-based quantum dots.Comment: 57 pages, 14 figure
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