Crustal fault reactivation facilitating lithospheric folding/buckling in the central Indian Ocean

High-quality, normal-incidence seismic reflection data confirm that tectonic deformation in the central Indian Ocean occurs at two spatial scales: whole lithosphere folding with wavelengths varying between 100 and 300 km, and compressional reactivation of crustal faults with a characteristic spacing of c. 5 km. Faults penetrate through the crust and probably into the upper mantle. Both types of deformation are driven by regional large intraplate stresses originating from the Indo-Eurasian collision. Numerical modelling of the spatial and temporal relationships between these two modes of deformations shows that, in agreement with geophysical observations, crustal faults are reactivated first with stick-slip behaviour. Subsequent lithospheric folding does not start until horizontal loading has significantly reduced the mechanical strength of the lithosphere, as predicted by elasto-plastic buckling theory. Modelling suggests that lithospheric folding does not develop in the absence of fault reactivation. Crustal fault reactivation, therefore, appears to be a key facilitating mechanism for oceanic lithospheric buckling in the central Indian Ocean

Sedimentary succession and tectonic history of a marginal plateau (Goban Spur, southwest of Ireland)

Goban Spur lies on the continental margin of northwest Europe, southwest of Ireland. It is a marginal plateau underlain by Hercynian granites and Palaeozoic sediments, which form large horsts, grabens and tilted fault blocks with a trend that is approximately parallel to the main Celtic/Armorican Shelf edge. The spur is thought to be a westward continuation of the buoyant Cornubian Ridge, and is bounded to the north and south by large fault lines which probably represent reactivation of Hercynian structural trends. The continental basement is further divided longitudinally into a low-lying outer zone (Intermediate Zone) and a high inner region (Goban Spur proper). The ocean/continent boundary is thought to lie at the outer edge of the Intermediate Zone, Sea-floor spreading anomalies immediately west of the Intermediate Zone suggest that the adjacent ocean crust was created prior to anomaly 33 (say at ca. 90 m.y. B.P.). The sedimentary sequence on Goban Spur can be subdivided into four layers which can be tentatively correlated with the stratigraphic succession on the Meriadzek Terrace (IPOD sites). Such a correlation suggests that the lowermost sediment layer (?Jurassic-Albian) represents a tectono-sedimentary rift infill, and that Layers 2–4 (Upper Cretaceous to Quaternary) were deposited during slow epeirogenic downwarping of the plateau and that the sedimentary processes involved both draping and strong current moulding. The relatively buoyant nature of Inner Goban Spur has inhibited the accumulation of a thick post-rifting sedimentary sequence (700–1000 m), and has shielded the Intermediate Zone from downslope mass movements of material. This has resulted in the accumulation of an anomalously thin post-rift stage outer margin sediment prism (ca. 1000 m) compared to most continent rises (up to 10 km)

Cote d'Ivoire Ghana margin - seismic imaging of passive rifted crust adjacent to a transform continental margin.

During May 1990 and January-February 1991, an extensive geophysical data set was collected over the Côte d'Ivoire-Ghana continental margin, located along the equatorial coast of West Africa. The Ghana margin is a transform continental margin running subparallel to the Romanche Fracture Zone and its associated marginal ridge - the Côte d'Ivoire-Ghana Ridge. From this data set, an explosive refraction line running approximately 150 km, ENE-WSW between 3°55'N, 3°21'W and 4°23'N, 2°4'W, has been modelled together with wide-angle airgun profiles, and seismic reflection and gravity data. This study is centred on the Côte d'Ioivre Basin located just to the north of the Côte d'Ivoire-Ghana Ridge, where bathymetric data suggest that a component of normal rifting occurred, rather than the transform motion observed along the majority of the equatorial West African margin. Traveltime and amplitude modelling of the ocean-bottom seismometer data shows that the continental Moho beneath the margin rises in an oceanward direction, from approximately 24 km below sea level to approximately 17 km. In the centre of the line where the crust thins most rapidly, there exists a region of anomalously high velocity at the base of the crust, reaching some 8 km in thickness. This higher-velocity region is thought to represent an area of localized underplating related to rifting. Modelling of marine gravity data, collected coincident with the seismic line, has been used to test the best-fitting seismic model. This modelling has shown that the observed free-air anomaly is dominated by the effects of crustal thickness, and that a region of higher density is required at the base of the crust to fit the observed data. This higher-density region is consistent in size and location with the high velocities required to fit the seismic data. (Résumé d'auteur

Growth of the Afanasy Nikitin seamount and its relationship with the 85?E Ridge, northeastern Indian Ocean

The Afanasy Nikitin seamount (ANS) is a major structural feature (400 km-long and 150 km-wide) in the Central Indian Basin, situated at the southern end of the so-called 85?E Ridge. Combined analyses of new multibeam bathymetric, seismic reflection and geochronological data together with previously described magnetic data provide new insights into the growth of the ANS through time, and its relationship with the 85?E Ridge. The ANS comprises a main plateau, rising 1200 m above the surrounding ocean floor (4800 m), and secondary elevated seamount highs, two of which (lie at 1600 and 2050 m water depths) have the morphology of a guyot, suggesting that they were formed above or close to sea-level. An unbroken sequence of spreading anomalies 34 through 32n.1 identified over the ANS reveal that the main plateau of the ANS was formed at 80–73 Ma, at around the same time as that of the underlying oceanic crust. The 40Ar/39Ar dates for two basalt samples dredged from the seamount highs are consistent, within error, at 67 Ma. These results, together with published results of late Cretaceous to early Cenozoic Indian Ocean plate reconstructions, indicate that the Conrad Rise hotspot emplaced both the main plateau of the ANS and Conrad Rise (including the Marion Dufresne, Ob and Lena seamounts) at 80–73 Ma, close to the India–Antarctica Ridge system. Subsequently, the seamount highs were formed by late-stage volcanism c. 6–13 Myr after the main constructional phase of the seamount plateau. Flexural analysis indicates that the main plateau and seamount highs of the ANS are consistent with Airy-type isostatic compensation, which suggest emplacement of the entire seamount in a near spreading-center setting. This is contrary to the flexural compensation of the 85?E Ridge further north, which is interpreted as being emplaced in an intraplate setting, i.e., 25–35 Myr later than the underlying oceanic crust. Therefore, we suggest that the ANS and the 85?E Ridge appear to be unrelated as they were formed by different mantle sources, and that the proximity of the southern end of the 85?E Ridge to the ANS is coincidental

Côte d'Ivoire-Ghana margin : seismic imaging of passive rifted crust adjacent to a transform continental margin

During May 1990 and January-February 1991, an extensive geophysical data set was collected over the Côte d'Ivoire-Ghana continental margin, located along the equatorial coast of West Africa. The Ghana margin is a transform continental margin running subparallel to the Romanche Fracture Zone and its associated marginal ridge - the Côte d'Ivoire-Ghana Ridge. From this data set, an explosive refraction line running approximately 150 km, ENE-WSW between 3°55'N, 3°21'W and 4°23'N, 2°4'W, has been modelled together with wide-angle airgun profiles, and seismic reflection and gravity data. This study is centred on the Côte d'Ioivre Basin located just to the north of the Côte d'Ivoire-Ghana Ridge, where bathymetric data suggest that a component of normal rifting occurred, rather than the transform motion observed along the majority of the equatorial West African margin. Traveltime and amplitude modelling of the ocean-bottom seismometer data shows that the continental Moho beneath the margin rises in an oceanward direction, from approximately 24 km below sea level to approximately 17 km. In the centre of the line where the crust thins most rapidly, there exists a region of anomalously high velocity at the base of the crust, reaching some 8 km in thickness. This higher-velocity region is thought to represent an area of localized underplating related to rifting. Modelling of marine gravity data, collected coincident with the seismic line, has been used to test the best-fitting seismic model. This modelling has shown that the observed free-air anomaly is dominated by the effects of crustal thickness, and that a region of higher density is required at the base of the crust to fit the observed data. This higher-density region is consistent in size and location with the high velocities required to fit the seismic data. (Résumé d'auteur

A free-air gravity anomaly map of the Irish continental margin and a new gravity model across the southern Porcupine Seabight

Incl. 1 mapSIGLEAvailable from British Library Document Supply Centre- DSC:7671.928(GSI-RS--85/4) / BLDSC - British Library Document Supply CentreGBUnited Kingdo

Catalytic mechanism of cofactor-free dioxygenases and how they circumvent spin-forbidden oxygenation of their substrates

Dioxygenases catalyze a diverse range of biological reactions by incorporating molecular oxygen into organic substrates. Typically, they use transition metals or organic cofactors for catalysis. Bacterial 1-H-3-hydroxy-4-oxoquinaldine-2,4-dioxygenase (HOD) catalyzes the spin-forbidden transfer of dioxygen to its N-heteroaromatic substrate in the absence of any cofactor. We combined kinetics, spectroscopic and computational approaches to establish a novel reaction mechanism. The present work gives insight into the rate limiting steps in the reaction mechanism, the effect of first-coordination sphere amino acids as well as electron-donating/electron-withdrawing substituents on the substrate. We highlight the role of active site residues Ser101/Trp160/His251 and their involvement in the reaction mechanism. The work shows, for the first time, that the reaction is initiated by triplet dioxygen and its binding to deprotonated substrate and only thereafter a spin state crossing to the singlet spin state occurs. As revealed by steady- and transient-state kinetics the oxygen-dependent steps are rate-limiting, whereas Trp160 and His251 are essential residues for catalysis and contribute to substrate positioning and activation, respectively. Computational modeling further confirms the experimental observations and rationalizes the electron transfer pathways, and the effect of substrate and substrate binding pocket residues. Finally, we make a direct comparison with iron-based dioxygenases and explain the mechanistic and electronic differences with cofactor-free dioxygenases. Our multidisciplinary study confirms that the oxygenation reaction can take place in absence of any cofactor by a unique mechanism in which the specially designed fit-for-purpose active-site architecture modulates substrate reactivity toward oxygen

Early (pre-8 Ma) fault activity and temporal strain accumulation in the central Indian Ocean

The diffuse deformation zone in the central Indian Ocean is the classical example of distributed deformation of the oceanic lithosphere with shortening between the Indian and Capricorn plates manifest as reverse faulting (5–10 km spaced faults) and long-wavelength (100–300 km) folding. The onset of this deformation is commonly regarded as a key far-field indicator for the start of major uplift of the Himalayas and Tibet, some 4000 km further to the north, due to increased deviatoric stresses within the wider India-Asia area. There has been disagreement concerning the likely timing for the onset of deformation between plate motion inversions and seismic reflection-based studies. In the present study, fault displacement data from seismic reflection profiles within the central Indian Ocean demonstrate that compressional activity started much earlier, at around 15.4–13.9 Ma. We reconstruct that 12% of the total reverse fault population had been activated, and 14% of the total strain accumulated, prior to a sharp increase in the deformation rate at 8.0–7.5 Ma. There is no evidence for any regional unconformity before 8.0–7.5 Ma, early shortening was accommodated by activity on single isolated fault blocks. Total strain estimates derived are more variable and complex than those predicted from plate inversion and do not show simple west to east increase