4,729 research outputs found
- and -spin relaxation time limitations of phosphorous donor electrons near crystalline silicon to silicon dioxide interface defects
A study of donor electron spins and spin--dependent electronic transitions
involving phosphorous (P) atoms in proximity of the (111) oriented
crystalline silicon (c-Si) to silicon dioxide (SiO) interface is
presented for [P] = 10 and [P] =
10 at about liquid He temperatures (
). Using pulsed electrically detected magnetic
resonance (pEDMR), spin--dependent transitions between the \Phos donor state
and two distinguishable interface states are observed, namely (i) \Pb centers
which can be identified by their characteristic anisotropy and (ii) a more
isotropic center which is attributed to E defects of the \sio bulk
close to the interface. Correlation measurements of the dynamics of
spin--dependent recombination confirm that previously proposed transitions
between \Phos and the interface defects take place. The influence of these
electronic near--interface transitions on the \Phos donor spin coherence time
as well as the donor spin--lattice relaxation time is then
investigated by comparison of spin Hahn--echo decay measurements obtained from
conventional bulk sensitive pulsed electron paramagnetic resonance and surface
sensitive pEDMR, as well as surface sensitive electrically detected inversion
recovery experiments. The measurements reveal that both and of
\Phos donor electrons spins in proximity of energetically lower interface
states at K are reduced by several orders of magnitude
Direct Observation of Quantum Coherence in Single-Molecule Magnets
Direct evidence of quantum coherence in a single-molecule magnet in frozen
solution is reported with coherence times as long as T2 = 630 ns. We can
strongly increase the coherence time by modifying the matrix in which the
single-molecule magnets are embedded. The electron spins are coupled to the
proton nuclear spins of both the molecule itself and interestingly, also to
those of the solvent. The clear observation of Rabi oscillations indicates that
we can manipulate the spin coherently, an essential prerequisite for performing
quantum computations.Comment: 5 Pages, 4 Figures, final version published in PR
Measuring errors in single qubit rotations by pulsed electron paramagnetic resonance
The ability to measure and reduce systematic errors in single-qubit logic
gates is crucial when evaluating quantum computing implementations. We describe
pulsed electron paramagnetic resonance (EPR) sequences that can be used to
measure precisely even small systematic errors in rotations of
electron-spin-based qubits. Using these sequences we obtain values for errors
in rotation angle and axis for single-qubit rotations using a commercial EPR
spectrometer. We conclude that errors in qubit operations by pulsed EPR are not
limiting factors in the implementation of electron-spin based quantum
computers
Transport and recombination through weakly coupled localized spin pairs in semiconductors during coherent spin excitation
Semi-analytical predictions for the transients of spin-dependent transport
and recombination rates through localized states in semiconductors during
coherent electron spin excitation are made for the case of weakly spin-coupled
charge carrier ensembles. The results show that the on-resonant Rabi frequency
of electrically or optically detected spin-oscillation doubles abruptly as the
strength of the resonant microwave field gamma B_1 exceeds the Larmor frequency
separation within the pair of charge carrier states between which the transport
or recombination transition takes place. For the case of a Larmor frequency
separation of the order of gamma B_1 and arbitrary excitation frequencies, the
charge carrier pairs exhibit four different nutation frequencies. From the
calculations, a simple set of equations for the prediction of these frequencies
is derived
Electron spin coherence in metallofullerenes: Y, Sc and La@C82
Endohedral fullerenes encapsulating a spin-active atom or ion within a carbon
cage offer a route to self-assembled arrays such as spin chains. In the case of
metallofullerenes the charge transfer between the atom and the fullerene cage
has been thought to limit the electron spin phase coherence time (T2) to the
order of a few microseconds. We study electron spin relaxation in several
species of metallofullerene as a function of temperature and solvent
environment, yielding a maximum T2 in deuterated o-terphenyl greater than 200
microseconds for Y, Sc and La@C82. The mechanisms governing relaxation (T1, T2)
arise from metal-cage vibrational modes, spin-orbit coupling and the nuclear
spin environment. The T2 times are over 2 orders of magnitude longer than
previously reported and consequently make metallofullerenes of interest in
areas such as spin-labelling, spintronics and quantum computing.Comment: 5 pages, 4 figure
Environmental effects on electron spin relaxation in N@C60
We examine environmental effects of surrounding nuclear spins on the electron
spin relaxation of the N@C60 molecule (which consists of a nitrogen atom at the
centre of a fullerene cage). Using dilute solutions of N@C60 in regular and
deuterated toluene, we observe and model the effect of translational diffusion
of nuclear spins of the solvent molecules on the N@C60 electron spin relaxation
times. We also study spin relaxation in frozen solutions of N@C60 in CS2, to
which small quantities of a glassing agent, S2Cl2 are added. At low
temperatures, spin relaxation is caused by spectral diffusion of surrounding
nuclear 35Cl and 37Cl spins in the S2Cl2, but nevertheless, at 20 K, T2 times
as long as 0.23 ms are observed.Comment: 7 pages, 6 figure
Toward a conceptual framework of emotional relationship marketing: an examination of two UK political parties
The purpose of this paper is to review the notion of branding and evaluate its applicability to political parties. As ideological politics is in decline, branding may provide a consistent narrative where voters feel a sense of warmth and belonging. The paper aims to build an understanding of the complexity of building a political brand where a combination of image, logo, leadership, and values can all contribute to a compelling brand narrative. It investigates how competing positive and negative messages attempt to build and distort the brand identity. A critical review of bran ding, relationship marketing, and political science literature articulates the conceptual development of branding and its applicability to political parties. The success or failure of negative campaigning is due to the authenticity of a political party’s brand values — creating a coherent brand story — if there is no distance between the brand values articulated by the political party and the values their community perceives then this creates an "authentic" brand. However, if there is a gap this paper illustrates how negative campaigning can be used to build a "doppelganger brand," which undermines the credibility of the authentic political brand. The paper argues that political parties need to understand how brand stories are developed but also how they can be used to protect against negative advertising. This has implications for political marketing strategists and political parties. This paper draws together branding theory and relationship marketing and incorporates them into a framework that makes a contribution to the political marketing literature
Indications for the Nonexistence of Three-Neutron Resonances near the Physical Region
The pending question of the existence of three-neutron resonances near the
physical energy region is reconsidered. Finite rank neutron-neutron forces are
used in Faddeev equations, which are analytically continued into the unphysical
energy sheet below the positive real energy axis. The trajectories of the
three-neutron S-matrix poles in the states of total angular momenta and parity
J^\pi=1/2 +- and J^\pi= 3/2 +- are traced out as a function of artificial
enhancement factors of the neutron-neutron forces. The final positions of the
S-matrix poles removing the artificial factors are found in all cases to be far
away from the positive real energy axis, which provides a strong indication for
the nonexistence of nearby three-neutron resonances. The pole trajectories
close to the threshold E=0 are also predicted out of auxiliary generated
three-neutron bound state energies using the Pad\'e method and agree very well
with the directly calculated ones.Comment: 20 pages, 7 Postscript figures, fig.1 is corrected, uses relax.st
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