363 research outputs found
Dissociative recombination measurements of HCl+ using an ion storage ring
We have measured dissociative recombination of HCl+ with electrons using a
merged beams configuration at the heavy-ion storage ring TSR located at the Max
Planck Institute for Nuclear Physics in Heidelberg, Germany. We present the
measured absolute merged beams recombination rate coefficient for collision
energies from 0 to 4.5 eV. We have also developed a new method for deriving the
cross section from the measurements. Our approach does not suffer from
approximations made by previously used methods. The cross section was
transformed to a plasma rate coefficient for the electron temperature range
from T=10 to 5000 K. We show that the previously used HCl+ DR data
underestimate the plasma rate coefficient by a factor of 1.5 at T=10 K and
overestimate it by a factor of 3.0 at T=300 K. We also find that the new data
may partly explain existing discrepancies between observed abundances of
chlorine-bearing molecules and their astrochemical models.Comment: Accepted for publication in ApJ (July 7, 2013
A renormalisation approach to excitable reaction-diffusion waves in fractal media
Of fundamental importance to wave propagation in a wide range of physical phenomena is the structural geometry of the supporting medium. Recently, there have been several investigations on wave propagation in fractal media. We present here a renormalization approach to the study of reaction-diffusion (RD) wave propagation on finitely ramified fractal structures. In particular we will study a Rinzel-Keller (RK) type model, supporting travelling waves on a Sierpinski gasket (SG), lattice
Cryogenic micro-calorimeters for mass spectrometric identification of neutral molecules and molecular fragments
We have systematically investigated the energy resolution of a magnetic
micro-calorimeter (MMC) for atomic and molecular projectiles at impact energies
ranging from to 150 keV. For atoms we obtained absolute energy
resolutions down to eV and relative energy resolutions
down to . We also studied in detail the MMC
energy-response function to molecular projectiles of up to mass 56 u. We have
demonstrated the capability of identifying neutral fragmentation products of
these molecules by calorimetric mass spectrometry. We have modeled the MMC
energy-response function for molecular projectiles and conclude that
backscattering is the dominant source of the energy spread at the impact
energies investigated. We have successfully demonstrated the use of a detector
absorber coating to suppress such spreads. We briefly outline the use of MMC
detectors in experiments on gas-phase collision reactions with neutral
products. Our findings are of general interest for mass spectrometric
techniques, particularly for those desiring to make neutral-particle mass
measurements
Dielectronic Recombination (via N=2 --> N'=2 Core Excitations) and Radiative Recombination of Fe XX: Laboratory Measurements and Theoretical Calculations
We have measured the resonance strengths and energies for dielectronic
recombination (DR) of Fe XX forming Fe XIX via N=2 --> N'=2 (Delta_N=0) core
excitations. We have also calculated the DR resonance strengths and energies
using AUTOSTRUCTURE, HULLAC, MCDF, and R-matrix methods, four different
state-of-the-art theoretical techniques. On average the theoretical resonance
strengths agree to within <~10% with experiment. However, the 1 sigma standard
deviation for the ratios of the theoretical-to-experimental resonance strengths
is >~30% which is significantly larger than the estimated relative experimental
uncertainty of <~10%. This suggests that similar errors exist in the calculated
level populations and line emission spectrum of the recombined ion. We confirm
that theoretical methods based on inverse-photoionization calculations (e.g.,
undamped R-matrix methods) will severely overestimate the strength of the DR
process unless they include the effects of radiation damping. We also find that
the coupling between the DR and radiative recombination (RR) channels is small.
We have used our experimental and theoretical results to produce
Maxwellian-averaged rate coefficients for Delta_N=0 DR of Fe XX. For kT>~1 eV,
which includes the predicted formation temperatures for Fe XX in an optically
thin, low-density photoionized plasma with cosmic abundances, our experimental
and theoretical results are in good agreement. We have also used our R-matrix
results, topped off using AUTOSTRUCTURE for RR into J>=25 levels, to calculate
the rate coefficient for RR of Fe XX. Our RR results are in good agreement with
previously published calculations.Comment: To be published in ApJS. 65 pages with 4 tables and lots of figure
Enhanced dielectronic recombination of lithium-like Ti19+ ions in external ExB fields
Dielectronic recombination(DR) of lithium-like Ti19+(1s2 2s) ions via 2s->2p
core excitations has been measured at the Heidelberg heavy ion storage ring
TSR. We find that not only external electric fields (0 <= Ey <= 280 V/cm) but
also crossed magnetic fields (30 mT <= Bz <= 80 mT) influence the DR via high-n
(2p_j nl)-Rydberg resonances. This result confirms our previous finding for
isoelectronic Cl14+ ions [Bartsch T et al, PRL 82, 3779 (1999)] that
experimentally established the sensitivity of DR to ExB fields. In the present
investigation the larger 2p_{1/2}-2p_{3/2} fine structure splitting of Ti19+
allowed us to study separately the influence of external fields via the two
series of Rydberg DR resonances attached to the 2s -> 2p_{1/2} and 2s ->
2p_{3/2} excitations of the Li-like core, extracting initial slopes and
saturation fields of the enhancement. We find that for Ey > 80 V/cm the field
induced enhancement is about 1.8 times stronger for the 2p_{3/2} series than
for the 2p_{1/2} series.Comment: 10 pages, 3 figures, to be published in Journal of Physics B, see
also http://www.strz.uni-giessen.de/~k
Dielectronic Recombination in Photoionized Gas. II. Laboratory Measurements for Fe XVIII and Fe XIX
In photoionized gases with cosmic abundances, dielectronic recombination (DR)
proceeds primarily via nlj --> nl'j' core excitations (Dn=0 DR). We have
measured the resonance strengths and energies for Fe XVIII to Fe XVII and Fe
XIX to Fe XVIII Dn=0 DR. Using our measurements, we have calculated the Fe
XVIII and Fe XIX Dn=0 DR DR rate coefficients. Significant discrepancies exist
between our inferred rates and those of published calculations. These
calculations overestimate the DR rates by factors of ~2 or underestimate it by
factors of ~2 to orders of magnitude, but none are in good agreement with our
results. Almost all published DR rates for modeling cosmic plasmas are computed
using the same theoretical techniques as the above-mentioned calculations.
Hence, our measurements call into question all theoretical Dn=0 DR rates used
for ionization balance calculations of cosmic plasmas. At temperatures where
the Fe XVIII and Fe XIX fractional abundances are predicted to peak in
photoionized gases of cosmic abundances, the theoretical rates underestimate
the Fe XVIII DR rate by a factor of ~2 and overestimate the Fe XIX DR rate by a
factor of ~1.6. We have carried out new multiconfiguration Dirac-Fock and
multiconfiguration Breit-Pauli calculations which agree with our measured
resonance strengths and rate coefficients to within typically better than
<~30%. We provide a fit to our inferred rate coefficients for use in plasma
modeling. Using our DR measurements, we infer a factor of ~2 error in the Fe XX
through Fe XXIV Dn=0 DR rates. We investigate the effects of this estimated
error for the well-known thermal instability of photoionized gas. We find that
errors in these rates cannot remove the instability, but they do dramatically
affect the range in parameter space over which it forms.Comment: To appear in ApJS, 44 pages with 13 figures, AASTeX with postsript
figure
Dielectronic Recombination of Ground-State and Metastable Li+ Ions
Dielectronic recombination has been investigated for Delta-n = 1 resonances
of ground-state Li+(1s^2) and for Delta-n = 0 resonances of metastable Li+(1s2s
^3S). The ground-state spectrum shows three prominent transitions between 53
and 64 eV, while the metastable spectrum exhibits many transitions with
energies < 3.2 eV. Reasonably good agreement of R-matrix, LS coupling
calculations with the measured recombination rate coefficient is obtained. The
time dependence of the recombination rate yields a radiative lifetime of 52.2
+- 5.0 s for the 2 ^3S level of Li+.Comment: Submitted to Phys. Rev. A; REVTeX, 4 pages, 3 figure
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