Plasmon Evolution and Charge-Density Wave Suppression in Potassium Intercalated Tantalum Diselenide

We have investigated the influence of potassium intercalation on the formation of the charge-density wave (CDW) instability in 2H-tantalum diselenide by means of Electron Energy-Loss Spectroscopy and density functional theory. Our observations are consistent with a filling of the conduction band as indicated by a substantial decrease of the plasma frequency in experiment and theory. In addition, elastic scattering clearly points to a destruction of the CDW upon intercalation as can be seen by a vanishing of the corresponding superstructures. This is accompanied by a new superstructure, which can be attributed to the intercalated potassium. Based on the behavior of the c-axis upon intercalation we argue in favor of interlayer-sites for the alkali-metal and that the lattice remains in the 2H-modification

Comparison of electrically driven lasers for space power transmission

High-power lasers in space could provide power for a variety of future missions such as spacecraft electric power requirements and laser propulsion. This study investigates four electrically pumped laser systems, all scaled to 1-MW laser output, that could provide power to spacecraft. The four laser systems are krypton fluoride, copper vapor, laser diode array, and carbon dioxide. Each system was powered by a large solar photovoltaic array which, in turn, provided power for the appropriate laser power conditioning subsystem. Each system was block-diagrammed, and the power and efficiency were found for each subsystem block component. The copper vapor system had the lowest system efficiency (6 percent). The CO2 laser was found to be the most readily scalable but has the disadvantage of long laser wavelength

An optimization model for metabolic pathways

This article is available open access through the publisher’s website through the link below. Copyright @ The Author 2009.Motivation: Different mathematical methods have emerged in the post-genomic era to determine metabolic pathways. These methods can be divided into stoichiometric methods and path finding methods. In this paper we detail a novel optimization model, based upon integer linear programming, to determine metabolic pathways. Our model links reaction stoichiometry with path finding in a single approach. We test the ability of our model to determine 40 annotated Escherichia coli metabolic pathways. We show that our model is able to determine 36 of these 40 pathways in a computationally effective manner. Contact: [email protected] Supplementary information: Supplementary data are available at Bioinformatics online (http://bioinformatics.oxfordjournals.org/cgi/content/full/btp441/DC1)

Escalation of error catastrophe for enzymatic self-replicators

It is a long-standing question in origin-of-life research whether the information content of replicating molecules can be maintained in the presence of replication errors. Extending standard quasispecies models of non-enzymatic replication, we analyze highly specific enzymatic self-replication mediated through an otherwise neutral recognition region, which leads to frequency-dependent replication rates. We find a significant reduction of the maximally tolerable error rate, because the replication rate of the fittest molecules decreases with the fraction of functional enzymes. Our analysis is extended to hypercyclic couplings as an example for catalytic networks.Comment: 6 pages, 4 figures; accepted at Europhys. Let

Rubidium in Metal-Deficient Disk and Halo Stars

We report the first extensive study of stellar Rb abundances. High-resolution spectra have been used to determine, or set upper limits on, the abundances of this heavy element and the associated elements Y, Zr, and Ba in 44 dwarfs and giants with metallicities spanning the range -2.0 <[Fe/H] < 0.0. In metal-deficient stars Rb is systematically overabundant relative to Fe; we find an average [Rb/Fe] of +0.21 for the 32 stars with [Fe/H] < -0.5 and measured Rb. This behavior contrasts with that of Y, Zr, and Ba, which, with the exception of three new CH stars (HD 23439A and B and BD +5 3640), are consistently slightly deficient relative to Fe in the same stars; excluding the three CH stars, we find the stars with [Fe/H] < -0.5 have average [Y/Fe], [Zr/Fe], and [Ba/Fe] of --0.19 (24 stars), --0.12 (28 stars), and --0.06 (29 stars), respectively. The different behavior of Rb on the one hand and Y, Zr, and Ba on the other can be attributed in part to the fact that in the Sun and in these stars Rb has a large r-process component while Y, Zr, and Ba are mostly s-process elements with only small r-process components. In addition, the Rb s-process abundance is dependent on the neutron density at the s-processing site. Published observations of Rb in s-process enriched red giants indicate a higher neutron density in the metal-poor giants. These observations imply a higher s-process abundance for Rb in metal-poor stars. The calculated combination of the Rb r-process abundance, as estimated for the stellar Eu abundances, and the s-process abundance as estimated for red giants accounts satisfactorily for the observed run of [Rb/Fe] with [Fe/H].Comment: 23 pages, 5 tables, 7 figure

Control of unstable steady states by time-delayed feedback methods

We show that time-delayed feedback methods, which have successfully been used to control unstable periodic ortbits, provide a tool to stabilize unstable steady states. We present an analytical investigation of the feedback scheme using the Lambert function and discuss effects of both a low-pass filter included in the control loop and non-zero latency times associated with the generation and injection of the feedback signal.Comment: 8 pages, 11 figure