Geochemistry of volcanic rocks from the Wawa greenstone belt

The Wawa greenstone belt is located in the District of Algoma and extends east-northeast from Lake Superior to the western part of the Sudbury District in Ontario, Canada. Recent mapping by Attoh has shown that an unconformity at the base of the Dore' Formation and equivalent sedimentary rocks marks a significant stratigraphic break which can be traced throughout the volcanic belt. This break has been used to subdivide the volcanic-sedimentary into pre- and post-Dore' sequences. The pre-Dore' sequence includes at least two cycles of mafic-to-felsic volcanism, each capped by an iron-formation unit. The post-Dore' sequence includes an older mafic-to-felsic unit, which directly overlies sedimentary rocks correlated with the Dore' Formation, and a younger felsic breccia unit interpreted to have formed as debris flows from a felsic volcanic center. In the present study, samples of both the pre-and post-Dore' volcanic sequences were analyzed for major and trace elements, incuding rare earths (REE). This preliminary study is part of an ongoing program to assess the petrogenesis of the volcanic rocks of the Wawa greenstone belt

Rhyolitic components of the Michipicoten greenstone belt, Ontario: Evidence for late Archaen intracontinental rifts or convergent plate margins in the Canadian Shield?

Rhyolitic rocks often are the dominant felsic end member of the biomodal volcanic suites that characterize many late Archean greenstone belts of the Canadian Shield. The rhyolites primarily are pyroclastic flows (ash flow tuffs) emplaced following plinian eruptions, although deposits formed by laval flows and phreatomagmatic eruptions also are presented. Based both on measured tectono-stratigraphic sections and provenance studies of greenstone belt sedimentary sequences, the rhyolites are believed to have been equal in abundance to associated basaltic rocks. In many recent discussions of the tectonic setting of late Archean Canadian greenstone belts, rhyolites have been interpreted as products of intracontinental rifting . A study of the tectono-stratigraphic relationships, rock associations and chemical characteristics of the particularly ell-exposed late Archean rhyolites of the Michipicoten greenstone belt, suggests that convergent plate margin models are more appropriate

The Wisconsin magmatic terrane: An Early Proterozoic greenstone-granite terrane formed by plate tectonic processes

The Wisconsin magmatic terrane (WMT) is an east trending belt of dominantly volcanic-plutonic complexes of Early Proterozoic age (approx. 1850 m.y.) that lies to the south of the Archean rocks and Early Proterozoic epicratonic sequence (Marquette Range Supergroup) in Michigan. It is separated from the epicratonic Marquette Range Supergroup by the high-angle Niagara fault, is bounded on the south, in central Wisconsin, by Archean gneisses, is truncated on the west by rocks of the Midcontinent rift system, and is intruded on the east by the post-orogenic Wolf river batholith. The overall lithologic, geochemical, metallogenic, metamorphic, and deformational characteristics of the WMT are similar to those observed in recent volcanic arc terranes formed at sites of plate convergence. It is concluded that the WMT represents an evolved oceanic island-arc terrane accreated to the Superior craton in the Early Proterozoic. This conclusion is strengthened by the apparent absence of Archean basement from most of the WMT, and the recent recognition of the passive margin character of the epicratonic Marquette Range Supergroup

Approaches and tools to manipulate the carbonate chemistry

Although the chemistry of ocean acidifi cation is very well understood (see chapter 1), its impact on marine organisms and ecosystems remains poorly known. The biological response to ocean acidifi cation is a recent field of research, the fi rst purposeful experiments have only been carried out as late as the 1980s (Agegian, 1985) and most were not performed until the late 1990s. The potentially dire consequences of ocean acidifi cation have attracted the interest of scientists and students with a limited knowledge of the carbonate chemistry and its experimental manipulation. Perturbation experiments are one of the key approaches used to investigate the biological response to elevated p(CO2). Such experiments are based on measurements of physiological or metabolic processes in organisms and communities exposed to seawater with normal and altered carbonate chemistry. The basics of the carbonate chemistry must be understood to perform meaningful CO2 perturbation experiments (see chapter 1). Briefl y, the marine carbonate system considers € CO2 ∗(aq) [the sum of CO2 and H2CO3], € HCO3 −, € CO3 2−, H+, € OH− , and several weak acid-base systems of which borate-boric acid (€ B(OH)4 − , B(OH)3) is the most important. As discussed by Dickson (chapter 1), if two components of the carbonate chemistry are known, all the other components can be calculated for seawater with typical nutrient concentrations at given temperature, salinity, and pressure. One of the possible pairs is of particular interest because both components can be measured with precision, accuracy, and are conservative in the sense that their concentrations do not change with temperature or pressure. Dissolved inorganic carbon (DIC) is the sum of all dissolved inorganic carbon species while total alkalinity (AT) equals € [HCO3 − ] + 2 € [CO3 2− ] + € [B(OH)4 − ] + € [OH− ] - [H+] + minor components, and refl ects the excess of proton acceptors over proton donors with respect to a zero level of protons (see chapter 1 for a detailed defi nition). AT is determined by the titration of seawater with a strong acid and thus can also be regarded as a measure of the buffering capacity. Any changes in any single component of the carbonate system will lead to changes in several, if not all, other components. In other words, it is not possible to vary a single component of the carbonate system while keeping all other components constant. This interdependency in the carbonate system is important to consider when performing CO2 perturbation experiments. To adjust seawater to different p(CO2) levels, the carbonate system can be manipulated in various ways that usually involve changes in AT or DIC. The goal of this chapter is (1) to examine the benefi ts and drawbacks of various manipulation methods used to date and (2) to provide a simple software package to assist the design of perturbation experiments

Weakly correlated electrons on a square lattice: a renormalization group theory

We study the weakly interacting Hubbard model on the square lattice using a one-loop renormalization group approach. The transition temperature T_c between the metallic and (nearly) ordered states is found. In the parquet regime, (T_c >> |mu|), the dominant correlations at temperatures below T_c are antiferromagnetic while in the BCS regime (T_c << |mu|) at T_c the d-wave singlet pairing susceptibility is most divergent.Comment: 12 pages, REVTEX, 3 figures included, submitted to Phys. Rev. Let

A Frustrated 3-Dimensional Antiferromagnet: Stacked J1−J2J_{1}-J_{2} Layers

We study a frustrated 3D antiferromagnet of stacked $J_1 - J_2$ layers. The intermediate 'quantum spin liquid' phase, present in the 2D case, narrows with increasing interlayer coupling and vanishes at a triple point. Beyond this there is a direct first-order transition from N{\' e}el to columnar order. Possible applications to real materials are discussed.Comment: 11 pages,7 figure

On the metal-insulator transition in the two-chain model of correlated fermions

The doping-induced metal-insulator transition in two-chain systems of correlated fermions is studied using a solvable limit of the t-J model and the fact that various strong- and weak-coupling limits of the two-chain model are in the same phase, i.e. have the same low-energy properties. It is shown that the Luttinger-liquid parameter K_\rho takes the universal value unity as the insulating state (half-filling) is approached, implying dominant d-type superconducting fluctuations, independently of the interaction strength. The crossover to insulating behavior of correlations as the transition is approached is discussed.Comment: 7 pages, 1 figur