Initial Stages of Sodium Deposition onto Au(111) from [MPPip][TFSI]: An In‐Situ STM Study for Sodium‐Ion Battery Electrolytes

Sodium-ion batteries are promising candidates for post-lithium-ion batteries. While sodium has a less negative standard electrode potential compared to lithium, it is still a strong reducing agent. Ionic liquids are suitable solvents for sodium metal batteries, since metallic sodium is very reactive, particularly with water and molecules containing acidic hydrogen atoms. In this study, the initial stages of electrodeposition of sodium on Au(111) from N-methyl-N-propylpiperidinium [MPPip] bis(trifluoromethanesulfonyl)imide [TFSI] were studied using voltammetry and in-situ scanning tunnelling microscopy. Four subsequent underpotential deposition stages were observed: (i) nucleation at the Au(111) reconstruction elbows, followed by (ii) growth of small monoatomically high islands that form (iii) a smooth layer via coalescence, and (iv) further island growth on top of the existing layers. The electrocrystallisation mode changed from smooth layer formation to 3D growth, resulting in cauliflower-like structures. The deposition process was accompanied by simultaneous alloy formation

Electrodeposition of Zinc onto Au(111) and Au(100) from the Ionic Liquid [MPPip][TFSI]

The improvement of rechargeable zinc/air batteries was a hot topic in recent years. Predominantly, the influence of water and additives on the structure of the Zn deposit and the possible dendrite formation were studied. However, the effect of the surface structure of the underlying substrate was not focused on in detail, yet. We now show the differences in electrochemical deposition of Zn onto Au(111) and Au(100) from the ionic liquid N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide. The fundamental processes were initially characterized via cyclic voltammetry and in situ scanning tunnelling microscopy. Bulk deposits were then examined using Auger electron spectroscopy and scanning electron microscopy. Different structures of Zn deposits are observed during the initial stages of electrocrystallisation on both electrodes, which reveals the strong influence of the crystallographic orientation on the metal deposition of zinc on gold

DIMENSIONALITY BASED SCALE SELECTION IN 3D LIDAR POINT CLOUDS

International audienceThis papers presents a multi-scale method that computes robust geometric features on lidar point clouds in order to retrieve the optimal neighborhood size for each point. Three dimensionality features are calculated on spherical neighborhoods at various radius sizes. Based on combinations of the eigenvalues of the local structure tensor, they describe the shape of the neighborhood, indicating whether the local geometry is more linear (1D), planar (2D) or volumetric (3D). Two radius-selection criteria have been tested and compared for finding automatically the optimal neighborhood radius for each point. Besides, such procedure allows a dimensionality labelling, giving significant hints for classification and segmentation purposes. The method is successfully applied to 3D point clouds from airborne, terrestrial, and mobile mapping systems since no a priori knowledge on the distribution of the 3D points is required. Extracted dimensionality features and labellings are then favorably compared to those computed from constant size neighborhoods

Versatile 3D-Printed Micro-Reference Electrodes for Aqueous and Non-Aqueous Solutions

While numerous reference electrodes suitable for aqueous electrolytes exist, there is no well-defined standard for non-aqueous electrolytes. Furthermore, reference electrodes are often large and do not meet the size requirements for small cells. In this work, we present a simple method for fabricating stable 3D-printed micro-reference electrodes. The prints are made from polyvinylidene fluoride, which is chemically inert in strong acids, bases, and commonly used non-aqueous solvents. We chose six different reference systems based on Ag, Cu, Zn, and Na, including three aqueous and three non-aqueous systems to demonstrate the versatility of the approach. Subsequently, we conducted cyclic voltammetry experiments and measured the potential difference between the aqueous homemade reference electrodes and a commercial Ag/AgCl-electrode. For the non-aqueous reference electrodes, we chose the ferrocene redox couple as an internal standard. From these measurements, we deduced that this new class of micro-reference electrodes is leak-tight and shows a stable electrode potential

Controlled-Atmosphere Flame Fusion Single-Crystal Growth of Non-Noble fcc, hcp, and bcc Metals Using Copper, Cobalt, and Iron

The growth of noble-metal single crystals via the flame fusion method was developed in the 1980s. Since then, there have been no major advancements to the technique until the recent development of the controlled-atmosphere flame fusion (CAFF) method to grow non-noble Ni single crystals. Herein, we demonstrate the generality of this method with the first preparation of fcc Cu as well as the first hcp and bcc single crystals of Co and Fe, respectively. The high quality of the single crystals was verified using scanning electron microscopy and Laue X-ray backscattering. Based on Wulff constructions, the equilibrium shapes of the single-crystal particles were studied, confirming the symmetry of the fcc, hcp, and bcc single-crystal lattices. The low cost of the CAFF method makes all kinds of high-quality non-noble single crystals independent of their lattice accessible for use in electrocatalysis, electrochemistry, surface science, and materials science.Funding Agencies|Natural Sciences and Engineering Research Council of Canada (NSERC)Natural Sciences and Engineering Research Council of Canada [RGPNM 477963-2015]; MITACS through the Globalink Research Award; German Research Foundation (DFG)German Research Foundation (DFG) [390874152, Sonderforschungsbereich SFB 1316]; Alexander von Humboldt foundationAlexander von Humboldt Foundation; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkcping University (Faculty Grant SFO-MatLiU) [2009 00971]; DAADDeutscher Akademischer Austausch Dienst (DAAD)</p