Complete Hydrogen Storage System by ISRU

New technologies make it possible to build in space a complete hydrogen storage system using ISRU methods and techniques. Hydrogen can be stored in a solid-state form on the surface atoms of high surface area matrices such as those of porous silicon. Silicon is abundant in regolith and can be purified using a purely mechanical means which results in particulates in the scale range of tens of nanometers. Reagents used to porosify these nano-particles can be regenerated thermally to essentially eliminate the need for resupply from earth. Catalysts are needed to divide dihydrogen gas into atomic hydrogen for solid-state adsorption and to mediate the temperatures and pressures of charge and discharge into ranges easily achievable with simple equipment. Recent research has identified the utility of non-platinum group catalyst materials which are widespread on the moon. Rapid discharge, needed for propulsion, is possible with infra-red illumination at wavelengths which pass through pure silicon but are absorbed by the silicon-hydrogen bond. Such IR emitters can be fabricated by embossing of silica and additive manufacturing of metals. Control and power electronics can be fabricated using a patented process designed for space operations, and built on either silicon or silicon carbide substrates derived from regolith. Bringing these five technologies together for the first time allows a system which can be fed with moderate pressure gaseous hydrogen at moderate temperatures, stored for long durations with minimum loss, then released upon demand across a wide range of controllable rates. Such a system can displace the need for cryogenic hydrogen storage. Being suitable to bottom-up fabrication using only in-space materials makes this a “green” ISRU technology to store hydrogen for fuel cells, rocket engines, and chemical processes

Alkaline static feed electrolyzer based oxygen generation system

In preparation for the future deployment of the Space Station, an R and D program was established to demonstrate integrated operation of an alkaline Water Electrolysis System and a fuel cell as an energy storage device. The program's scope was revised when the Space Station Control Board changed the energy storage baseline for the Space Station. The new scope was aimed at the development of an alkaline Static Feed Electrolyzer for use in an Environmental Control/Life Support System as an oxygen generation system. As a result, the program was divided into two phases. The phase 1 effort was directed at the development of the Static Feed Electrolyzer for application in a Regenerative Fuel Cell System. During this phase, the program emphasized incorporation of the Regenerative Fuel Cell System design requirements into the Static Feed Electrolyzer electrochemical module design and the mechanical components design. The mechanical components included a Pressure Control Assembly, a Water Supply Assembly and a Thermal Control Assembly. These designs were completed through manufacturing drawing during Phase 1. The Phase 2 effort was directed at advancing the Alkaline Static Feed Electrolyzer database for an oxygen generation system. This development was aimed at extending the Static Feed Electrolyzer database in areas which may be encountered from initial fabrication through transportation, storage, launch and eventual Space Station startup. During this Phase, the Program emphasized three major areas: materials evaluation, electrochemical module scaling and performance repeatability and Static Feed Electrolyzer operational definition and characterization

Cell cycle-dependent phosphorylation of Theileria annulata schizont surface proteins

The invasion of Theileria sporozoites into bovine leukocytes is rapidly followed by the destruction of the surrounding host cell membrane, allowing the parasite to establish its niche within the host cell cytoplasm. Theileria infection induces host cell transformation, characterised by increased host cell proliferation and invasiveness, and the activation of anti-apoptotic genes. This process is strictly dependent on the presence of a viable parasite. Several host cell kinases, including PI3-K, JNK, CK2 and Src-family kinases, are constitutively activated in Theileria-infected cells and contribute to the transformed phenotype. Although a number of host cell molecules, including IkB kinase and polo-like kinase 1 (Plk1), are recruited to the schizont surface, very little is known about the schizont molecules involved in host-parasite interactions. In this study we used immunofluorescence to detect phosphorylated threonine (p-Thr), serine (p-Ser) and threonine-proline (p-Thr-Pro) epitopes on the schizont during host cell cycle progression, revealing extensive schizont phosphorylation during host cell interphase. Furthermore, we established a quick protocol to isolate schizonts from infected macrophages following synchronisation in S-phase or mitosis, and used mass spectrometry to detect phosphorylated schizont proteins. In total, 65 phosphorylated Theileria proteins were detected, 15 of which are potentially secreted or expressed on the surface of the schizont and thus may be targets for host cell kinases. In particular, we describe the cell cycle-dependent phosphorylation of two T. annulata surface proteins, TaSP and p104, both of which are highly phosphorylated during host cell S-phase. TaSP and p104 are involved in mediating interactions between the parasite and the host cell cytoskeleton, which is crucial for the persistence of the parasite within the dividing host cell and the maintenance of the transformed state

Poincar\'e Husimi representation of eigenstates in quantum billiards

For the representation of eigenstates on a Poincar\'e section at the boundary of a billiard different variants have been proposed. We compare these Poincar\'e Husimi functions, discuss their properties and based on this select one particularly suited definition. For the mean behaviour of these Poincar\'e Husimi functions an asymptotic expression is derived, including a uniform approximation. We establish the relation between the Poincar\'e Husimi functions and the Husimi function in phase space from which a direct physical interpretation follows. Using this, a quantum ergodicity theorem for the Poincar\'e Husimi functions in the case of ergodic systems is shown.Comment: 17 pages, 5 figures. Figs. 1,2,5 are included in low resolution only. For a version with better resolution see http://www.physik.tu-dresden.de/~baecker

Quantum state conversion by cross-Kerr interaction

A generalized Mach-Zehnder-type interferometer equipped with cross-Kerr elements is proposed to convert N-photon truncated single-mode quantum states into (N+1)-mode single-photon states, which are suitable for further state manipulation by means of beam splitter arrays and ON/OFF-detections, and vice versa. Applications to the realization of unitary and non-unitary transformations, quantum state reconstruction, and quantum telemanipulation are studied.Comment: 22 pages, 4 figures, using a4.st