11,627 research outputs found
Electron Transfer in Porphyrin Complexes in Different Solvents
The electron transfer in different solvents is investigated for systems
consisting of donor, bridge and acceptor. It is assumed that vibrational
relaxation is much faster than the electron transfer. Electron transfer rates
and final populations of the acceptor state are calculated numerically and in
an approximate fashion analytically. In wide parameter regimes these solutions
are in very good agreement. The theory is applied to the electron transfer in
with free-base porphyrin () being the donor,
zinc porphyrin () the bridge, and quinone () the acceptor.
It is shown that the electron transfer rates can be controlled efficiently by
changing the energy of the bridging level which can be done by changing the
solvent. The effect of the solvent is determined for different models.Comment: 28 pages + 5 figures, submitted to J. Phys. Chem. For more details
see the Ph. D. thesis in quant-ph archive
http://xxx.lanl.gov/abs/quant-ph/000100
The influence of self-citation corrections on Egghe's g index
The g index was introduced by Leo Egghe as an improvement of Hirsch's index h
for measuring the overall citation record of a set of articles. It better takes
into account the highly skewed frequency distribution of citations than the h
index. I propose to sharpen this g index by excluding the self-citations. I
have worked out nine practical cases in physics and compare the h and g values
with and without self-citations. As expected, the g index characterizes the
data set better than the h index. The influence of the self-citations appears
to be more significant for the g index than for the h index.Comment: 9 pages, 2 figures, submitted to Scientometric
Insights on star formation histories and physical properties of Herschel-detected galaxies
We test the impact of using variable star forming histories (SFHs) and the
use of the IR luminosity (LIR) as a constrain on the physical parameters of
high redshift dusty star-forming galaxies. We explore in particular the stellar
properties of galaxies in relation with their location on the SFR-M* diagram.
We perform SED fitting of the UV-NIR and FIR emissions of a large sample of
GOODS-Herschel galaxies, for which rich multi-wavelength observations are
available. We test different SFHs and imposing energy conservation in the SED
fitting process, to face issues like the age-extinction degeneracy and produce
SEDs consistent with observations. Our models work well for the majority of the
sample, with the notable exception of the high LIR end, for which we have
indications that our simple energy conservation approach cannot hold true. We
find trends in the SFHs fitting our sources depending on stellar mass M* and z.
Trends also emerge in the characteristic timescales of the SED models depending
on the location on the SFR-M* diagram. We show that whilst using the same
available observational data, we can produce galaxies less star-forming than
usually inferred, if we allow declining SFHs, while properly reproducing their
observables. These sources can be post-starbursts undergoing quenching, and
their SFRs are potentially overestimated if inferred from their LIR. Fitting
without the IR constrain leads to a strong preference for declining SFHs, while
its inclusion increases the preference of rising SFHs, more so at high z, in
tentative agreement with the cosmic star formation history. Keeping in mind
that the sample is biased towards high LIR, the evolution shaped by our model
appears as both bursty (initially) and steady-lasting (later on). The global
SFH of the sample follows the cosmic SFH with a small scatter, and is
compatible with the "downsizing" scenario of galaxy evolution.Comment: 28 pages, 26 figures, one appendix, Accepted for publication in
Astronomy & Astrophysic
Direct measurement of diurnal polar motion by ring laser gyroscopes
We report the first direct measurements of the very small effect of forced
diurnal polar motion, successfully observed on three of our large ring lasers,
which now measure the instantaneous direction of Earth's rotation axis to a
precision of 1 part in 10^8 when averaged over a time interval of several
hours. Ring laser gyroscopes provide a new viable technique for directly and
continuously measuring the position of the instantaneous rotation axis of the
Earth and the amplitudes of the Oppolzer modes. In contrast, the space geodetic
techniques (VLBI, SLR, GPS, etc.) contain no information about the position of
the instantaneous axis of rotation of the Earth, but are sensitive to the
complete transformation matrix between the Earth-fixed and inertial reference
frame. Further improvements of gyroscopes will provide a powerful new tool for
studying the Earth's interior.Comment: 5 pages, 4 figures, agu2001.cl
Near-Infrared spectroscopy of the super star cluster in NGC1705
We study the near-infrared properties of the super star cluster NGC1750-1 in
order to constrain its spatial extent, its stellar population and its age. We
use adaptive optics assisted integral field spectroscopy with SINFONI on the
VLT. We estimate the spatial extent of the cluster and extract its K-band
spectrum from which we constrain the age of the dominant stellar population.
Our observations have an angular resolution of about 0.11", providing an upper
limit on the cluster radius of 2.85+/-0.50 pc depending on the assumed
distance. The K-band spectrum is dominated by strong CO absorption bandheads
typical of red supergiants. Its spectral type is equivalent to a K4-5I star.
Using evolutionary tracks from the Geneva and Utrecht groups, we determine an
age of 12+/-6 Myr. The large uncertainty is rooted in the large difference
between the Geneva and Utrecht tracks in the red supergiants regime. The
absence of ionized gas lines in the K-band spectrum is consistent with the
absence of O and/or Wolf-Rayet stars in the cluster, as expected for the
estimated age.Comment: 5 pages, 4 figures. Research Note accepted in Astronomy and
Astrophysic
The Physical Properties of LBGs at z>5: Outflows and the "pre-enrichment problem"
We discuss the properties of Lyman Break galaxies (LBGs) at z>5 as determined
from disparate fields covering approximately 500 sq. arcmin. While the broad
characteristics of the LBG population has been discussed extensively in the
literature, such as luminosity functions and clustering amplitude, we focus on
the detailed physical properties of the sources in this large survey (>100 with
spectroscopic redshifts). Specifically, we discuss ensemble mass estimates,
stellar mass surface densities, core phase space densities, star-formation
intensities, characteristics of their stellar populations, etc as obtained from
multi-wavelength data (rest-frame UV through optical) for a subsample of these
galaxies. In particular, we focus on evidence that these galaxies drive
vigorous outflows and speculate that this population may solve the so-called
``pre-enrichment problem''. The general picture that emerges from these studies
is that these galaxies, observed about 1 Gyr after the Big Bang, have
properties consistent with being the progenitors of the densest stellar systems
in the local Universe -- the centers of old bulges and early type galaxies.Comment: 4 pages, to appear in "Pathways Through an Eclectic Universe", J. H.
Knappen, T. J. Mahoney, and A. Vazedekis (Eds.), ASP Conf. Ser., 200
DDF and Pohlmeyer invariants of (super)string
We show how the Pohlmeyer invariants of the bosonic string are expressible in
terms of DDF invariants. Quantization of the DDF observables in the usual way
yields a consistent quantization of the algebra of Pohlmeyer invariants.
Furthermore it becomes straightforward to generalize the Pohlmeyer invariants
to the superstring as well as to all backgrounds which allow a free field
realization of the worldsheet theory.Comment: 17 pp, minor typos corrected, references to papers by Isaev and
Borodulin added, which contain essentially the same results as reported her
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