Investigation of changes in crystalline and amorphous structure during deformation of nano-reinforced semi-crystalline polymers by space-resolved synchrotron saxs and waxs

Complex structural changes occur in semi-crystalline polymers during deformation. In (nano-)filled systems the situation becomes even more complicated, since not only phase changes may take place, but also local (interfacial) failure between phases may occur. To help identify specific processes taking place within these systems, simultaneous small- and wide-angle X-ray scattering (SAXS/WAXS) measurements were performed using synchrotron radiation during in situ deformation. Using a highly focused beam, spatially resolved local information can be extracted by scanning the beam across the deformed/damaged region within the sample. The characteristic changes in the different phases are presented and discussed. While the study of WAXS patterns gives insight into the orientation and dimensions of the crystallites, SAXS provides information about the mutual arrangement of phases and the interfacial failure phenomena. Based on the analysis of the results obtained in our experiments it will be shown that the first changes in the crystalline phase appear long before macroscopic yielding of the sample is reached, i.e. the onset of irreversible deformation takes place. In the post-yield regime radical changes are observed in both the long- and short-range structures. It is concluded that the presence of nano-fillers exerts a strong influence on the establishment of microcrystalline structure, and hence also on the deformation behaviour at the microscopic scale

Angular Distribution of Auger Electrons Emitted through the Resonant Transfer and Excitation Process Following O⁵⁺+He Collisions

This Letter reports the first measurements of the angular distribution of Auger electrons emitted from the decay of the (1s2s2p2)3D O4+** doubly excited state formed predominantly through resonant transfer and excitation (RTE) in collisions of 13-MeV O5+ projectiles with He. The (1s2s2p2)3D angular distribution is strongly peaked along the beam direction, in agreement with recent calculations of the RTE angle-dependent impulse approximation. Furthermore, interference effects between the RTE and the elastic target direct-ionization channels are observed

Ab initio simulations of liquid NaSn alloys: Zintl anions and network formation

Using the Car-Parrinello technique, ab initio molecular dynamics simulations are performed for liquid NaSn alloys in five different compositions (20, 40, 50, 57 and 80 % sodium). The obtained structure factors agree well with the data from neutron scattering experiments. The measured prepeak in the structure factor is reproduced qualitatively for most compositions. The calculated and measured positions of all peaks show the same trend as function of the composition.\\ The dynamic simulations also yield information about the formation and stability of Sn$_4$ clusters (Zintl anions) in the liquid. In our simulations of compositions with 50 and 57 % sodium we observe the formation of networks of tin atoms. Thus, isolated tin clusters are not stable in such liquids. For the composition with 20 % tin only isolated atoms or dimers of tin appear, ``octet compounds'' of one Sn atom surrounded by 4 Na atoms are not observed.Comment: 12 pages, Latex, 3 Figures on reques

Electron-Electron Interactions in Transfer and Excitation in F⁸⁺ →₂ Collisions

We have measured projectile Auger electrons emitted after collisions of H-like F with H2. The cross sections for emission of KLL, KLM, KLN, and KLO Auger electrons show maxima as a function of the projectile energy. One maximum in the KLL emission cross section is due to resonant transfer and excitation. A second maximum in the cross section for KLL emission as well as the maxima in the emission cross section for the higher-n Auger electrons are attributed to a new transfer and excitation process. This involves excitation of a projectile electron by one target electron accompanied by the capture of a second target electron

Double Excitation of He by Fast Ions

Autoionization of He atoms following double excitation by electrons, protons, CQ+ (Q=4-6), and FQ+ (Q=7-9) ions has been studied. The electron-emission yields from the doubly excited 2s2(1S), 2s2p(1P), and 2p2(1P) states were measured at the reduced projectile energy of 1.5 MeV/nucleon for observation angles between 10°and 60°. The results indicate excitation to the 2s2(1S) and 2p2(1D) states increases as approximately Q3, while excitation to the 2s2p(1P) state varies as approximately Q2, where Q is the charge of the projectile. These charge dependences are significantly less than the Q4 dependence expected in the independent-electron model, suggesting the interaction between the two target electrons is important in creating the doubly excited states

Anomalous Quasiparticle Lifetime in Graphite: Band Structure Effects

We report ab initio calculation of quasiparticle lifetimes in graphite, as determined from the imaginary part of the self-energy operator within the GW aproximation. The inverse lifetime in the energy range from 0.5 to 3.5 eV above the Fermi level presents significant deviations from the quadratic behavior naively expected from Fermi liquid theory. The deviations are explained in terms of the unique features of the band structure of this material. We also discuss the experimental results from different groups and make some predictions for future experiments.Comment: 4 pages, 4 figures, submitted PR

Vaquita Face Extinction from Bycatch. Comment on Manjarrez-Bringas, N. et al., Lessons for Sustainable Development: Marine Mammal Conservation Policies and Its Social and Economic Effects.

We are among the scientists who have documented the environmental and ecological changes to the Upper Gulf of California following the reduction in the Colorado River’s flow. We object to any suggestion that our research supports Manjarrez-Bringas et al.’s conclusion that the decline in the Colorado River’s flow is the reason for the decline in the population of the endangered vaquita porpoise (Phocoena sinus). Manjarrez-Bringas et al.’s conclusions are incongruent with their own data, their logic is untenable, their analyses fail to consider current illegal fishing practices, and their recommendations are unjustified and misdirected. Vaquita face extinction because of bycatch, not because of the lack of river flow

Comment on Rojas-Bracho and Colleagues (2019): Unsubstantiated Claims Can Lead to Tragic Conservation Outcomes

The vaquita’s decline is a tragic story indeed. However, the lack of action to prevent the extinction of this species is not due to unsubstantiated claims and scientific uncertainty

Social inequalities in stage at diagnosis of rectal but not in colonic cancer: a nationwide study

We investigated stage at diagnosis in relation to socioeconomic status (SES) among 15 274 patients with colorectal adenocarcinoma diagnosed in 1996–2004 nationwide in Denmark. The effect of SES on the risk of being diagnosed with distant metastasis was analysed using logistic regression models. A reduction in the risk of being diagnosed with distant metastasis was seen in elderly rectal cancer patients with high income, living in owner–occupied housing and living with a partner. Among younger rectal cancer patients, a reduced risk was seen in those having long education. No social gradient was found among colon cancer patients. The social gradient found in rectal cancer patients was significantly different from the lack of association found among colon cancer patients. There are socioeconomic inequalities in the risk of being diagnosed with distant metastasis of a rectal, but not a colonic, cancer. The different risk profile of these two cancers may reflect differences in symptomatology