2,092 research outputs found
Diffusion and jump-length distribution in liquid and amorphous CuZr
Using molecular dynamics simulation, we calculate the distribution of atomic
jum ps in CuZr in the liquid and glassy states. In both states
the distribution of jump lengths can be described by a temperature independent
exponential of the length and an effective activation energy plus a
contribution of elastic displacements at short distances. Upon cooling the
contribution of shorter jumps dominates. No indication of an enhanced
probability to jump over a nearest neighbor distance was found. We find a
smooth transition from flow in the liquid to jumps in the g lass. The
correlation factor of the diffusion constant decreases with decreasing
temperature, causing a drop of diffusion below the Arrhenius value, despite an
apparent Arrhenius law for the jump probability
Validation of Puck’s failure criterion for CFRP composites in the cryogenic regime
For future launch vehicles, lightweight cryogenic pressure vessels are required for storage of the liquid hydrogen fuel. For their structural assessment, reliable and validated failure criteria are required. The present contribution provides an overview over the results of an ongoing research activity concerned with the validation of Puck’s composite failure criterion in the cryogenic regime. In a first step, an experimental investigation on unidirectionally fiber reinforced materials on coupon level has been performed. This test campaign has been complemented by tests on small breadboard-type specimens with an angle-ply stacking sequence. The specimens were featuring holes and tapered sections to provide stress gradients and concentrations. Test were performed at ambient temperature and in a liquid Helium environment. Puck’s failure criterion has been applied and found to provide a good prediction of first ply failure in both environments
Sparse random matrices and vibrational spectra of amorphous solids
A random matrix approach is used to analyze the vibrational properties of
amorphous solids. We investigated a dynamical matrix M=AA^T with non-negative
eigenvalues. The matrix A is an arbitrary real NxN sparse random matrix with n
independent non-zero elements in each row. The average values =0 and
dispersion =V^2 for all non-zero elements. The density of vibrational
states g(w) of the matrix M for N,n >> 1 is given by the Wigner quarter circle
law with radius independent of N. We argue that for n^2 << N this model can be
used to describe the interaction of atoms in amorphous solids. The level
statistics of matrix M is well described by the Wigner surmise and corresponds
to repulsion of eigenfrequencies. The participation ratio for the major part of
vibrational modes in three dimensional system is about 0.2 - 0.3 and
independent of N. Together with term repulsion it indicates clearly to the
delocalization of vibrational excitations. We show that these vibrations spread
in space by means of diffusion. In this respect they are similar to diffusons
introduced by Allen, Feldman, et al., Phil. Mag. B 79, 1715 (1999) in amorphous
silicon. Our results are in a qualitative and sometimes in a quantitative
agreement with molecular dynamic simulations of real and model glasses.Comment: 24 pages, 7 figure
A model for the infrared-radio correlation of main-sequence galaxies at GHz frequencies and its dependence on redshift and stellar mass
The infrared-radio correlation (IRRC) of star-forming galaxies can be used to
estimate their star formation rate (SFR) based on the radio continuum
luminosity at MHz-GHz frequencies. For application in future deep radio
surveys, it is crucial to know whether the IRRC persists at high redshift z.
Delvecchio et al. (2020) observed that the 1.4 GHz IRRC correlation of
star-forming galaxies is nearly z-invariant up to z~4, but depends strongly on
the stellar mass M_star. This should be taken into account for SFR calibrations
based on radio luminosity. To understand the physical cause of the
M_star-dependence of the IRRC and its properties at higher z, we construct a
phenomenological model for galactic radio emission involving magnetic fields
generated by a small-scale dynamo, a steady-state cosmic ray population, as
well as observed scaling relations that reduce the number of free parameters.
The best agreement between the model and the characteristics of the IRRC
observed by Delvecchio et al. (2020) is found when the efficiency of the
SN-driven turbulence is 5 % and when saturation of the small-scale dynamo
occurs once 10 % of the kinetic energy is converted into magnetic energy. The
observed dependence of the IRRC on M_star and z can be reproduced with our
model. For galaxies with intermediate to high (M_star ~ 10^9.5 - 10^11 M_sun)
stellar masses, our model results in a IRRC which is nearly independent of z.
For galaxies with lower masses (M_star ~ 10^8.5 M_sun), we find that the
IR-to-radio flux ratio increases with increasing redshift. This matches the
observational data in that mass bin which, however, only extends to z~1.5. The
increase of the IR-to-radio flux ratio for low-mass galaxies at z>1.5 that is
predicted by our model could be tested with future deep radio observations.Comment: 18 pages, 17 figures, submitted to A&
Voronoi-Delaunay analysis of normal modes in a simple model glass
We combine a conventional harmonic analysis of vibrations in a one-atomic
model glass of soft spheres with a Voronoi-Delaunay geometrical analysis of the
structure. ``Structure potentials'' (tetragonality, sphericity or perfectness)
are introduced to describe the shape of the local atomic configurations
(Delaunay simplices) as function of the atomic coordinates. Apart from the
highest and lowest frequencies the amplitude weighted ``structure potential''
varies only little with frequency. The movement of atoms in soft modes causes
transitions between different ``perfect'' realizations of local structure. As
for the potential energy a dynamic matrix can be defined for the ``structure
potential''. Its expectation value with respect to the vibrational modes
increases nearly linearly with frequency and shows a clear indication of the
boson peak. The structure eigenvectors of this dynamical matrix are strongly
correlated to the vibrational ones. Four subgroups of modes can be
distinguished
Ice XII in its second regime of metastability
We present neutron powder diffraction results which give unambiguous evidence
for the formation of the recently identified new crystalline ice phase[Lobban
et al.,Nature, 391, 268, (1998)], labeled ice XII, at completely different
conditions. Ice XII is produced here by compressing hexagonal ice I_h at T =
77, 100, 140 and 160 K up to 1.8 GPa. It can be maintained at ambient pressure
in the temperature range 1.5 < T < 135 K. High resolution diffraction is
carried out at T = 1.5 K and ambient pressure on ice XII and accurate
structural properties are obtained from Rietveld refinement. At T = 140 and 160
K additionally ice III/IX is formed. The increasing amount of ice III/IX with
increasing temperature gives an upper limit of T ~ 150 K for the successful
formation of ice XII with the presented procedure.Comment: 3 Pages of RevTeX, 3 tables, 3 figures (submitted to Physical Review
Letters
Continuum limit of amorphous elastic bodies: A finite-size study of low frequency harmonic vibrations
The approach of the elastic continuum limit in small amorphous bodies formed
by weakly polydisperse Lennard-Jones beads is investigated in a systematic
finite-size study. We show that classical continuum elasticity breaks down when
the wavelength of the sollicitation is smaller than a characteristic length of
approximately 30 molecular sizes. Due to this surprisingly large effect
ensembles containing up to N=40,000 particles have been required in two
dimensions to yield a convincing match with the classical continuum predictions
for the eigenfrequency spectrum of disk-shaped aggregates and periodic bulk
systems. The existence of an effective length scale \xi is confirmed by the
analysis of the (non-gaussian) noisy part of the low frequency vibrational
eigenmodes. Moreover, we relate it to the {\em non-affine} part of the
displacement fields under imposed elongation and shear. Similar correlations
(vortices) are indeed observed on distances up to \xi~30 particle sizes.Comment: 28 pages, 13 figures, 3 table
Interatomic-Coulombic-decay-induced recapture of photoelectrons in helium dimers
We investigate the onset of photoionization shakeup induced interatomic
Coulombic decay (ICD) in He2 at the He+*(n = 2) threshold by detecting two He+
ions in coincidence. We find this threshold to be shifted towards higher
energies compared to the same threshold in the monomer. The shifted onset of
ion pairs created by ICD is attributed to a recapture of the threshold
photoelectron after the emission of the faster ICD electron.Comment: 5 Pages, 2 Figure
A measurement of the evolution of Interatomic Coulombic Decay in the time domain
During the last 15 years a novel decay mechanism of excited atoms has been
discovered and investigated. This so called ''Interatomic Coulombic Decay''
(ICD) involves the chemical environment of the electronically excited atom: the
excitation energy is transferred (in many cases over long distances) to a
neighbor of the initially excited particle usually ionizing that neighbor. It
turned out that ICD is a very common decay route in nature as it occurs across
van-der-Waals and hydrogen bonds. The time evolution of ICD is predicted to be
highly complex, as its efficiency strongly depends on the distance of the atoms
involved and this distance typically changes during the decay. Here we present
the first direct measurement of the temporal evolution of ICD using a novel
experimental approach.Comment: 6 pages, 4 figures, submitted to PR
Crystal-like high frequency phonons in the amorphous phases of solid water
The high frequency dynamics of low- (LDA) and high-density amorphous-ice
(HDA) and of cubic ice (I_c) has been measured by inelastic X-ray Scattering
(IXS) in the 1-15 nm^{-1} momentum transfer (Q) range. Sharp phonon-like
excitations are observed, and the longitudinal acoustic branch is identified up
to Q = 8nm^{-1} in LDA and I_c and up to 5nm^{-1} in HDA. The narrow width of
these excitations is in sharp contrast with the broad features observed in all
amorphous systems studied so far. The "crystal-like" behavior of amorphous
ices, therefore, implies a considerable reduction in the number of decay
channels available to sound-like excitations which is assimilated to low local
disorder.Comment: 4 pages, 3 figure
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