Decomposition and primary crystallization in undercooled Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 melts

Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 bulk metallic glasses were prepared by cooling the melt with a rate of about 10 K/s and investigated with respect to their chemical and structural homogeneity by atom probe field ion microscopy and transmission electron microscopy. The measurements on these slowly cooled samples reveal that the alloy exhibits phase separation in the undercooled liquid state. Significant composition fluctuations are found in the Be and Zr concentration but not in the Ti, Cu, and Ni concentration. The decomposed microstructure is compared with the microstructure obtained upon primary crystallization, suggesting that the nucleation during primary crystallization of this bulk glass former is triggered by the preceding diffusion controlled decomposition in the undercooled liquid state

Magnetic field induced finite size effect in type-II superconductors

We explore the occurrence of a magnetic field induced finite size effect on the specific heat and correlation lengths of anisotropic type-II superconductors near the zero field transition temperature Tc. Since near the zero field transition thermal fluctuations are expected to dominate and with increasing field strength these fluctuations become one dimensional, whereupon the effect of fluctuations increases, it appears unavoidable to account for thermal fluctuations. Invoking the scaling theory of critical phenomena it is shown that the specific heat data of nearly optimally doped YBa2Cu3O7-x are inconsistent with the traditional mean-field and lowest Landau level predictions of a continuous superconductor to normal state transition along an upper critical field Hc2(T). On the contrary, we observe agreement with a magnetic field induced finite size effect, whereupon even the correlation length longitudinal to the applied field H cannot grow beyond the limiting magnetic length L(H). It arises because with increasing magnetic field the density of vortex lines becomes greater, but this cannot continue indefinitely. L(H) is then roughly set on the proximity of vortex lines by the overlapping of their cores. Thus, the shift and the rounding of the specific heat peak in an applied field is traced back to a magnetic field induced finite size effect in the correlation length longitudinal to the applied field.Comment: 8 pages, 4 figure

Crystallization of Carbon Oxygen Mixtures in White Dwarf Stars

We determine the phase diagram for dense carbon/ oxygen mixtures in White Dwarf (WD) star interiors using molecular dynamics simulations involving liquid and solid phases. Our phase diagram agrees well with predictions from Ogata et al. and Medin and Cumming and gives lower melting temperatures than Segretain et al. Observations of WD crystallization in the globular cluster NGC 6397 by Winget et al. suggest that the melting temperature of WD cores is close to that for pure carbon. If this is true, our phase diagram implies that the central oxygen abundance in these stars is less than about 60%. This constraint, along with assumptions about convection in stellar evolution models, limits the effective S factor for the $^{12}$C($\alpha,\gamma$)$^{16}$O reaction to S_{300} <= 170 keV barns.Comment: 4 pages, 2 figures, Phys. Rev. Lett. in pres

Magnetic field induced 3D to 1D crossover in type II superconductors

We review and analyze magnetization and specific heat investigations on type-II superconductors which uncover remarkable evidence for the magnetic field induced fnite size effect and the associated 3D to 1D crossover which enhances thermal fluctuations.Comment: 26 pages, 19 figure

A Comparison of Phycocyanins from Three Different Species of Cyanobacteria Employing Resonance-Enhanced Coherent Anti-Stokes Raman Spectroscopy

Resonance-enhanced coherent anti-Stokes Raman spectra are recorded for monomers and trimers of phycocyanin from three different cyanobacteria: Westiellopsis prolifica, Mastigocladus laminosus and Spirulina platensis. It is shown that upon aggregation from monomer to trimer the electronic structures of both the α84 and β84 chromophores are changed. The spectra of the trimers originating from S. platensis and M. laminosus are very similar to each other, but distinctly different from the spectrum of W. prolifica

Unravelling the Mysteries of the Leo Ring: An Absorption Line Study of an Unusual Gas Cloud

Since the 1980's discovery of the large (2x10^9 Msun) intergalactic cloud known as the Leo Ring, this object has been the center of a lively debate about its origin. Determining the origin of this object is still important as we develop a deeper understanding of the accretion and feedback processes that shape galaxy evolution. We present HST/COS observations of three sightlines near the Ring, two of which penetrate the high column density neutral hydrogen gas visible in 21 cm observations of the object. These observations provide the first direct measurement of the metallicity of the gas in the Ring, an important clue to its origins. Our best estimate of the metallicity of the ring is ~10% Zsun, higher than expected for primordial gas but lower than expected from an interaction. We discuss possible modifications to the interaction and primordial gas scenarios that would be consistent with this metallicity measurement.Comment: 11 pages, 7 figures, accepted Ap

Oxidation and crystallization of an amorphous Zr60Al15Ni25 alloy

The amorphous ternary metallic alloy Zr60Al15Ni25 was oxidized in dry oxygen in the temperature range 310 ±C to 410 ±C. Rutherford backscattering (RBS) and cross-sectional transmission electron microscopy (TEM) studies suggest that during this treatment an amorphous layer of zirconium-aluminum-oxide is formed at the surface. Nickel was depleted in the oxide and enriched in the amorphous alloy near the interface. The oxide layer thickness grows parabolically with annealing duration, with a transport constant of 2.8 x 10^-5 m^2/s x exp(-1.7 eV/kT). The oxidation rate may be controlled by the diffusion of Ni in the amorphous alloy. At later stages of the oxidation process, precipitates of nanocrystalline ZrO2 appear in the oxide near the interface. Finally, two intermetallic phases nucleate and grow simultaneously in the alloy, one at the interface and one within the alloy. An explanation involving preferential oxidation is proposed

Diffusion of Neon in White Dwarf Stars

Sedimentation of the neutron rich isotope $^{22}$Ne may be an important source of gravitational energy during the cooling of white dwarf stars. This depends on the diffusion constant for $^{22}$Ne in strongly coupled plasma mixtures. We calculate self-diffusion constants $D_i$ from molecular dynamics simulations of carbon, oxygen, and neon mixtures. We find that $D_i$ in a mixture does not differ greatly from earlier one component plasma results. For strong coupling (coulomb parameter $\Gamma>$ few), $D_i$ has a modest dependence on the charge $Z_i$ of the ion species, $D_i \propto Z_i^{-2/3}$. However $D_i$ depends more strongly on $Z_i$ for weak coupling (smaller $\Gamma$). We conclude that the self-diffusion constant $D_{\rm Ne}$ for $^{22}$Ne in carbon, oxygen, and neon plasma mixtures is accurately known so that uncertainties in $D_{\rm Ne}$ should be unimportant for simulations of white dwarf cooling.Comment: 6 pages, 5 figures, minor changes, Phys. Rev. E in pres

Long-range entanglement generation via frequent measurements

A method is introduced whereby two non-interacting quantum subsystems, that each interact with a third subsystem, are entangled via repeated projective measurements of the state of the third subsystem. A variety of physical examples are presented. The method can be used to establish long range entanglement between distant parties in one parallel measurement step, thus obviating the need for entanglement swapping.Comment: 7 pages, incl. 2 figures. v2: added a few small clarifications and a referenc