A mechanistic perspective on plastically flexible coordination polymers

Mechanical flexibility in single crystals of covalently bound materials is a fascinating and poorly understood phenomenon. We present here the first example of a plastically flexible one‐dimensional (1D) coordination polymer. The compound [Zn(μ‐Cl)2(3,5‐dichloropyridine)2]n is flexible over two crystallographic faces. Remarkably, the single crystal remains intact when bent to 180°. A combination of microscopy, diffraction, and spectroscopic studies have been used to probe the structural response of the crystal lattice to mechanical bending. Deformation of the covalent polymer chains does not appear to be responsible for the observed macroscopic bending. Instead, our results suggest that mechanical bending occurs by displacement of the coordination polymer chains. Based on experimental and theoretical evidence, we propose a new model for mechanical flexibility in 1D coordination polymers. Moreover, our calculations propose a cause of the different mechanical properties of this compound and a structurally similar elastic material

In vitro evidence for senescent multinucleated melanocytes as a source for tumor-initiating cells

Oncogenic signaling in melanocytes results in oncogene-induced senescence (OIS), a stable cell-cycle arrest frequently characterized by a bi- or multinuclear phenotype that is considered as a barrier to cancer progression. However, the long-sustained conviction that senescence is a truly irreversible process has recently been challenged. Still, it is not known whether cells driven into OIS can progress to cancer and thereby pose a potential threat. Here, we show that prolonged expression of the melanoma oncogene N-RAS61K in pigment cells overcomes OIS by triggering the emergence of tumor-initiating mononucleated stem-like cells from senescent cells. This progeny is dedifferentiated, highly proliferative, anoikis-resistant and induces fast growing, metastatic tumors. Our data describe that differentiated cells, which are driven into senescence by an oncogene, use this senescence state as trigger for tumor transformation, giving rise to highly aggressive tumor-initiating cells. These observations provide the first experimental in vitro evidence for the evasion of OIS on the cellular level and ensuing transformation

Flux-quantum-modulated Kondo conductance in a multielectron quantum dot

We investigate a lateral semiconductor quantum dot with a large number of electrons in the limit of strong coupling to the leads. A Kondo effect is observed and can be tuned in a perpendicular magnetic field. This Kondo effect does not exhibit Zeeman splitting. It shows a modulation with the periodicity of one flux quantum per dot area at low temperatures. The modulation leads to a novel, strikingly regular stripe pattern for a wide range in magnetic field and number of electrons.Comment: 4 pages, 5 figure

Quantum dots with two electrons: Singlet-triplet transitions

The magnetic character of the ground-state of two electrons on a double quantum dot, connected in series to left and right single-channel leads, is considered. By solving exactly for the spectrum of the two interacting electrons, it is found that the coupling to the continuum of propagating states on the leads, in conjunction with the electron-electron interactions, may result in a delocalization of the bound state of the two electrons. This, in turn, reduces significantly the range of the Coulomb interaction parameters over which singlet-triplet transitions can be realized. It is also found that the coupling to the leads favors the singlet ground-state.Comment: 8 pages, submitted to Phys. Rev.

Low-temperature nonequilibrium transport in a Luttinger liquid

The temperature-dependent nonlinear conductance for transport of a Luttinger liquid through a barrier is calculated in the nonperturbative regime for $g=1/2-\epsilon$, where $g$ is the dimensionless interaction constant. To describe the low-energy behavior, we perform a leading-log summation of all diagrams contributing to the conductance which is valid for $|\epsilon| << 1$. With increasing external voltage, the asymptotic low-temperature behavior displays a turnover from the $T^{2/g-2}$ to a universal $T^2$ law.Comment: 13 pages RevTeX 3.0, accepted by Physical Review

Anti-Kondo resonance in transport through a quantum wire with a side-coupled quantum dot

An interacting quantum dot side-coupled to a perfect quantum wire is studied. Transport through the quantum wire is investigated by using an exact sum rule and the slave-boson mean field treatment. It is shown that the Kondo effect provides a suppression of the transmission due to the destructive interference of the ballistic channel and the Kondo channel. At finite temperatures, anti-resonance behavior is found as a function of the quantum dot level position, which is interpreted as a crossover from the high temperature Kondo phase to the low temperature charge fluctuation phase.Comment: 4 pages Revtex, 3 eps figure

Coulomb effects in granular materials at not very low temperatures

We consider effects of Coulomb interaction in a granular normal metal at not very low temperatures suppressing weak localization effects. In this limit calculations with the initial electron Hamiltonian are reduced to integrations over a phase variable with an effective action, which can be considered as a bosonization for the granular metal. Conditions of the applicability of the effective action are considered in detail and importance of winding numbers for the phase variables is emphasized. Explicit calculations are carried out for the conductivity and the tunneling density of states in the limits of large $g\gg 1$ and small $g\ll 1$ tunnelling conductances. It is demonstrated for any dimension of the array of the grains that at small $g$ the conductivity and the tunnelling density of states decay with temperature exponentially. At large $g$ the conductivity also decays with decreasing the temparature and its temperature dependence is logarithmic independent of dimensionality and presence of a magnetic field. The tunnelling density of states for $g\gg 1$ is anomalous in any dimension but the anomaly is stronger than logarithmic in low dimensions and is similar to that for disordered systems. The formulae derived are compared with existing experiments. The logarithmic behavior of the conductivity at large $g$ obtained in our model can explain numerous experiments on systems with a granular structure including some high $T_{c}$ materials.Comment: 30 page

Low temperature transport in AC-driven Quantum Dots in the Kondo regime

We present a fully nonequilibrium calculation of the low temperature transport properties of a quantum dot in the Kondo regime when an AC potential is applied to the gate voltage. We solve a time dependent Anderson model with finite on-site Coulomb interaction. The interaction self-energy is calculated up to second order in perturbation theory in the on-site interaction, in the context of the Keldysh non-equilibrium technique, and the effect of the AC voltage is taken into account exactly for all ranges of AC frequencies and AC intensities. The obtained linear conductance and time-averaged density of states of the quantum dot evolve in a non trivial way as a function of the AC frequency and AC intensity of the harmonic modulation.Comment: 30 pages,7 figure

Non-equilibrium Kondo effect in asymmetrically coupled quantum dot

The quantum dot asymmetrically coupled to the external leads has been analysed theoretically by means of the equation of motion (EOM) technique and the non-crossing approximation (NCA). The system has been described by the single impurity Anderson model. To calculate the conductance across the device the non-equilibrium Green's function technique has been used. The obtained results show the importance of the asymmetry of the coupling for the appearance of the Kondo peak at nonzero voltages and qualitatively explain recent experiments.Comment: 7 pages, 6 figures, Physical Review B (accepted for publication