Charge storage in nanotubes: the case of a 2-1 electrolyte

We consider a 2-1 electrolyte in contact with a narrow nanotube, which only allows one-dimensional storage along the axis. The asymmetry does not allow an a priori definition of the potential of zero charge; instead, the natural reference is the electrode potential at which both ions have the same electrochemical potential; the value of the latter can serve as a measure of ionophilicity. Near this potential, ionophobic tubes are filled with a dilute gas, ionophilic tubes are filled with a one-dimensional solid containing about the same number of the divalent ions and the monovalent counterions, a structure that is stabilized by a strong screening of the Coulomb interaction by an induced counter charge on the walls of the tube. The filling of the tube by the application of an electrode potential exhibits a complicated pattern of interactions between the two kinds of ions.Comment: 7 pages, 6 figure

A new wide band time normaliser circuit for bunch position measurements with high bandwidth and wide dynamic range

Trajectory and closed orbit measurements are vital for commissioning and operation of accelerators. With the push for high luminosities at modern colliders, the azimuthal bunch distribution becomes very complex, so that various phenomena (beam-beam forces, wake fields) strongly affect the orbits of individual bunches. Hence a system with high bandwidth capable of measuring the transverse position of any bunch is desirable. With the current techniques a bandwidth above 100 MHz can only be achieved by individual integration and digitisation of the pick-up signals. The drawback of such an approach is the limited dynamic range of typically 30 dB. In the context of the development of an orbit system for the LHC at CERN a high bandwidth could be achieved by extending the principle of phase normalisation to a wide band time normalisation of the position monitor signals. The circuit described in this paper (Wide band time normalizer) combines the signals of two pick-up electrodes with different delays and converts the beam position information into a pulse width modulation of the digital output signal. This way a bandwidth of more than 40 MHz and a dynamic range of about 50 dB could be achieved. The paper introduces the requirements for the LHC orbit system, compares various technical solutions and finally explains the working principle of the wide band time normalizer including some laboratory tests results

The Measurement of Chromaticity via a Head-Tail Phase Shift

The most common method of measuring the chromaticities of a circular machine is to measure the betatron tune as a function of the beam energy and then to calculate the chromaticity from the resulting gradient. Even as a simple difference method between two machine energies this method does not allow instantaneous measurements, for instance during energy ramping or beta squeezing. In preparation for the LHC a new approach has been developed which uses the energy spread in the beams for a chromaticity measurement. Transverse oscillations are excited with a single kick and the chromaticity is calculated from the phase difference of the individually sampled head and tail motions of a single bunch. Using this method the chromaticity can be calculated using the data from only one synchrotron period (about 15-50 msec in the case of the LHC). This paper describes the theory behind this technique, two different experimental set-ups and the results of measurements carried out in the SPS

Real-Time Monitoring of Beam-Beam Modes at LEP

By slightly exciting one of two colliding bunches in LEP, it is possible to enhance the eigenfrequencies of the resonant system of the two bunches coupled by the space charge force. The LEP Qmeter has been adapted to detect, among these excited frequencies, the so called s- and p- modes, whose distance is proportional to the luminosity. A real time display of these quantities provides the Operators with an effective way of finely optimizing the luminosity

Understanding the structure and reactivity of NiCu nanoparticles: An atomistic model

The structure of bimetallic NiCu nanoparticles (NP) is investigated as a function of their composition and size by means of Lattice MonteCarlo (LMC) and molecular dynamics (MD) simulations. According to our results, copper segregation takes place at any composition of the particles. We found that this feature is not size-dependent. In contrast, nickel segregation depends on the NP size. When the size increases, Ni atoms tend to remain in the vicinity of the surface and deeper. For smaller NPs, Ni atoms are located at the surface as well. Our results also showed that most of the metal atoms segregated at the surface area were found to decorate edges and/or form islands. Our findings agree qualitatively with the experimental data found in the literature. In addition, we comment on the reactivity of these nanoparticles.Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Belletti, Gustavo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaFil: Shermukhamedov, S. A.. Kazan National Research Technological University; RusiaFil: Glukhov, D. V.. Kazan National Research Technological University; RusiaFil: Santos, Elizabeth del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Institute of Theoretical Chemistry; Alemania. Universitat Ulm; AlemaniaFil: Schmickler, Wolfgang. Universitat Ulm; Alemania. Institute of Theoretical Chemistry; AlemaniaFil: Nazmutdinov, Renat. Kazan National Research Technological University; Rusi

Luminosity optimisation using beam-beam deflections at LEP

In maximizing the performance of the LEP electron-positron collider it is important to ensure that the beams collide head-on at the interaction points. The deflection of the beams due to the beam-beam interactions has been measured using orbit monitors located close to the interaction points. The dependence of the beam-beam deflection on the transverse distance between the beams has been used to optimise the overlap of the beams in the vertical plane and to measure the beam sizes at the interaction points

CdTe Photoconductors for LHC Luminosity Monitoring

Detectors using CdTe photoconductors are being used with great success in LEP to monitor the vertical beam emittance. They can withstand tremendous irradiation, of up to 10^13 Gy, from hard X-rays. For the LHC, monitors measuring the relative luminosity will be placed inside absorbers located 142 m from the interaction points, where they will receive about 10^8 Gy per year due to gamma radiation and neutrons. Thick-polycristalline-CdTe detectors were recently tested for speed, sensitivity and radiation resistance before and after receiving up to 10^15 neutrons per cm^2. The test results are presented here, along with a comparison of the calculated charge deposition in Silicon, Diamond and GaAs detectors

Redox Entropy of Plastocyanin: Developing a Microscopic View of Mesoscopic Polar Solvation

We report applications of analytical formalisms and Molecular Dynamics (MD) simulations to the calculation of redox entropy of plastocyanin metalloprotein in aqueous solution. The goal of our analysis is to establish critical components of the theory required to describe polar solvation at the mesoscopic scale. The analytical techniques include a microscopic formalism based on structure factors of the solvent dipolar orientations and density and continuum dielectric theories. The microscopic theory employs the atomistic structure of the protein with force-field atomic charges and solvent structure factors obtained from separate MD simulations of the homogeneous solvent. The MD simulations provide linear response solvation free energies and reorganization energies of electron transfer in the temperature range 280--310 K. We found that continuum models universally underestimate solvation entropies, and a more favorable agreement is reported between the microscopic calculations and MD simulations. The analysis of simulations also suggests that difficulties of extending standard formalisms to protein solvation are related to the inhomogeneous structure of the solvation shell at the protein-water interface combining islands of highly structured water around ionized residues along with partial dewetting of hydrophobic patches. Quantitative theories of electrostatic protein hydration need to incorporate realistic density profile of water at the protein-water interface.Comment: 17 pages, 12 figure

ARTUS: A Rhic TUne monitor System

This report describes various measurement techniques and their possible realizations

Study of the Stabilization to the Nanometer Level of Mechanical Vibrations of the CLIC Main Beam

Original publication available at http://www.jacow.org/International audienceTo reach the design luminosity of CLIC, the movements of the quadrupoles should be limited to the nanometre level in order to limit the beam size and emittance growth. Below 1 Hz, the movements of the main beam quadrupoles will be corrected by a beambased feedback. But above 1 Hz, the quadrupoles should be mechanically stabilized. A collaboration effort is ongoing between several institutes to study the feasibility of the "nanostabilization" of the CLIC quadrupoles. The study described in this paper covers the characterization of independent measuring techniques including optical methods to detect nanometre sized displacements and analyze the vibrations. Actuators and feedback algorithms for sub-nanometre movements of magnets with a mass of more than 400 kg are being developed and tested. Input is given to the design of the quadrupole magnets, the supports and alignment system in order to limit the amplification of the vibration sources at resonant frequencies. A full scale mock-up integrating all these features is presently under design. Finally, a series of experiments in accelerator environments should demonstrate the feasibility of the nanometre stabilization