Kondo Lattice without Nozieres Exhaustion Effect

We discuss the properties of layered Anderson/Kondo lattices with metallic electrons confined in 2D xy planes and local spins in insulating layers forming chains in z direction. Each spin in this model possesses its own 2D Kondo cloud, so that the Nozieres' exhaustion problem does not occur. The excitation spectrum of the model is gapless both in charge and spin sectors. The disordered phases and possible experimental realizations of the model are briefly discussed.Comment: 4 pages, 3 figure

Signatures of electron-electron correlations in the optical spectra of α\alpha-(BEDT-TTF)2M_2MHg(SCN)4_4 (MM=NH4_4 and Rb)

We interpret the optical spectra of $\alpha$-(BEDT-TTF)$_2M$Hg(SCN)$_4$ (M=NH$_4$ and Rb) in terms of a 1/4 filled metallic system close to charge ordering and show that in the conductivity spectra of these compounds a fraction of the spectral weight is shifted from the Drude-peak to higher frequencies due to strong electronic correlations. Analyzing the temperature dependence of the electronic parameters, we distinguish between different aspects of the influence of electronic correlations on optical properties. We conclude, that the correlation effects are slightly weaker in the NH$_4$ compound compared to the Rb one.Comment: Proceedings ISCOM0

Upper critical field study in the organic superconductor β′′\beta''-(ET)2_{2}SF5_{5}CH2_{2}CF2_{2}SO3_{3} : Possibility of Fulde-Ferrell-Larkin-Ovchinnikov state

We report upper critical field measurements in the metal-free-all-organic superconductor $\beta''$-(ET)$_{2}$SF$_{5}$CH$_{2}$CF$_{2}$SO$_{3}$ obtained from measuring the in-plane penetration depth using the tunnel diode oscillator technique. For magnetic field applied parallel to the conducting planes the low temperature upper critical fields are found to exceed the Pauli limiting field calculated by using a semi-empirical method. Furthermore, we found a signature that could be the phase transition between the superconducting vortex state and the Fulde-Ferrell-Larkin-Ovchinnikov state in the form of a kink just below the upper critical field and only at temperatures below 1.23 K.Comment: 4 pages, 6 figure

Test for interlayer coherence in a quasi-two-dimensional superconductor

Peaks in the magnetoresistivity of the layered superconductor $\kappa$-(BEDT-TTF)$_2$Cu(NCS)$_2$, measured in fields $\leq 45$ T applied within the layers, show that the Fermi surface is extended in the interlayer direction and enable the interlayer transfer integral ($t_{\perp} \approx 0.04$ meV) to be deduced. However, the quasiparticle scattering rate $\tau^{-1}$ is such that $\hbar/\tau \sim 6t_{\perp}$, implying that $\kappa$-(BEDT-TTF)$_2$Cu(NCS)$_2$ meets the criterion used to identify interlayer incoherence. The applicability of this criterion to anisotropic materials is thus shown to be questionable.Comment: 5 pages, 4 figure

Comparison of the Fermi-surface topologies of kappa-(BEDT-TTF)_2 Cu(NCS)_2 and its deuterated analogue

We have measured details of the quasi one-dimensional Fermi-surface sections in the organic superconductor kappa-(BEDT-TTF)_2 Cu(NCS)_2 and its deuterated analogue using angle-dependent millimetre-wave techniques. There are significant differences in the corrugations of the Fermi surfaces in the deuterated and undeuterated salts. We suggest that this is important in understanding the inverse isotope effect, where the superconducting transition temperature rises on deuteration. The data support models for superconductivity which invoke electron-electron interactions depending on the topological properties of the Fermi surface

Effect of a chitosan additive to a Sn2+-containing toothpaste on its anti-erosive/anti-abrasive efficacy—a controlled randomised in situ trial

Objectives: It is well known that Sn2+ is a notable anti-erosive agent. There are indications that biopolymers such as chitosan can enhance the effect of Sn2+, at least in vitro. However, little information exists about their anti-erosive/anti-abrasive in situ effects. In the present in situ study, the efficacy of Sn2+-containing toothpastes in the presence or absence of chitosan was tested. Methods: Ten subjects participated in the randomised crossover study, wearing mandibular appliances with human enamel specimens. Specimens were extraorally demineralised (7days, 0.5% citric acid, pH 2.6; 6 × 2min/day) and intraorally exposed to toothpaste suspensions (2 × 2min/day). Within the suspension immersion time, one half of the specimens were additionally brushed intraorally with a powered toothbrush (5s, 2.5N). Tested preparations were a placebo toothpaste (negative control), two experimental toothpastes (F/Sn = 1,400ppm F−, 3,500ppm Sn2+; F/Sn/chitosan = 1,400ppm F−, 3,500ppm Sn2+, 0.5% chitosan) and an SnF2-containing gel (positive control, GelKam = 3,000ppm Sn2+, 1,000ppm F−). Substance loss was quantified profilometrically (μm). Results: In the placebo group, tissue loss was 11.2 ± 4.6 (immersion in suspension) and 17.7 ± 4.7 (immersion in suspension + brushing). Immersion in each Sn2+-containing suspension significantly reduced tissue loss (p ≤ 0.01); after immersion in suspension + brushing, only the treatments with GelKam (5.4 ± 5.5) and with F/Sn/chitosan (9.6 ± 5.6) significantly reduced loss [both p ≤ 0.05 compared to placebo; F/Sn 12.8 ± 6.4 (not significant)] Conclusion: Chitosan enhanced the efficacy of the Sn2+-containing toothpaste as an anti-erosive/anti-abrasive agent. Clinical relevance: The use of Sn2+- and chitosan-containing toothpaste is a good option for symptomatic therapy in patients with regular acid impacts