Appropriateness of Management Zones for Characterizing Spatial Variability of Soil Properties and Irrigated Corn Yields across Years

Recent precision-agriculture research has focused on use of management zones (MZ) as a method for variable application of inputs like N. The objectives of this study were to determine (i) if landscape attributes could be aggregated into MZthat characterize spatial varia- tion in soil chemical properties and corn yields and (ii) if temporal variability affects expression of yield spatial variability. This work was conducted on an irrigated cornfield near Gibbon, NE. Five landscape attributes, including a soil brightness image (red, green, and blue bands), elevation, and apparent electrical conductivity, were acquired for the field.Ageoreferenced soil-sampling scheme was used to determine soil chemical properties (soil pH, electrical conductivity, P, and organic matter). Georeferenced yield monitor data were collected for five (1997–2001) seasons. The five landscape attributes were aggregated into four MZ using principal-component analysis of landscape attributes and unsupervised classification of principal-component scores. All of the soil chemical properties differed among the four MZ. While yields were observed to differ by up to 25% between the highest- and lowest-yielding MZ in three of five seasons, receiving average precipitation, less-pronounced (≤5%) differences were noted among the same MZ in the driest and wettest seasons. This illustrates the significant role temporal variability plays in altering yield spatial variability, even under irrigation. Use of MZ for variable application tem, of inputs like N would only have been appropriate for this field in three out of the five seasons, seriously restricting the use of this approach under variable environmental conditions

Groundwater Discharge Characteristics for Selected Streams within the Loup River Basin, Nebraska, 2014–16

Streams in the Loup River Basin are sensitive to groundwater withdrawals because of the close hydrologic connection between groundwater and surface water. Groundwater discharge is the primary component of streamflow in the Loup River Basin and constitutes more than 90 percent of streamflow in the central part of the Sand Hills. To improve the understanding of geologic controls and various climatic and land-use changes on groundwater discharge, the United States Geological Survey (USGS), in cooperation with the Upper Loup Natural Resources District (NRD), the Lower Loup NRD, and the Nebraska Environmental Trust, studied the spatial and temporal characteristics of groundwater discharge within the Loup River Basin. This report documents the methods of data collection and analysis, which include the collection of approximately 350 river miles of aerial thermal infrared imagery and continuous groundwater-level and temperature data from six streamflow-gaging stations within the Loup River Basin. The results from the stream reconnaissance and examination of aerial thermal infrared imagery demonstrated the influence of the surficial and subsurface geology on the spatial characteristics of groundwater discharge to streams in the Loup River Basin. At the headwaters of the South Loup River, streamflow is sustained and increased from focused groundwater discharge emanating from Quaternary deposits at many small (less than 0.1 cubic foot per second) focused points. The volume of water produced from this dense network of focused groundwater discharge points along the North Fork South Loup River is sufficient to provide approximately 40 percent of the flow measured at the South Loup River at Arnold, Nebraska streamflow-gaging station (USGS station 06781600) during the irrigation season. Approximately 5 miles downstream from the South Loup River at Arnold, Nebr., streamflow-gaging station, the river incises into Pliocene-age sand and gravel deposits, which provide additional groundwater discharge to the stream. The streamflow of the South Loup River increases by a factor of 5 across a 62-mile reach of the middle South Loup River. Increases in streamflow along the upper Dismal River result from a dense network of focused groundwater discharge points within semiconsolidated Pliocene-age deposits. Below the Dismal River near Thedford, Nebraska, streamflow-gaging station (USGS station 06775900), the Dismal River incises into the Ogallala Formation over a short reach before flowing over coarser, more permeable Quaternary-age alluvial deposits. Diffuse groundwater discharge sustains and increases the streamflow of the lower Dismal River in this reach. Groundwater sapping was evident on some stream reaches and has increased the size and flow of focused groundwater discharge points. Previous researchers have documented streambed incision and groundwater sapping on the upper Dismal River that have created and enlarged focused groundwater discharge points capturing additional groundwater. Similar processes appear to have played a role in the formation of larger focused groundwater discharge points, which sustain the flow of the middle South Loup River. The constant flow of groundwater into the South Loup River has removed finer-grained Quaternary sediments and further exposed Pliocene-age gravel deposits. Headward erosion is evident where some of the large focused groundwater discharge points have incised their own draws and terminate in bowl-like depressions away from the stream. Within the Loup River NRDs, the percentage of groundwater-irrigated land in a stream basin is one factor that affects groundwater discharge to streams. A striking example was at the South Loup River at Saint Michael, Nebraska, groundwater and streamflow-gaging station (USGS station 06784000) where the shallow groundwater levels declined below the level of the stream during the middle to late part of the growing season (July to September) when consumptive groundwater use was at its peak. The South Loup River Basin above the South Loup River at Saint Michael, Nebr., streamflow-gaging station has the highest percentage of groundwater-irrigated row crops of all the basins examined in this study. Continuous groundwater and surface-water levels measured at the North Loup River at the Taylor, Nebr., streamflow-gaging station (USGS station 06786000) indicate that the stream is receiving groundwater throughout the year; however, when consumptive groundwater use peaks during the middle to late part of the growing season (July to September), the difference in elevation between the groundwater level and the stream elevation decreases, which indicates a reduction in the amount of groundwater discharge received

Groundwater Movement and Interaction with Surface Water Near the Confluence of the Platte and Elkhorn Rivers, Nebraska, 2016–18

Document abstract The State of Nebraska requires a sustainable balance between long-term water supplies and uses of groundwater and surface water and requires Natural Resources Districts to include the effect of groundwater use on surface-water systems as part of their respective integrated management plans. Recent droughts in Nebraska (2000–6; 2012–13) have amplified concerns about the long-term sustainability of groundwater and surface-water resources in the state, and concerns about the effect of groundwater irrigation on both streamflow and the water supplies needed to meet wildlife, recreational, and municipal needs. The lower Platte River provides nearly 100 percent of drinking-water supplies to Lincoln, Nebraska, 40 to 60 percent of drinking-water supplies to Omaha, Nebraska, and critical aquatic and riparian habitat for threatened and endangered species. The Lower Platte River Basin-wide Management Plan has been jointly developed by the Nebraska Department of Natural Resources and seven Natural Resources Districts to address some of these concerns by managing groundwater and surface-water resources conjunctively. To sustain flows in the lower Platte River that are needed for municipal water supplies, water managers have proposed projects aimed at temporary storage of surface water in upstream parts of the basin to mitigate periods of low flow in the lower Platte River. To increase scientific understanding and provide support for any potential future streamflow augmentation projects, the Papio-Missouri River Natural Resources District, the Lower Platte North Natural Resources District, and the Nebraska Department of Natural Resources, in cooperation with the United States Geological Survey, initiated this study to examine groundwater/surface-water interaction along the lower Platte and Elkhorn Rivers upstream from their confluence. The study design described herein focused on understanding seasonal characteristics of groundwater movement and interaction with surface water during periods of high groundwater demand (June through August) and low groundwater demand (all other months). Understanding how groundwater movement and interaction with surface water are affected by streamflow conditions and local groundwater demand is critical to the development of any streamflow augmentation project intended to sustain streamflow and mitigate periods of low flow in the lower Platte River. The characteristics of groundwater movement and interaction with surface water are affected by hydrologic and local climatic conditions. For the study area, 2016–18 conditions can be broadly characterized as above normal precipitation. The flows measured at the Elkhorn River at Waterloo, Nebraska, streamflow-gaging station (U.S. Geological Survey station 06800500) were above the long-term median, and the streamflow of the Platte River near Leshara, Nebraska, streamflow-gaging station (06796500) remained normal or slightly above normal for the duration of this study. Continuous streamflow and water-level data were interpreted to examine differences in groundwater movement and interaction with surface water between the Platte and Elkhorn Rivers during high and low groundwater demand periods. Although the streamflow for the Platte and Elkhorn Rivers and their tributaries was less during the high groundwater demand period, the hydraulic gradient along a transect of recorder wells was identical (0.0012 foot per foot) during the high and low groundwater demand synoptic water-level and streamflow surveys. The hydraulic gradient between the Platte and Elkhorn Rivers generally remained between 0.0011 and 0.0012 foot per foot. It can be inferred that the hydraulic gradient, which is the only temporally variable factor in Darcy’s Law, is consistent throughout the study period and that groundwater flow does not vary appreciably along this transect. The northern part of the study area (north of the transect of recorder wells) has consistent groundwater and tributary flow from Big Slough, Rawhide Creek (Old Channel), and Rawhide Creek for low and high groundwater demand periods. In the southern part of the study area (south of the transect of recorder wells), tributary flow is more variable and dependent on local groundwater demand and flow conditions of the Platte River. Small decreases (less than 2 feet) in the groundwater levels, such as those measured during the high groundwater demand period, can have substantial changes in the streamflow in an unnamed tributary to the Elkhorn River. The streamflow measured during the high groundwater demand synoptic water-level and streamflow survey had decreased by nearly a factor of 20 when compared to the low groundwater demand period. The volume of groundwater discharge received by the Elkhorn River was estimated by examining the changes in streamflow between measurement locations. Streamflow measurements indicate that the groundwater discharge received by the Elkhorn River in the southern part of the study area was seasonably variable, making it difficult if not impossible to estimate an annual value. In the Elkhorn River, between the Elkhorn River at Waterloo, Nebr., streamflow-gaging station and the Q Street Bridge, streamflow measurements collected during the low groundwater demand period indicated a gain of 80 cubic feet per second, which is comparable to the gain estimated using aerial thermal infrared imagery and water temperature data. Streamflow measurements collected during the high groundwater demand period indicate a loss of 80 cubic feet per second across this same reach. In assessing water supply conditions in the lower Platte River system, the term “loss” in reference to streamflow in the Elkhorn River should be used with caution. Most likely, flow from the Elkhorn River which is “lost” to the groundwater system will later discharge to surface water closer to the confluence of the Platte and Elkhorn Rivers as underflow. A calibrated groundwater flow model of the study area likely is required to predict the fate of this water and to quantify groundwater discharge during varying hydrologic conditions along this reach. Aerial thermal infrared imagery indicated that much of the groundwater discharge in the southern part of the study area is focused across a 3-mile reach where the Elkhorn River turns southwest, perpendicular to the regional groundwater flow direction. Points of focused groundwater discharge were not detected with aerial thermal infrared imagery, indicating that groundwater discharge is diffuse rather than concentrated at focused points. Temperature-based streambed flux estimates indicated that strong regional groundwater gradients are not driving groundwater discharge and hyporheic flow is the dominant groundwater/surface-water exchange process. Data abstract This dataset includes measured water-levels, water-level contours, aerial thermal infrared (TIR) imagery, and a stream centerline that were used to describe groundwater movement and interaction with surface water between the lower Platte and lower Elkhorn Rivers upstream of their confluence. The study design described herein focused on understanding seasonal characteristics of groundwater movement and interaction with surface water during periods of high groundwater demand (June through August) and low groundwater demand (all other months). Measured groundwater level and surface-water level data were collected during a low groundwater demand period in fall of 2016 and a high groundwater demand period in summer of 2017. Two sets of water-level contours were manually digitized within a Geographic Information System (GIS) to describe groundwater movement and flow directions for the low groundwater demand period and the high groundwater demand period. A georeferenced mosaic of high-resolution, aerial thermal infrared (TIR) images of the lower Elkhorn River, Nebraska, are presented as a gridded (raster) image in GeoTiff format. The image is a 1.64-ft by 1.64-ft grid of corrected surface temperatures, in degrees Fahrenheit, of the lower Elkhorn River and adjacent area. The dataset encompasses a 10-mile reach of the river, from 0.4 miles upstream from United States Geological Survey (USGS) streamflow-gaging station 06800500, Elkhorn River at Waterloo, Nebraska, to 1.8 miles downstream from USGS site 06800800, Elkhorn River at Q St Bridge near Venice, Nebraska. A reach centerline was manually digitized in a GIS along the 100-mile reach. Stream surface temperatures were extracted from the aerial TIR imagery and plotted against distance downstream to interpret groundwater discharge patterns

Optimization of adsorptive removal of α-toluic acid by CaO2 nanoparticles using response surface methodology

The present work addresses the optimization of process parameters for adsorptive removal of α-toluic acid by calcium peroxide (CaO2) nanoparticles using response surface methodology (RSM). CaO2 nanoparticles were synthesized by chemical precipitation method and confirmed by Transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) analysis which shows the CaO2 nanoparticles size range of 5–15 nm. A series of batch adsorption experiments were performed using CaO2 nanoparticles to remove α-toluic acid from the aqueous solution. Further, an experimental based central composite design (CCD) was developed to study the interactive effect of CaO2 adsorbent dosage, initial concentration of α-toluic acid, and contact time on α-toluic acid removal efficiency (response) and optimization of the process. Analysis of variance (ANOVA) was performed to determine the significance of the individual and the interactive effects of variables on the response. The model predicted response showed a good agreement with the experimental response, and the coefficient of determination, (R2) was 0.92. Among the variables, the interactive effect of adsorbent dosage and the initial α-toluic acid concentration was found to have more influence on the response than the contact time. Numerical optimization of process by RSM showed the optimal adsorbent dosage, initial concentration of α-toluic acid, and contact time as 0.03 g, 7.06 g/L, and 34 min respectively. The predicted removal efficiency was 99.50%. The experiments performed under these conditions showed α-toluic acid removal efficiency up to 98.05%, which confirmed the adequacy of the model prediction