179 research outputs found
Direct observation of t2g orbital ordering in magnetite
Using soft-x-ray diffraction at the site-specific resonances in the Fe L23
edge, we find clear evidence for orbital and charge ordering in magnetite below
the Verwey transition. The spectra show directly that the (001/2) diffraction
peak (in cubic notation) is caused by t2g orbital ordering at octahedral Fe2+
sites and the (001) by a spatial modulation of the t2g occupation.Comment: to appear in Phys. Rev. Let
Spectroscopy of stripe order in La1.8Sr0.2NiO4 using resonant soft x-ray diffraction
Strong resonant enhancements of the charge-order and spin-order
superstructure-diffraction intensities in La1.8Sr0.2NiO4 are observed when
x-ray energies in the vicinity of the Ni L2,3 absorption edges are used. The
pronounced photon-energy and polarization dependences of these diffraction
intensities allow for a critical determination of the local symmetry of the
ordered spin and charge carriers. We found that not only the antiferromagnetic
order but also the charge-order superstructure resides within the NiO2 layers;
the holes are mainly located on in-plane oxygens surrounding a Ni2+ site with
the spins coupled antiparallel in close analogy to Zhang-Rice singlets in the
cuprates.Comment: 4 pages, 3 figure
In-situ electron-beam lithography of deterministic single-quantum-dot mesa-structures using low-temperature cathodoluminescence spectroscopy
We report on the deterministic fabrication of sub-um mesa structures
containing single quantum dots by in-situ electron-beam lithography. The
fabrication method is based on a two-step lithography process using a
low-temperature cathodoluminescence (CL) spectroscopy setup. In the first step
the position and spectral features of single InGaAs quantum dots (QDs) are
detected by CL. Then circular sub-um mesa-structures are exactly defined by
high-resolution electron-beam lithography and subsequent etching in the second
step. CL spectroscopy and micro-photoluminscence spectroscopy demonstrate the
high optical quality of the single-QD mesa-structures with emission linewidths
below 15 ueV and g(2)(0) = 0.04. Our lithography method allows for an alignment
precision better than 100 nm which paves the way for a fully-deterministic
device technology using in-situ CL lithography.Comment: 4 pages, 4 figure
Electronic structure of NiSSe across the phase transition
We report very highly resolved photoemission spectra of NiS(1-x)Se(x) across
the so-called metal-insulator transition as a function of temperature as well
as composition. The present results convincingly demonstrate that the low
temperature, antiferromagnetic phase is metallic, with a reduced density of
states at E. This decrease is possibly due to the opening of gaps along
specific directions in the Brillouin zone caused by the antiferromagnetic
ordering.Comment: Revtex, 4 pages, 3 postscript figure
Epitaxial and layer-by-layer growth of EuO thin films on yttria-stabilized cubic zirconia (001) using MBE distillation
We have succeeded in growing epitaxial and highly stoichiometric films of EuO
on yttria-stabilized cubic zirconia (YSZ) (001). The use of the Eu-distillation
process during the molecular beam epitaxy assisted growth enables the
consistent achievement of stoichiometry. We have also succeeded in growing the
films in a layer-by-layer fashion by fine tuning the Eu vs. oxygen deposition
rates. The initial stages of growth involve the limited supply of oxygen from
the YSZ substrate, but the EuO stoichiometry can still be well maintained. The
films grown were sufficiently smooth so that the capping with a thin layer of
aluminum was leak tight and enabled ex situ experiments free from trivalent Eu
species. The findings were used to obtain recipes for better epitaxial growth
of EuO on MgO (001).Comment: 10 pages, 15 figure
Analysis of charge and orbital order in Fe_{3}O_{4} by Fe L_{2,3} resonant x-ray diffraction
To elucidate charge and orbital order below the Verwey transition temperature
TV∼125 K, a thin layer of magnetite partially detwined by growth on the
stepped MgO(001) substrate has been studied by means of soft x-ray diffraction
at the Fe L2,3 resonance. The azimuth angle, incident photon polarization, and
energy dependence of the (0012)c and (001)c reflection intensities have been
measured, and analyzed using a configuration-interaction FeO6 cluster model.
The azimuth dependence of the (0012)c reflection intensities directly
represents the space-group symmetry of the orbital order in the initial state
rather than indirectly through the intermediate-state level shifts caused by
the order-induced lattice distortions. From the analysis of the (0012)c
reflection intensities, the orbital order in the t2g orbitals of B sites below
TV is proved to have a large monoclinic deformation with the value of
Re[Fxy]/Re[Fyz]∼2. This finding contradicts the majority of theories on the
Verwey transition so far proposed. We show that the experimentally observed
resonance spectra cannot be explained by orbital and charge orders obtained
with recent LDA+U and GGA+U band structure calculations but by a complex-
number orbital order with excellent agreement
Epitaxy, stoichiometry, and magnetic properties of Gd-doped EuO films on YSZ (001)
We have succeeded in preparing high-quality Gd-doped single-crystalline EuO
films. Using Eu-distillation-assisted molecular beam epitaxy and a systematic
variation in the Gd and oxygen deposition rates, we have been able to observe
sustained layer-by-layer epitaxial growth on yttria-stabilized cubic zirconia
(001). The presence of Gd helps to stabilize the layer-by-layer growth mode. We
used soft x-ray absorption spectroscopy at the Eu and Gd M4,5 edges to confirm
the absence of Eu3+ contaminants and to determine the actual Gd concentration.
The distillation process ensures the absence of oxygen vacancies in the films.
From magnetization measurements we found the Curie temperature to increase
smoothly as a function of doping from 70 K up to a maximum of 125 K. A
threshold behavior was not observed for concentrations as low as 0.2%.Comment: 8 pages, 9 figure
Prediction of huge X-ray Faraday rotation at the Gd N_4,5 threshold
X-ray absorption spectra in a wide energy range around the 4d-4f excitation
threshold of Gd were recorded by total electron yield from in-plane magnetized
Gd metal films. Matching the experimental spectra to tabulated absorption data
reveals unprecedented short light absorption lengths down to 3 nm. The
associated real parts of the refractive index for circularly polarized light
propagating parallel or antiparallel to the Gd magnetization, determined
through the Kramers-Kronig transformation, correspond to a magneto-optical
Faraday rotation of 0.7 degrees per atomic layer. This finding shall allow the
study of magnetic structure and magnetization dynamics of lanthanide elements
in nanosize systems and dilute alloys.Comment: 4 pages, 2 figures, final version resubmitted to Phys. Rev. B, Brief
Reports. Minor change
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