A lichen protected by a super-hydrophobic and breathable structure

A species of lichen, Lecanora conizaeoides, is shown to be super-hydrophobic. It uses a combination of hydrophobic compounds and multi-layered roughness to shed water effectively. This is combined with gas channels to produce a biological analogue of a waterproof, breathable garment. The particular lichen grows mostly during wet seasons and is unusually resistant to acid rain [Hauck, M., 2003. The Bryotogist 106(2), 257-269; Honegger, R., 1998. Lichenologist 30(3),193-212]. The waterproof, breathable surface allows this lichen to photosynthesise when other species are covered with a layer of water. In addition, rainwater runs off the surface of the organism, reducing its intake of water from above and probably contributing to its resistance to acid rain

Anisotropic Electron Spin Lifetime in (In,Ga)As/GaAs (110) Quantum Wells

Anisotropic electron spin lifetimes in strained undoped (In,Ga)As/GaAs (110) quantum wells of different width and height are investigated by time-resolved Faraday rotation and time-resolved transmission and are compared to the (001)-orientation. From the suppression of spin precession, the ratio of in-plane to out-of-plane spin lifetimes is calculated. Whereas the ratio increases with In concentration in agreement with theory, a surprisingly high anisotropy of 480 is observed for the broadest quantum well, when expressed in terms of spin relaxation times.Comment: 4 pages, 4 figures, revise

Precise predictions for V + 2 jet backgrounds in searches for invisible Higgs decays

We present next-to-leading order QCD and electroweak (EW) theory predictions for V + 2 jet production, with V = Z, W$^{±}$, considering both the QCD and EW production modes and their interference. We focus on phase-space regions where V + 2 jet production is dominated by vector-boson fusion, and where these processes yield the dominant irreducible backgrounds in searches for invisible Higgs boson decays. Predictions at parton level are provided together with detailed prescriptions for their implementation in experimental analyses based on the reweighting of Monte Carlo samples. The key idea is that, exploiting accurate data for W + 2 jet production in combination with a theory-driven extrapolation to the Z + 2 jet process can lead to a determination of the irreducible background at the few-percent level. Particular attention is devoted to the estimate of the residual theoretical uncertainties due to unknown higher-order QCD and EW effects and their correlation between the different V + 2 jet processes, which is key to improve the sensitivity to invisible Higgs decays

NLO QCD+EW predictions for 2ℓ\ell2v diboson signatures at the LHC

We present next-to-leading order (NLO) calculations including QCD and electroweak (EW) corrections for 2$\ell$2ν diboson signatures with two opposite-charge leptons and two neutrinos. Specifically, we study the processes $pp \to e^+\mu^-\nu_e\overline{\nu}_{\mu}$ and $pp \to e^+e^-\nu\overline{\nu}$, including all relevant off-shell diboson channels, $W^+W^-, ZZ, \gamma Z$, as well as non-resonant contributions. Photon-induced processes are computed at NLO EW, and we discuss subtle differences related to the definition and the renormalisation of the coupling α for processes with initial- and final-state photons. All calculations are performed within the automated Munich/Sherpa+OpenLoops frameworks, and we provide numerical predictions for the LHC at 13 TeV. The behaviour of the corrections is investigated with emphasis on the high-energy regime, where NLO EW effects can amount to tens of percent due to large Sudakov logarithms. The interplay between $W$ $W$and $ZZ$ contributions to the same-flavour channel, $pp \to e^+e^-\nu\overline{\nu}$, is discussed in detail, and a quantitative analysis of photon-induced contributions is presented. Finally, we consider approximations that account for all sources of large logarithms, at high and low energy, by combining virtual EW corrections with a YFS soft-photon resummation or a QED parton shower

Simulation of cyclotron resonant scattering features: The effect of bulk velocity

X-ray binary systems consisting of a mass donating optical star and a highly magnetized neutron star, under the right circumstances, show quantum mechanical absorption features in the observed spectra called cyclotron resonant scattering features (CRSFs). We have developed a simulation to model CRSFs using Monte Carlo methods. We calculate Green's tables which can be used to imprint CRSFs to arbitrary X-ray continua. Our simulation keeps track of scattering parameters of individual photons, extends the number of variable parameters of previous works, and allows for more flexible geometries. Here we focus on the influence of bulk velocity of the accreted matter on the CRSF line shapes and positions

Comparison of fibre optical measurements and discrete element simulations for the study of granulation in a spout fluidized bed

Spout fluidized beds are frequently used for the production of granules or particles through granulation. The products find application in a large variety of applications, for example detergents, fertilizers, pharmaceuticals and food. Spout fluidized beds have a number of advantageous properties, such as a high mobility of the particles, which prevents undesired agglomeration and yields excellent heat transfer properties. The particle growth mechanism in a spout fluidized bed as function of particle-droplet interaction has a profound influence on the particle morphology and thus on the product quality. Nevertheless, little is known about the details of the granulation process. This is mainly due to the fact that the granulation process is not visually accessible. In this work we use fundamental, deterministic models to enable the detailed investigation of granulation behaviour in a spout fluidized bed. A discrete element model is used describing the dynamics of the continuous gas-phase and the discrete droplets and particles. For each element momentum balances are solved. The momentum transfer among each of the three phases is described in detail at the level of individual elements. The results from the discrete element model simulations are compared with local measurements of particle volume fractions as well as particle velocities by using a novel fibre optical probe in a fluidized bed of 400 mm I.D. Simulations and experiments were carried out for three different cases using Geldart B type aluminium oxide particles: a freely bubbling fluidized bed; a spout fluidized bed without the presence of droplets and a spout fluidized bed with the presence of droplets. It is demonstrated how the discrete element model can be used to obtain information about the interaction of the discrete phases, i.e. the growth zone in a spout fluidized bed. Eventually this kind of information can be used to obtain closure information required in more coarse grained models

Chemical Composition of Polymer Surfaces Imaged by Atomic ForceMicroscopy and Complementary Approaches

In this article we review the recent developments in the field of high resolution lateral mapping of the surface chemical composition of polymers by atomic force microscopy (AFM) and other complementary imaging techniques. The different AFM approaches toward nanometer scale mapping with chemical sensitivity based on chemical force microscopy (CFM) are discussed as a means to unravel, for instance, the lateral distribution of surface chemistry, the stability of various types of functional groups in various environments, or the interactions with controlled functional groups at the tip surface. The applicability and current limitations of CFM, which allows one to image chemical functional group distributions with a resolution in principle down to the 10–20 nm scale, are critically discussed. In addition, complementary imaging techniques are briefly reviewed and compared to the AFM-based techniques. The complementary approaches comprise various spectroscopies (infrared and Raman), secondary ion mass spectrometry (SIMS), matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS), X-ray photoelectron spectroscopy (XPS or ESCA), and near-field optical techniques used for imaging

Self-Complementary Recognition of Supramolecular Urea - Aminotriazines in Solution and on Surfaces

The recognition of self-complementary quadruple urea–aminotriazine (UAT)-based hydrogen-bonded arrays was investigated in solution and at surfaces. For this purpose, an UAT-based donor–acceptor–donor–acceptor (DADA) array and complementary receptors were synthesized. Two-dimensional proton nuclear magnetic resonance (1H NMR) measurements in CDCl3 pointed at an intramolecular hydrogen-bond stabilization of the UAT, which promotes a planar molecular geometry and, thereby, results in a significant stabilization of the dimeric complex. The bond strength of the UAT dimers at surfaces was determined by atomic force microscopy-based single molecule force spectroscopy (AFM–SMFS) in hexadecane. The UAT receptor was immobilized on gold surfaces using an ultrathin layer of ethylene glycol terminated lipoic acid and isocyanate chemistry. The layers obtained and the reversible self-complementary recognition were thoroughly characterized with contact angle measurements, grazing angle Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and AFM. Loading rate-dependent SMFS measurements yielded a barrier width xβ and a bond lifetime at zero force toff(0) of 0.29 ± 0.02 nm and 100 ± 80 ms, respectively. The value of the corresponding off-rate constant koff suggests a substantially larger value of the dimerization constant compared to theoretical predictions, which is fully in line with the additional intramolecular hydrogen-bond stabilization detected in solution by 1H NMR spectroscopy

Patterns of Surface Immobilized Block Copolymer Vesicle Nanoreactors

The immobilization and positioning of ultra small reaction vessels on solid supports open new pathways in applications such as lab-on-a-chip, sensors, microanalyses and microreactors. In our work block copolymer vesicles made from polystyrene-block-polyacrylic acid (PS-b-PAA) were immobilized from aqueous medium onto 3-amino propyl trimethoxysilane functionalized silicon surfaces exploiting electrostatic interactions. The immobilization of the vesicles was investigated by Fourier transform infrared (FTIR) spectroscopy, as well as fluorescence optical and atomic force microscopy (AFM). In addition, the influence of pH and ionic strength on the surface coverage of vesicles bound to the surface was elucidated. Finally micro-molding in capillaries (MIMIC) was utilized to create line patterns of the vesicles containing the enzyme trypsin and the fluorogenic substrate rhodamine 110 bisamide. The selective positioning of vesicle nanoreactors in conjunction with electrostatic immobilization serves as a proof of principle for potential applications in real-time observation of confined chemical reaction inside vesicles as nanocontainers and for the fabrication of integrated microarray systems