1,142 research outputs found

    Baryonic and mesonic 3-point functions with open spin indices

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    We have implemented a new way of computing three-point correlation functions. It is based on a factorization of the entire correlation function into two parts which are evaluated with open spin- (and to some extent flavor-) indices. This allows us to estimate the two contributions simultaneously for many different initial and final states and momenta, with little computational overhead. We explain this factorization as well as its efficient implementation in a new library which has been written to provide the necessary functionality on modern parallel architectures and on CPUs, including Intel's Xeon Phi series.Comment: 7 pages, 5 figures, Proceedings of Lattice 201

    The oscillatory fingerprints of self-prioritization : Novel markers in spectral EEG for self-relevant processing

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    Funding Information: The research reported in this article was supported by a Grant from the Deutsche Forschungsgemeinschaft (SCHA 2253/1–1). Open Access funding enabled and organized by Projekt DEAL.Peer reviewedPublisher PD

    Small and Large Satellites: Joint Operations in Earth Observation

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    While projects for the exploration of space remain ambitious and financially as well as technologically demanding projects, their benefit in understanding our planet is unrivaled [1]. On top of enabling technologies that keep drastically altering the way we communicate, navigate, or build our cities, they currently present the only means of assessing key environmental variables on a global scale [2]–[5]. Today, we witness the New Space era with promises of ever easier, faster, and cheaper space access as a major driving force for the future development to four space capabilities, specifically in Earth Observation (EO), but also in communication (COM) and navigation (NAV) applications. Since from an economic point of view, only now it became possible to achieve resolution and coverage matching the needs of many applications outside the scientific community by means of small satellite constellations[6]–[9]

    Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes

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    Di-tert-butyliminoborane is found to be a very useful synthon for the synthesis of a variety of functionalized 1,4-azaborinines by the Rh-mediated cyclization of iminoboranes with alkynes. The reactions proceed via [2 + 2] cycloaddition of iminoboranes and alkynes in the presence of [RhCl(PiPr3)2]2, which gives a rhodium η4-1,2-azaborete complex that yields 1,4-azaborinines upon reaction with acetylene. This reaction is compatible with substrates containing more than one alkynyl unit, cleanly affording compounds containing multiple 1,4-azaborinines. The substitution of terminal alkynes for acetylene also led to 1,4-azaborinines, enabling ring substitution at a predetermined location. We report the first general synthesis of this new methodology, which provides highly regioselective access to valuable 1,4-azaborinines in moderate yields. A mechanistic rationale for this reaction is supported by DFT calculations, which show the observed regioselectivity to arise from steric effects in the B-C bond coupling en route to the rhodium η4-1,2-azaborete complex and the selective oxidative cleavage of the B-N bond of the 1,2-azaborete ligand in its subsequent reaction with acetylene.</p

    Additive Manufactured Structures for the 12U Nanosatellite ERNST

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    One of the emerging technologies in recent years is additive manufacturing. It promises unprecedented design freedom in both modeling and rapid manufacturing. We are reaping the benefits of additive manufacturing for our 12U nanosatellite ERNST by printing the optical bench that supports the spacecraft payloads. We design the structures by using a finite-element numerical approach for optimizing the topology with respect to 1) available design space, 2) payload interfaces, 3) mechanical launch loads, and 4) thermal loads generated by the cryocooler of the MWIR main payload. We cope with the latter by integrating a pyramidal structured radiator surface in the optical bench as a functional element. Making use of the selective laser melting technique, we manufactured the first version of the optical bench for the engineering model of the ERNST spacecraft from AlSi10Mg alloy. Vibrational testing proved the suitability of our multidisciplinary design approach and the production quality. We are currently implementing the next version of the ERNST optical bench including spacecraft design changes and using ScalmalloyÂź, a material developed for additive manufacturing that provides high tensile strength and low thermal expansion. This marks a next step on the way to the application of additive manufactured components in space

    Dibora[2]ferrocenophane: a carbene-stabilized diborene in a strained cis-configuration

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    Unsaturated bridges that link the two cyclopentadienyl ligands together in strained ansa metallocenes are rare and limited to carbon-carbon double bonds. The synthesis and isolation of a strained ferrocenophane containing an unsaturated two-boron bridge, isoelectronic with a C=C double bond, was achieved by reduction of a carbene-stabilized 1,1’-bis(dihaloboryl)ferrocene. A combination of spectroscopic and electrochemical measurements as well as density functional theory (DFT) calculations was used to assess the influence of the unprecedented strained cis configuration on the optical and electrochemical properties of the carbene-stabilized diborene unit. Initial reactivity studies show that the dibora[2]ferrocenophane is prone to boron-boron double bond cleavage reactions
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