696 research outputs found

    The Challenges of Capacity Building in the Aligning Forces for Quality Alliances

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    Summarizes the challenges and trade-offs in infrastructure and governance as well as stakeholder relations and participation, such as inclusive versus efficient decision making, in an alliance to coordinate regional healthcare improvement activities

    Aligning product and supply chain strategies in the mobile phone industry

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    Thesis (S.M.)--Massachusetts Institute of Technology, System Design and Management Program, 2009.Cataloged from PDF version of thesis.Includes bibliographical references (p. 87-88).Designing and managing the supply chain of a company in the mobile phone industry is particularly challenging. Short product lifecycles, rapidly evolving technology, globally linked distribution networks, increasing product variability and high levels of demand and supply uncertainty all create problems for those managing these supply chains. As competition in this industry increases and profit margins decrease, proper supply chain management practices will only become more important to companies competing in this industry. In order to succeed, companies must implement their supply chain so that it effectively supports their corporate strategy. This thesis investigates the relationship between corporate strategy and supply chain strategy within the mobile phone industry. Although it is directed at one industry, the wide variety of products in terms of price and functionality suggests that there isn't a "one size fits all" supply chain strategy appropriate for all companies that produce mobile phones. An extensive survey was developed that asks participants strategic, tactical and operational questions about different aspects of supply chains that deliver mobile phones. This is used to identify areas in which the stated supply chain strategy impacts the design and operation of the supply chain. Finally, differences in supply chain practices between high and low performers are identified based on supply chain strategy.by Robert Scanlon.S.M

    Anion Distribution, Structural Distortion, and Symmetry-Driven Optical Band Gap Bowing in Mixed Halide Cs2SnX6 Vacancy Ordered Double Perovskites.

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    Mixed anion compounds in the Fm3Ì…m vacancy ordered perovskite structure were synthesized and characterized experimentally and computationally with a focus on compounds where A = Cs+. Pure anion Cs2SnX6 compounds were formed with X = Cl, Br, and I using a room temperature solution phase method. Mixed anion compounds were formed as solid solutions of Cs2SnCl6 and Cs2SnBr6 and a second series from Cs2SnBr6 and Cs2SnI6. Single phase structures formed across the entirety of both composition series with no evidence of long-range anion ordering observed by diffraction. A distortion of the cubic A2BX6 structure was identified in which the spacing of the BX6 octahedra changes to accommodate the A site cation without reduction of overall symmetry. Optical band gap values varied with anion composition between 4.89 eV in Cs2SnCl6 to 1.35 eV in Cs2SnI6 but proved highly nonlinear with changes in composition. In mixed halide compounds, it was found that lower energy optical transitions appeared that were not present in the pure halide compounds, and this was attributed to lowering of the local symmetry within the tin halide octahedra. The electronic structure was characterized by photoemission spectroscopy, and Raman spectroscopy revealed vibrational modes in the mixed halide compounds that could be assigned to particular mixed halide octahedra. This analysis was used to determine the distribution of octahedra types in mixed anion compounds, which was found to be consistent with a near-random distribution of halide anions throughout the structure, although some deviations from random halide distribution were noted in mixed iodide-bromide compounds, where the larger iodide anions preferentially adopted trans configurations

    Spatial Electron-hole Separation in a One Dimensional Hybrid Organic-Inorganic Lead Iodide.

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    The increasing efficiency of the inorganic-organic hybrid halides has revolutionised photovoltaic research. Despite this rapid progress, the significant issues of poor stability and toxicity have yet to be suitably overcome. In this article, we use Density Functional Theory to examine (Pb2I6) · (H2DPNDI) · (H2O) · (NMP), an alternative lead-based hybrid inorganic-organic solar absorber based on a photoactive organic cation. Our results demonstrate that optical properties suitable for photovoltaic applications, in addition to spatial electron-hole separation, are possible but efficient charge transport may be a limiting factor
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