Strategic delegation in a sequential model with multiple stages

We analyze strategic delegation in a Stackelberg model with an arbitrary number, n, of firms. We show that the n-1 last movers delegate their production decisions to managers whereas the first mover does not. Equilibrium incentive rates are increasing in the order with which managers select quantities. Letting u_i^* denote the equilibrium payoff of the firm whose manager moves in the i-th place, we show that u_n^*>u_{n-1}^*>...>u_2^*>u_1^*. We also compare the delegation outcome of our game with that of a Cournot oligopoly and show that the late (early) moving firms choose higher (lower) incentive rates than the Cournot firms.Comment: To appear in International Game Theory Review (IGTR), Vol. 13, No. 3 (2011) 1-1

Fiscal residua and federalist reform in Italy. Will regional and redistributive policies survive?

This paper criticizes the idea to conceive the fiscal federalist reform in Italy as a tool to empower central-northern regions to retain resources otherwise wasted in the South. We argue that such a view muddles up efficiency and redistribution issues, thus threatening the legitimate inter-regional fiscal flows. To dispute the thesis of excessive transfers to Mezzogiorno regions, we first show that the regional distribution of (both current and capital) government expenditure has systematically penalized the South in the last 15 years. Secondly, for the years 2004-2006, we calculate «benchmark» regional fiscal residua, consistent with the progressive Italian personal taxation (IRPEF), and the announced targets of regional policies (45% of total capital government expenditure to be made in the South). For most centre-northern regions, the actual residua turn out to be lower than the «benchmark» ones.Mezzogiorno, redistribution, inter-governmental relations, federalism, regional development policies

Potential of Cellulose-Based Superabsorbent Hydrogels as Water Reservoir in Agriculture

The present work deals with the development of a biodegradable superabsorbent hydrogel, based on cellulose derivatives, for the optimization of water resources in agriculture, horticulture and, more in general, for instilling a wiser and savvier approach to water consumption. The sorption capability of the proposed hydrogel was firstly assessed, with specific regard to two variables that might play a key role in the soil environment, that is, ionic strength and pH. Moreover, a preliminary evaluation of the hydrogel potential as water reservoir in agriculture was performed by using the hydrogel in experimental greenhouses, for the cultivation of tomatoes. The soil-water retention curve, in the presence of different hydrogel amounts, was also analysed. The preliminary results showed that the material allowed an efficient storage and sustained release of water to the soil and the plant roots. Although further investigations should be performed to completely characterize the interaction between the hydrogel and the soil, such findings suggest that the envisaged use of the hydrogel on a large scale might have a revolutionary impact on the optimization of water resources management in agriculture

Biomimetic calcium carbonate with hierarchical porosity produced using cork as a sustainable template agent

Calcium carbonate has many applications in different fields; its use in environment remediation is particularly considered, due to its non-toxicity and potentially high efficiency. The structure, morphology and surface features of calcium carbonate can greatly affect its performance. Hierarchical porosity, in particular, can be beneficial for several functional properties. In this study, we report the synthesis of biomorphic calcium carbonate using a sustainable template agent – waste cork powder. Pyrolysed cork powder was infiltrated by an appropriate calcium-containing salt and successively thermally treated. Selected precursors, different impregnation-solution concentrations and thermal conditions were tested. The resulting materials were characterised by XRD, Raman spectroscopy and SEM. Surface area and porosity features were studied by BET analysis, with a detailed study on the effect of synthesis on the mesoporosity of the materials, average sizes varying between 4−15 nm. The most valuable results were achieved with calcium acetate followed by pyrolysis performed for relatively short time period. This maintained the porous 3D honeycomb cork structure made of ∼20 μm hexagonal cells, while consisting of highly mesoporous single-phase CaCO3. Such samples showed the highest surface area ever reported for CaCO3 prepared using a plant-based template; moreover, it also exhibited a dual-scale hierarchical porosity as, in addition to micrometer scale cellular macroporosity, it contained a significant mesoporosity in the cell walls, with a very narrow range of 3.6–3.9 nm. These promising characteristics enable the potential employment of cork-derived CaCO3 for environment remediation.publishe

Cork-derived hierarchically porous hydroxyapatite with different stoichiometries for biomedical and environmental applications

Hierarchically porous hydroxyapatite derived from cork powder shows excellent performance in biomedicine (low cytotoxicity) and environmental remediation (high Pb2+ removal)

Residui fiscali regionali e riforma federalista. Quanto residuerà delle politiche regionali e redistributive?

This paper criticizes the idea to conceive the fiscal federalist reform in Italy as a tool to empower central-northern regions to retain resources otherwise wasted in the South. We argue that such a view muddles up efficiency and redistribution issues, thus threatening the legitimate inter-regional fiscal flows. To dispute the thesis of excessive transfers to Mezzogiorno regions, we first show that the regional distribution of (both current and capital) government expenditure has systematically penalized the South in the last 15 years. Secondly, for the years 2004-2006, we calculate «benchmark» regional fiscal residua, consistent with the progressive Italian personal taxation (IRPEF), and the announced targets of regional policies (45% of total capital government expenditure to be made in the South). For most centre-northern regions, the actual residua turn out to be lower than the «benchmark» ones

Cognitive processess and cognitive reserve in multiple sclerosis

Multiple Sclerosis (MS) is characterized by motor, cognitive, and neuropsychiatric symptoms, which can occur independently. While MS is traditionally considered an inflammatory disease of the white matter, degeneration of gray matter is increasingly recognized as an important contributor to the progressive cognitive decline. A protective factor against the progression of cognitive dysfunction in MS could be the cognitive reserve, defined as resistance to brain dysfunction. Aim of the present study is to evaluate the role of cognitive reserve for different aspects of cognitive dysfunction of patients with MS. We found that patients with MS and lower cognitive reserve have poorer neuropsychological performance and slower information speed processing. These findings support the notion that intellectual reserve may protect some aspects of cognitive function in patients with MS

A Full-Field Calibration Approach on Material Parameter Identification

In the recent years, the usage of HS-steels has risen significantly in the automotive field. Their characteristics, such as hardness and favorable weight to strength ratio, can increase safety, fuel efficiency and overall product profitability. In this context, for the design with this material it has become crucial to be able to characterize precisely HS-steels and accurately predict their failure in many complex conditions, to fully exploit their capabilities. One of the most accredited ways to approach the prediction of failure for a wide range of materials is the generalized incremental stress-state dependent damage model GISSMO. The model is highly flexible and provides a framework inside LS-DYNA in which failure parameters can be tuned to reproduce experimental data. The definition of the optimal parameters is an inverse problem, therefore it was implemented using LS-OPT. In this work, the experimental evaluation of the MS1500 was carried out using the digital image correlation (DIC). With such technology, the displacements’ field of the test specimen is recorded.The evalueted field was processed as a family of stress-strain curves (hyper-curves) and became the objective of the optimization. This approach is named full field calibration and in this work was split in two phases. First, the stress-strain curve of the material was defined, then the tuning of the GISSMO parameters was performed. To evaluate the effectiveness of the full field approach a parallel study was implemented. The same routine of optimization run with a single stress-strain curve, which was measured with an extensometer. The comparison between the results obtained with the traditional approach and the results obtained with the full field approach highlighted the strenghts and the limitations of the two methods

Chitosan-hydroxyapatite composites made from sustainable sources: a morphology and antibacterial study

Chitosan (Cs) and hydroxyapatite (HA) 3D scaffolds/composites were prepared with a sustainable process, as HA was obtained using CaCO3 derived from cork, a natural material used as a template agent. The HA@Cs composites were prepared with HA in situ formation in a Cs solution, with a dissolution-precipitation mechanism. Different reaction times were considered, with time of 72 h leading to the best materials (sample CsHA_72). X-ray Diffraction (XRD) analysis confirmed HA formation. The analysis of Cs unit cell parameters showed that, for the unmodified Cs, the cell had larger dimensions and a higher degree of distortion than previously reported in literature; HA incorporation in the CsHA_72 composite led to a further increase in the cell dimensions. The morphology of the scaffolds was studied with Scanning Electron Microscopy (SEM) and a high level of porosity was observed; a statistical comparison was performed between the unmodified Cs and CsHA_72 to determine the pore size, structure, and distribution. This analysis, the first of this kind for this type of composites, showed smaller and more circular pores for the CsHA_72 composite (average diameter of 70 μm vs. 88 μm for unmodified Cs). The overall level of porosity, however, did not change (>77%); likewise, the Young modulus was not affected by HA incorporation (about 11 kPa). Antibacterial tests, performed on Escherichia coli and Staphylococcus aureus, showed that HA presence did not significantly reduce the antimicrobial properties; the composites were particularly effective towards S. aureus, as a >90% the bacterial population reduction was observed for an incubation time of 2 h. HA@Cs also showed excellent biocompatibility and good cell proliferation. The properties of these 3D scaffolds make them suitable for application as biomaterials.info:eu-repo/semantics/publishedVersio