How head nurses and clinical instructors see their own and each other's activities in relation to student nurse education

Thesis (M.S.)--Boston Universit

Characterization of novel ichnofossils in meteorite impact glass from the Ries impact structure, Germany

The initial catastrophic biological effects of hypervelocity impacts are well established. However, a growing body of evidence suggests that meteorite impact events have beneficial effects for microbial life. This, in turn, has led many to suggest that impact craters may have been important habitats for life on early Earth. Any large meteorite impact into a water-rich target on a solid planetary body has the potential to generate hydrothermal systems. Impact-generated hydrothermal systems expand the potential environments for microbial colonization to environments without endogenous volcanic heat sources to drive hydrothermal activity. Examination of impact glass from the Ries impact structure, Germany, has revealed the presence of putative microbial alteration. Given the probable ubiquity of impact glasses in post-impact environments throughout the Solar System, it is important to understand the biological components and potential of such systems. A multi-analytical approach to assess the biogenicity of the tubular features in the Ries glasses has been used. Their complex morphology (spiralling, bifurcation, avoidance, lack of intersection) has been studied extensively using both optical and scanning electron microscopy. Using Energy Dispersive Spectroscopy we have shown the presence of a depletion zone indicative of biological processing surrounding the tubules. Fourier Transform Infrared Spectroscopy has identified the presence of organic compounds spatially associated with the tubules and absent in crystallite regions. Synchrotron near edge fine structure (NEXAFS) spectroscopy at the C K-edge also indicates the presence of organically bound carbon in the glassy matrix surrounding the tubules, but absent in the matrix hosting only crystallites. NEXAFS spectroscopy at the Fe L2 and L3 -edges indicates distinct patterns of Fe speciation in the tubules not present in the Fe-rich abiotic quench crystallites. Together, these results are strongly suggestive of a microbial alteration origin for the tubules in the Ries glasses. Impact cratering is a significant and ubiquitous geological process on terrestrial bodies in the Solar System as well as on the early Earth, as such the discovery of biogenic features in impact glass has profound implications for early life on Earth and the early evolution of life on Earth as well as for life on other terrestrial planets

Federal taxation of the personal insurance estate

Thesis (M.B.A.)--Boston Universit

Role of Meteorite Impacts in the Origin of Life

The conditions, timing, and setting for the origin of life on Earth and whether life exists elsewhere in our solar system and beyond represent some of the most fundamental scientific questions of our time. Although the bombardment of planets and satellites by asteroids and comets has long been viewed as a destructive process that would have presented a barrier to the emergence of life and frustrated or extinguished life, we provide a comprehensive synthesis of data and observations on the beneficial role of impacts in a wide range of prebiotic and biological processes. In the context of previously proposed environments for the origin of life on Earth, we discuss how meteorite impacts can generate both subaerial and submarine hydrothermal vents, abundant hydrothermal–sedimentary settings, and impact analogues for volcanic pumice rafts and splash pools. Impact events can also deliver and/or generate many of the necessary chemical ingredients for life and catalytic substrates such as clays as well. The role that impact cratering plays in fracturing planetary crusts and its effects on deep subsurface habitats for life are also discussed. In summary, we propose that meteorite impact events are a fundamental geobiological process in planetary evolution that played an important role in the origin of life on Earth. We conclude with the recommendation that impact craters should be considered prime sites in the search for evidence of past life on Mars. Furthermore, unlike other geological processes such as volcanism or plate tectonics, impact cratering is ubiquitous on planetary bodies throughout the Universe and is independent of size, composition, and distance from the host star. Impact events thus provide a mechanism with the potential to generate habitable planets, moons, and asteroids throughout the Solar System and beyond

An astrobiological experiment to explore the habitability of tidally locked M-dwarf planets

We present a summary of a three-year academic research proposal drafted during the Sao Paulo Advanced School of Astrobiology (SPASA) to prepare for upcoming observations of tidally locked planets orbiting M-dwarf stars. The primary experimental goal of the suggested research is to expose extremophiles from analogue environments to a modified space simulation chamber reproducing the environmental parameters of a tidally locked planet in the habitable zone of a late-type star. Here we focus on a description of the astronomical analysis used to define the parameters for this climate simulation

The Cell and the Sum of Its Parts: Patterns of Complexity in Biosignatures as Revealed by Deep UV Raman Spectroscopy

The next NASA-led Mars mission (Mars 2020) will carry a suite of instrumentation dedicated to investigating Martian history and the in situ detection of potential biosignatures. SHERLOC, a deep UV Raman/Fluorescence spectrometer has the ability to detect and map the distribution of many organic compounds, including the aromatic molecules that are fundamental building blocks of life on Earth, at concentrations down to 1 ppm. The mere presence of organic compounds is not a biosignature: there is widespread distribution of reduced organic molecules in the Solar System. Life utilizes a select few of these molecules creating conspicuous enrichments of specific molecules that deviate from the distribution expected from purely abiotic processes. The detection of far from equilibrium concentrations of a specific subset of organic molecules, such as those uniquely enriched by biological processes, would comprise a universal biosignature independent of specific terrestrial biochemistry. The detectability and suitability of a small subset of organic molecules to adequately describe a living system is explored using the bacterium Escherichia coli as a model organism. The DUV Raman spectra of E. coli cells are dominated by the vibrational modes of the nucleobases adenine, guanine, cytosine, and thymine, and the aromatic amino acids tyrosine, tryptophan, and phenylalanine. We demonstrate that not only does the deep ultraviolet (DUV) Raman spectrum of E. coli reflect a distinct concentration of specific organic molecules, but that a sufficient molecular complexity is required to deconvolute the cellular spectrum. Furthermore, a linear combination of the DUV resonant compounds is insufficient to fully describe the cellular spectrum. The residual in the cellular spectrum indicates that DUV Raman spectroscopy enables differentiating between the presence of biomolecules and the complex uniquely biological organization and arrangements of these molecules in living systems. This study demonstrates the ability of DUV Raman spectroscopy to interrogate a complex biological system represented in a living cell, and differentiate between organic detection and a series of Raman features that derive from the molecular complexity inherent to life constituting a biosignature

Prediction of pH Change in Processed Acidified Turnips

The acetic acid uptake by turnips was studied during an acidification process in containers. The process was successfully described by a Fickian diffusion, using a correlation for the buffer effect. Diffusion coefficients (0.629 to 3.99 × 10-9 m2/sec) and partition coefficients (0.8 to 1.1) were obtained by optimization of the fit between experimental and theoretical values, using the simplex method. The partition coefficient did not show an evident dependence on temperature, while diffusivity followed an Arrhenius type behavior. The relationship between acid concentration and pH was described using a cubic model with parameters independent of temperature. Results showed that the combination of these models describing the acid diffusion into the food and the buffering effects of the food allowed accurate prediction of pH evolution in the acidification process

Field and laboratory validation of remote rover operations Science Team findings: The CanMars Mars Sample Return analogue mission

The CanMars Mars Sample Return Analogue Deployment (MSRAD) was a closely simulated, end-to-end Mars Sample Return (MSR) mission scenario, with instrumentation, goals, and constraints modeled on the upcoming NASA Mars 2020 rover mission; this paper reports on the post-mission validation of the exercise. The exercise utilized the CSA Mars Exploration Science Rover (MESR) rover, deployed to Utah, USA, at a Mars-analogue field site. The principal features of the field site located near Green River, Utah are Late Jurassic inverted, fluvial paleochannels, analogous to features on Mars in sites being considered for the ESA ExoMars rover mission and present within the chosen landing site for the Mars 2020 rover mission. The in-simulation (“in-sim”) mission operations team worked remotely from The University of Western Ontario, Canada. A suite of MESR-integrated and hand-held spectrometers was selected to mimic those of the Mars 2020 payload, and a Utah-based, on-site team was tasked with field operations to carry out the data collection and sampling as commanded by the in-sim team. As a validation of the in-sim mission science findings, the field team performed an independent geological assessment. This paper documents the field team's on-site geological assessment and subsequent laboratory and analytical results, then offers a comparison of mission (in-sim) and post-mission (laboratory) science results. The laboratory-based findings were largely consistent with the in-sim rover-derived data and geological interpretations, though some notable exceptions highlight the inherent difficulties in remote science. In some cases, available data was insufficient for lithologic identification given the absence of other important contextual information (e.g., textural information). This study suggests that the in-sim instruments were largely adequate for the Science Team to characterize samples; however, rover-based field work is necessarily hampered by mobility and time constraints with an obvious effect on efficiency but also precision, and to some extent, accuracy of the findings. The data show a dearth of preserved total organic carbon (TOC) – used as a proxy for ancient biosignature preservation potential – in the fluvial-lacustrine system of this field site, suggesting serious consideration with respect to the capabilities and opportunities for addressing the Mars exploration goals. We therefore suggest a thorough characterization of terrestrial sites analogous to those of Mars rover landing sites, and in-depth field studies like CanMars as important, pre-mission strategic exercises