A numerical study of transient heat and mass transfer in crystal growth

A numerical analysis of transient heat and solute transport across a rectangular cavity is performed. Five nonlinear partial differential equations which govern the conservation of mass, momentum, energy and solute concentration related to crystal growth in solution, are simultaneously integrated by a numerical method based on the SIMPLE algorithm. Numerical results showed that the flow, temperature and solute fields are dependent on thermal and solutal Grashoff number, Prandtl number, Schmidt number and aspect ratio. The average Nusselt and Sherwood numbers evaluated at the center of the cavity decrease markedly when the solutal buoyancy force acts in the opposite direction to the thermal buoyancy force. When the solutal and thermal buoyancy forces act in the same direction, however, Sherwood number increases significantly and yet Nusselt number decreases. Overall effects of convection on the crystal growth are seen to be an enhancement of growth rate as expected but with highly nonuniform spatial growth variations

Anisotropic, multi-carrier transport at the (111) LaAlO3_3/SrTiO3_3 interface

The conducting gas that forms at the interface between LaAlO$_3$ and SrTiO$_3$ has proven to be a fertile playground for a wide variety of physical phenomena. The bulk of previous research has focused on the (001) and (110) crystal orientations. Here we report detailed measurements of the low-temperature electrical properties of (111) LAO/STO interface samples. We find that the low-temperature electrical transport properties are highly anisotropic, in that they differ significantly along two mutually orthogonal crystal orientations at the interface. While anisotropy in the resistivity has been reported in some (001) samples and in (110) samples, the anisotropy in the (111) samples reported here is much stronger, and also manifests itself in the Hall coefficient as well as the capacitance. In addition, the anisotropy is not present at room temperature and at liquid nitrogen temperatures, but only at liquid helium temperatures and below. The anisotropy is accentuated by exposure to ultraviolet light, which disproportionately affects transport along one surface crystal direction. Furthermore, analysis of the low-temperature Hall coefficient and the capacitance as a function of back gate voltage indicates that in addition to electrons, holes contribute to the electrical transport.Comment: 11 pages, 9 figure

1-D Numerical Analysis of RBCC Engine Performance

An RBCC engine combines air breathing and rocket engines into a single engine to increase the specific impulse over an entire flight trajectory. Considerable research pertaining to RBCC propulsion was performed during the 1960's and these engines were revisited recently as a candidate propulsion system for either a single-stage-to-orbit (SSTO) or two-stage-to-orbit (TSTO) launch vehicle. There are a variety of RBCC configurations that had been evaluated and new designs are currently under development. However, the basic configuration of all RBCC systems is built around the ejector scramjet engine originally developed for the hypersonic airplane. In this configuration, a rocket engine plays as an ejector in the air-augmented initial acceleration mode, as a fuel injector in scramjet mode and the rocket in all rocket mode for orbital insertion. Computational fluid dynamics (CFD) is a useful tool for the analysis of complex transport processes in various components in RBCC propulsion systems. The objective of the present research was to develop a transient 1-D numerical model that could be used to predict flow behavior throughout a generic RBCC engine following a flight path

Ignition transient analysis of solid rocket motor

Measurement data on the performance of Space Shuttle Solid Rocket Motor show wide variations in the head-end pressure changes and the total thrust build-up during the ignition transient periods. To analyze the flow and thermal behavior in the tested solid rocket motors, a 1-dimensional, ideal gas flow model via the SIMPLE algorithm was developed. Numerical results showed that burning patterns in the star-shaped head-end segment of the propellant and the erosive burning rate are two important factors controlling the ignition transients. The objective of this study is to extend the model to include the effects of aluminum particle commonly used in solid propellants. To treat the effects of aluminum-oxide particles in the combustion gas, conservation of mass, momentum, and energy equations for the particles are added in the numerical formulation and integrated by an inter-phase-slip algorithm

Ignition transient analysis of solid rocket motor

To predict pressure-time and thrust-time behavior of solid rocket motors, a one-dimensional numerical model is developed. The ignition phase of solid rocket motors (time less than 0.4 sec) depends critically on complex interactions among many elements, such as rocket geometry, heat and mass transfer, flow development, and chemical reactions. The present model solves the mass, momentum, and energy equations governing the transfer processes in the rocket chamber as well as the attached converging-diverging nozzle. A qualitative agreement with the SRM test data in terms of head-end pressure gradient and the total thrust build-up is obtained. Numerical results show that the burning rate in the star-segmented head-end section and the erosive burning are two important parameters in the ignition transient of the solid rocket motor (SRM)

Searching for Dark Photons with Maverick Top Partners

In this paper, we present a model in which an up-type vector-like quark (VLQ) is charged under a new $U(1)_d$ gauge force which kinetically mixes with the SM hypercharge. The gauge boson of the $U(1)_d$ is the dark photon, $\gamma_d$. Traditional searches for VLQs rely on decays into Standard Model electroweak bosons $W,Z$ or Higgs. However, since no evidence for VLQs has been found at the Large Hadron Collider (LHC), it is imperative to search for other novel signatures of VLQs beyond their traditional decays. As we will show, if the dark photon is much less massive than the Standard Model electroweak sector, $M_{\gamma_d}\ll M_Z$, for the large majority of the allowed parameter space the VLQ predominately decays into the dark photon and the dark Higgs that breaks the $U(1)_d$ . That is, this VLQ is a `maverick top partner' with nontraditional decays. One of the appeals of this scenario is that pair production of the VLQ at the LHC occurs through the strong force and the rate is determined by the gauge structure. Hence, the production of the dark photon at the LHC only depends on the strong force and is largely independent of the small kinetic mixing with hypercharge. This scenario provides a robust framework to search for a light dark sector via searches for heavy colored particles at the LHC.Comment: 40 pages and 11 figure

Dreading and Ranting: The Distinct Effects of Anxiety and Anger in Online Seller Reviews

This paper explores effects of the emotions embedded in a seller review on its perceived helpfulness. Drawing on frameworks from the emotion and cognitive processing literatures, the authors propose that although emotional review content is subject to a well-known negativity bias, the effects of discrete emotions will vary, and that one source of this variance is perceptions of reviewers’ cognitive effort. We focused on the roles of two distinct, negative emotions common to seller reviews: anxiety and anger. In Study 1, actual seller reviews from Yahoo Shopping websites were collected to determine the effects of anxiety and anger on review helpfulness. In Study 2, an experiment was utilized to identify and explain the differential impact of anxiety and anger in terms of perceived reviewer effort. Our findings demonstrate the importance of examining discrete emotions in online word-of-mouth, and they also carry important practical implications for consumers and online retailers

Synthesis and characterisation of advanced ball-milled Al-Al2O3 nanocomposites for selective laser melting

Selective laser melting (SLM) offers significant potential for the manufacture of the advanced complex-shaped aluminium matrix composites (AMCs) used in the aerospace and automotive domains. Previous studies have indicated that advanced composite powders suitable for SLM include spherical powders with homogeneous reinforcement distribution, a particle size of < 100 μm and good flowability (Carr index < 15%); however, the production of such composite powders continues to be a challenge. Due to the intensive impacts of grinding balls, the high-energy ball-milling (HEBM) process has been employed to refine Al particles and disperse the nano Al2O3 reinforcements in the Al matrix to improve their mechanical properties. Notwithstanding, the specific characteristics of ball-milled powders for SLM and the effect of milling and pause duration on the fabrication of composite powders have not previously been investigated. The aim of this study was to synthesise Al-4 vol.% Al2O3 nano-composite powders using HEBM with two different types of milling and pause combinations. The characteristics of the powders subjected to up to 20 h of milling were investigated. The short milling (10 min) and long pause (15 min) combination provided a higher yield (66%) and narrower particle size distribution range than long milling (15 min) and a short pause (5 min). The nano Al2O3 reinforcements were observed to be dispersed uniformly after 20 h of milling, and the measured Carr index of 13.2% indicated that the ball-milled powder offered good flowability. Vickers micro-hardness tests indicated that HEBM significantly improved the mechanical properties of the ball-milled powders

Gender Differences in Collaborative Problem-Solving Skills in a Cross-Country Perspective

Effective collaborative problem solving comprises cognitive dimensions, in which men tend to outperform women, and social dimensions in which women tend to outperform men. We extend research on between-country differences in gender gaps by considering collaborative problem solving and its association with two indicators of societal-level gender inequality. The first indicator reflects women's underrepresentation in the labor market and politics. The second reflects women's underrepresentation in stereotypically masculine fields and men's underrepresentation in stereotypically feminine fields among university students. We use cross-country evidence on collaborative problem-solving skills among 15-year-old students from 44 countries (N = 343,326) who participated in the 2015 Programme for International Student Assessment (PISA). Girls outperform boys in collaborative problem solving in all countries. Gender gaps in collaborative problem solving in favor of girls are less pronounced in countries where women are especially underrepresented in the labor market and politics but more pronounced in countries where men and women are more likely to conform to gender stereotypes in selecting a field of study at university. Societal-level gender equality plays a bigger role in explaining between-country differences in achievement in domains with a gender gap in favor of girls—such as collaborative problem solving and, to a lesser extent, reading—and a smaller role in explaining between-country differences in achievement in domains with a gender gap in favor of boys—such as mathematics