Gas phase polymerization of ethylene with a silica-supported metallocene catalyst: influence of temperature on deactivation

Ethylene was polymerized at 5 bar in a stirred powder bed reactor with silica supported rac-Me2Si[Ind]2ZrCl2/methylaluminoxane (MAO) at temperatures between 40°C and 80°C using NaCl as support bed and triethylaluminium (TEA) as a scavenger for impurities. For this fixed recipe and a given charge of catalyst. the average catalyst activity is reproducible within 10% for low temperatures. The polymerization rate and the rate of deactivation increase with increasing temperature. The deactivation could be modeled using a first order dependence with respect to the polymerization rate

Canada's Strategy of Dispossession: Aboriginal Land and Rights Cessions in Comprehensive Land Claims

This paper offers a sociological interpretation of the Canadian Comprehensive Land Claims (CLC) process, arguing that CLC is a strategy used by the state to dispossess Aboriginal peoples. CLC does this through leveraging the cession of Aboriginal rights and the relinquishing of indigenous lands. Drawing upon the ongoing Innu Nation Tshash Petapen (?New Dawn?) agreement, I examine four related aspects of the process and the agreement which operate to dispossess the Innu: (1) the undemocratic social and political contexts in which agreement is elicited, (2) the depletion of Aboriginal rights of the indigenous party, (3) the depletion of indigenous lands, and (4) the creation of wealth and debt. Finally, I will interpret these processes as building on social changes inflicted on the Innu. These are characterized by imposed law and the state of exception

Apprendere una lingua straniera: tempo e spazio nella cultura italiana

La conoscenza di almeno una lingua straniera è uno degli obiettivi principali dei programmi culturali e scientifici dell’Unione europea che, all’incirca dalla metà degli anni 80, la riconosce come uno strumento qualificante al fine di costruire un’identità comune tra i paesi europei

The quiescent progenitors of four Type II-P/L supernovae

We present Large Binocular Telescope difference imaging data for the final years of four Type II-P/L supernovae progenitors. For all four, we find no significant evidence for stochastic or steady variability in the U, B, V, or R-bands. Our limits constrain variability to no more than roughly 5-10% of the expected R-band luminosities of the progenitors. These limits are comparable to the observed variability of red supergiants in the Magellanic Clouds. Based on these four events, the probability of a Type II-P/L progenitor having an extended outburst after Oxygen ignition is <37% at 90% confidence. Our observations cannot exclude short outbursts in which the progenitor returns to within ~10% of its quiescent flux on the time scale of months with no dust formation.Comment: 9 pages, 8 figures, 1 table. Accepted to MNRA

Total photoionization cross sections of atomic oxygen from threshold to 44.3A

The relative cross section of atomic oxygen for the production of singly charged ions has been remeasured in more detail and extended to cover the wavelength range 44.3 to 910.5 A by the use of synchrotron radiation. In addition, the contribution of multiple ionization to the cross sections has been measured allowing total photoionization cross sections to be obtained below 250 A. The results have been made absolute by normalization to previously measured data. The use of synchrotron radiation has enabled measurements of the continuum cross section to be made between the numerous autoionizing resonances that occur near the ionization thresholds. This in turn has allowed a more critical comparison of the various theoretical estimates of the cross section to be made. The series of autoionizing resonances leading to the 4-P state of the oxygen ion have been observed for the first time in an ionization type experiment and their positions compared with both theory and previous photographic recordings

Investigation on the influence of nematophagous fungi as feed additive on nematode infection risk of sheep and goats on pasture

Gastrointestinal nematodes in small ruminants cause high economic losses. Thus on most farms anthelmintic treatment is required. In response to increasing problems with anthelmintic resistance, biological control, for example the use of nematophagous fungi, has received significant attention. The aim of this study was to investigate the effect of Duddingtonia flagrans orally applied to small ruminants on natural infection with gastrointestinal nematodes in a field study in Northern Germany. 20 goats and 20 sheep were fed daily for 3 months with 5x105 spores of D. flagrans per kg bodyweight. Differences in body weight, faecal egg count and larval development in faeces and on pasture in comparison with same-sized control groups were analysed. After 3 months the control goats showed significantly higher mean faecal egg count than the fungus-fed group. No significant difference was found between the two sheep groups. The maximum in larval reduction in faeces was 81.3 % in the sheep groups and 67.9 % in the goat groups (not significant). At the end of the study the body weight gain in the fungus-treated groups was 1.7 kg higher in goats and 0.7 kg higher in sheep than in the control groups (not significant). Regarding the first-year-grazing goats only, the bodyweights revealed significant differences (p<0.05). No statistically significant differences were observed in pasture larval counts. In the study presented here, no clear effect of fungus could be observed. A modified feeding regimen, perhaps with permanent release boluses or feed blocks, may improve the efficacy. Furthermore, it seems that climatic conditions during the study period could have influenced the results and displayed how sensitive the fungus application may be on such parameters