578 research outputs found
Mujeres e ideas en América Latina : una relación problemática
Fil: Salomone, Alicia N.
Un Libro Quemado
Los escritos de Alfonsina Storni reunidos en este libro fueron publicados entre 1919 y 1921 en la revista La Nota y el diario La Nación. Sus títulos, como “¿Quién es el enemigo del divorcio?”, “Los defectos masculinos” o “¿Por qué las maestras se casan poco?”, dan cuenta de una mirada crítica e irreverente que desafió las costumbres y las normas de su época.
Usando como molde las típicas columnas femeninas que giran en torno al mundo doméstico, Storni dio un paso más allá e incorporó temas polémicos tales como la presencia de la mujer en el mercado de trabajo y su rol en la sociedad moderna. Su escritura visionaria y su lucidez crítica la ubican dentro de una contracorriente de voces como las de Virginia Woolf, Clarice Lispector y Silvina Ocampo.
A lo largo de toda su obra, Storni exploró distintos géneros, desdoblándose, recurriendo al humor y transgrediendo los estereotipos que pretendieron encasillarla. Rescatar sus escritos es traer a colación un pensamiento original que supo adelantarse a su tiempo y que continúa haciendo eco en la sociedad actual.https://scholarship.richmond.edu/bookshelf/1218/thumbnail.jp
Pd-catalyzed Reductions in Deep Eutectic Solvents by Using Aluminum and Water as Hydrogen Source
The reduction of organic functional groups, using metal-catalyzed hydrogenations, is one of the most
employed strategy in organic chemistry for the synthesis of both fine and bulk chemicals.[1]
Hydrogen is an explosive gas and its production needs extensive energy and generates a considerable
amount of carbon dioxide. Therefore, the development of cost-effective reduction methods that use
safe reagents, environmentally-friendly solvents and prevent or minimize waste formation represents
a challenge of great interest in sustainable chemistry. As part of our ongoing efforts in the discovery
of sustainable synthetic methodologies,[2] an alternative and safe palladium-catalyzed hydrogenation
reaction in Deep Eutectic Solvents (DESs) is here described.[3] The use of aluminum powder in
combination with water and a base in DESs, results in an environmentally-responsible system for the
controlled in-situ generation of hydrogen. Our optimized protocol is effective for the reduction of a
wide range of functional groups, containing C–C, C–N, C–O, N–O multiple bonds as well as for the
dearomatization of (hetero)aromatic compounds, and leads to the desired products in yield up-to 99%.
The simplicity, cost, tunability, scalability and the environmentally benign character of both catalytic
system and DESs, offer numerous advantages over the currently available methods that employ
external and dangerous H2 source and harsh, volatile organic solvents
Metabolism of a synthetic compared with a natural therapeutic pulmonary surfactant in adult mice
Secreted pulmonary surfactant phosphatidylcholine (PC) has a complex intra-alveolar metabolism that involves uptake and recycling by alveolar type II epithelial cells, catabolism by alveolar macrophages, and loss up the bronchial tree. We compared the in vivo metabolism of animal-derived poractant alfa (Curosurf) and a synthetic surfactant (CHF5633) in adult male C57BL/6 mice. The mice were dosed intranasally with either surfactant (80 mg/kg body weight) containing universally 13C-labeled dipalmitoyl PC (DPPC) as a tracer. The loss of [U13C]DPPC from bronchoalveolar lavage and lung parenchyma, together with the incorporation of 13C-hydrolysis fragments into new PC molecular species, was monitored by electrospray ionization tandem mass spectrometry. The catabolism of CHF5633 was considerably delayed compared with poractant alfa, the hydrolysis products of which were cleared more rapidly. There was no selective resynthesis of DPPC and, strikingly, acyl remodeling resulted in preferential synthesis of polyunsaturated PC species. In conclusion, both surfactants were metabolized by similar pathways, but the slower catabolism of CHF5633 resulted in longer residence time in the airways and enhanced recycling of its hydrolysis products into new PC species
Life cycle inventory data for the Italian agri-food sector: background, sources and methodological aspects
AbstractPurposeFor the development of any life cycle assessment study, the practitioner frequently integrates primary data collected on-field, with background data taken from various life cycle inventory databases which are part of most commercial LCA software packages. However, such data is often not generally applicable to all product systems since, especially concerning the agri-food sector, available datasets may not be fully representative of the site specificity of the food product under examination. In this context, the present work investigates the background, sources and methodological aspects that characterise the most known commercial databases containing agri-food data, with a focus on four agri-food supply chains (olive oil, wine, wheat products and citrus fruit), which represent an important asset for the Italian food sector.MethodsSpecifically, the paper entails a review of currently available LCI databases and their datasets with a twofold scope: firstly, to understand how agri-food data is modelled in these databases for a coherent and consistent representation of regional scenarios and to verify whether they are also suitable for the Italian context and, secondly, to identify and analyse useful and relevant methodological approaches implemented in the existing LCI databases when regional data are modelled.ResultsBased on the aforementioned review, it is possible to highlight some problems which may arise when developing an LCI pertaining to the four Italian agri-food supply chains, namely:1. The need for specific inventory datasets to tackle the specificities of agri-food product systems.2. The lack of datasets, within the existing DBs, related to the Italian context and to the abovementioned supply chains. In fact, at present, in the currently available LCI DBs, there are very few (or in some cases none) datasets related to Italian wine, olive oil, wheat-based products and citrus fruit. The few available datasets often contain some data related to the Italian context but also approximate data with that of product systems representing other countries.Furthermore, the present study allowed to identify and discuss the main aspects to be used as starting elements for modelling regional data to be included in a future Italian LCI database of the abovementioned four supply chains.ConclusionsThe results of the present study represent a starting point for the collection of data and its organisation, in order to develop an Italian LCI agri-food database with datasets which are representative of the regional specificities of four agri-food supply chains which play an important role in the Italian economy
Life cycle inventory data for the Italian agri-food sector: background, sources and methodological aspects
Purpose: For the development of any life cycle assessment study, the practitioner frequently integrates primary data collected on-field, with background data taken from various life cycle inventory databases which are part of most commercial LCA software packages. However, such data is often not generally applicable to all product systems since, especially concerning the agri-food sector, available datasets may not be fully representative of the site specificity of the food product under examination. In this context, the present work investigates the background, sources and methodological aspects that characterise the most known commercial databases containing agri-food data, with a focus on four agri-food supply chains (olive oil, wine, wheat products and citrus fruit), which represent an important asset for the Italian food sector. Methods: Specifically, the paper entails a review of currently available LCI databases and their datasets with a twofold scope: firstly, to understand how agri-food data is modelled in these databases for a coherent and consistent representation of regional scenarios and to verify whether they are also suitable for the Italian context and, secondly, to identify and analyse useful and relevant methodological approaches implemented in the existing LCI databases when regional data are modelled. Results: Based on the aforementioned review, it is possible to highlight some problems which may arise when developing an LCI pertaining to the four Italian agri-food supply chains, namely: 1. The need for specific inventory datasets to tackle the specificities of agri-food product systems. 2. The lack of datasets, within the existing DBs, related to the Italian context and to the abovementioned supply chains. In fact, at present, in the currently available LCI DBs, there are very few (or in some cases none) datasets related to Italian wine, olive oil, wheat-based products and citrus fruit. The few available datasets often contain some data related to the Italian context but also approximate data with that of product systems representing other countries. Furthermore, the present study allowed to identify and discuss the main aspects to be used as starting elements for modelling regional data to be included in a future Italian LCI database of the abovementioned four supply chains. Conclusions: The results of the present study represent a starting point for the collection of data and its organisation, in order to develop an Italian LCI agri-food database with datasets which are representative of the regional specificities of four agri-food supply chains which play an important role in the Italian economy
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