Spectral studies of some hydroxy-derivatives of anthraquinones

The u.v., visible, and i.r. spectra of several hydroxy-anthraquinones are discussed and the bands are assigned. These bands are compared with those of anthracene and anthraquinone. The band at 207 nm. is assigned to a n-sigma* transition; the bands at 252, 272, and 326 nm. are assigned by measuring spectra in solvents of various polarities. The stability constant for the 12-dihydroxyanthraquinone-ethanol complex is obtained

Onset of phase correlations in YBa2Cu3O{7-x} as determined from reversible magnetization measurements

Isofield magnetization curves are obtained and analyzed for three single crystals of YBa2Cu3O{7-x}, ranging from optimally doped to very underdoped, as well as the BCS superconductor Nb, in the presence of magnetic fields applied both parallel and perpendicular to the $ab$ planes. Near Tc, the magnetization exhibits a temperature dependence \sqrt{M} [Ta(H)-T]^m. In accordance with recent theories, we associated Ta(H) with the onset of coherent phase fluctuations of the superconducting order parameter. For Nb and optimally doped YBaCuO, Ta(H) is essentially identical to the mean-field transition line Tc(H). The fitting exponent m=0.5 takes its mean-field value for Nb, and varies just slightly from 0.5 for optimally doped YBaCuO. However, underdoped YBCO samples exhibit anomalous behavior, with Ta(H)>Tc for H applied parallel to the c axis, suggesting that the magnetization is probing a region of temperatures above Tc where phase correlations persist. In this region, the fitting exponent falls in the range 0.5 < m < 0.8 for H\parallel c, compared with m~0. for $H\parallel ab planes. The results are interpreted in terms of an anisotropic pairing symmetry of the order parameter: d-wave along the ab planes and s-wave along the c axis.Comment: 5 pages, 4 figure

Reliability analysis of a structural ceramic combustion chamber

The Weibull modulus, fracture toughness and thermal properties of a silicon nitride material used to make a gas turbine combustor were experimentally measured. The location and nature of failure origins resulting from bend tests were determined with fractographic analysis. The measured Weibull parameters were used along with thermal and stress analysis to determine failure probabilities of the combustor with the CARES design code. The effect of data censoring, FEM mesh refinement, and fracture criterion were considered in the analysis

Organized Current Patterns in Disordered Conductors

We present a general theory of current deviations in straight current carrying wires with random imperfections, which quantitatively explains the recent observations of organized patterns of magnetic field corrugations above micron-scale evaporated wires. These patterns originate from the most efficient electron scattering by Fourier components of the wire imperfections with wavefronts along the $\pm 45^{\circ}$ direction. We show that long range effects of surface or bulk corrugations are suppressed for narrow wires or wires having an electrically anisotropic resistivity

Experimental observation of high field diamagnetic fluctuations in Niobium

We have performed a magnetic study of a bulk metallic sample of Nb with critical temperature $T_{c}=8.5$ K. Magnetization versus temperature (M {\it vs} T) data obtained for fixed magnetic fields above 1 kOe show a superconducting transition which becomes broader as the field is increased. The data are interpreted in terms of the diamagnetic lowest Landau level (LLL) fluctuation theory. The scaling analysis gives values of the superconducting transition temperature $T_{c}(H)$ consistent with $H_{c2}(T)$% . We search for universal 3D LLL behavior by comparing scaling results for Nb and YBaCuO, but obtain no evidence for universality.Comment: 5 pages, 6 figures, Accepted for publication in Phys.Rev.

Vanishing of the upper critical field in Bi_2Sr_2CaCu_2O_{8+\delta} from Landau-Ott scaling

We apply Landau-Ott scaling to the reversible magnetization data of Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ published by Y. Wang et al. [\emph{Phys. Rev. Lett. \textbf{95} 247002 (2005)}] and find that the extrapolation of the Landau-Ott upper critical field line vanishes at a critical temperature parameter, T^*_c, a few degrees above the zero resistivity critical temperature, T_c. Only isothermal curves below and near to T_c were used to determine this transition temperature. This temperature is associated to the disappearance of the mixed state instead of a complete suppression of superconductivity in the sample.Comment: 3 figure

Preparation of Waste Paper Fibrous Cement and Studying of Some Physical Properties

Waste paper is available in environment from different sources, such as office, newspaper and markets. Waste papers are the abundant source of cellulose and may be used as landfill. Using of these wastes in building materials has two benefits, the first one has reduced the environmental pollution and the second improves the physical properties of concrete and building bricks (or blocks). Addition of waste paper cellulose to concrete at certain percentage improve its thermal insulation properties and affect its density to produce lightweight and insulating building materials. The material which produces by using waste paper is called papercrete. It is a mixture of waste paper pulp, sand, cement and water by replacing the cement by waste paper pulp at a certain percentage. Also fibrous cement could be produced by mixing of waste paper pulp with cement and water. In the current work the waste paper was processed to obtain the raw materials of papercrete and fibrous cement. The processing method includes a sequence of processes which are shredding, soaking, mixing, dewatering and drying. In the dewatering process, a wet pulp was obtained and it can be used as it is in the mixtures of papercrete or fibrous cement. A dry pulp also could be used. It is observed that one kilogram of office paper and that of newspaper produces 3.24 kg and 3.26 kg of wet paper pulp respectively. The dry pulp, which is produced during the drying process is 0.954 kg and 0.949 kg for 1 kg of office paper and newspaper respectively. Design of mix proportion, test of water absorption, apparent porosity and drying curve of samples with different percentage of paper pulp were investigated in the present work. Keywords: wastepaper, papercrete, fibrous cement, porosity, water absorption, bulk densit

Polarographic Studies on Complexes of Pd(II) & Co(II) with Triethanolamine

721-72

The CMB and the measure of the multiverse

In the context of eternal inflation, cosmological predictions depend on the choice of measure to regulate the diverging spacetime volume. The spectrum of inflationary perturbations is no exception, as we demonstrate by comparing the predictions of the fat geodesic and causal patch measures. To highlight the effect of the measure---as opposed to any effects related to a possible landscape of vacua---we take the cosmological model, including the model of inflation, to be fixed. We also condition on the average CMB temperature accompanying the measurement. Both measures predict a 1-point expectation value for the gauge-invariant Newtonian potential, which takes the form of a (scale-dependent) monopole, in addition to a related contribution to the 3-point correlation function, with the detailed form of these quantities differing between the measures. However, for both measures both effects are well within cosmic variance. Our results make clear the theoretical relevance of the measure, and at the same time validate the standard inflationary predictions in the context of eternal inflation.Comment: 28 pages; v2: reference added, some clarification