4 research outputs found
On microdosimetry of neutrons of selectable energy in mixed (n,y) fields
Biological damage of tissue due to intermediate energy neutrons is generally known to be very important in radiobiology and radiation protection. However, there is no suitable method to determine the quality of these neutrons in particular in the working environment of mixed (n,y) radiation fields. In this thesis, an attempt is made to develop a dosimeter based on microdosimetric principles which has the capability for such a purpose. With this
object the basic concepts of microdosimetry are reviewed and discussed with emphasis on their application for radiation protection and in designing of the dosimeter.
Microdosimetry based on low pressure tissue-equivalent proportional counters
(TEPCs) is a powerful technique for determining microscopic distributions of energy
deposition and quality of ionizing radiations. However the energy deposition spectra of
intermediate energy neutrons in mixed fields of fast neutrons can only be measured using
TEPC in co-axial double cylindrical form by an appropriate choice for the thickness of the
common tissue-equivalent (TE) dividing wall separating the inner and outer counters and by
appropriate use of coincidence/anti-coincidence pulse arrangements. An analytical calculation
for the response of the inner counter operating in coincidence/anti-coincidence modes with
the outer counter was developed. However there will be some events, due to fast neutrons,
which will contribute to the signals from intermediate energy neutrons and which cannot be
removed by anti-coincidence. For these analytical corrections must be made. Also, the
events associated with the dividing wall inherent in the system can contribute to the response
of the inner counter and must be corrected by calculation. The calculation was possible due
to the fact that recoil particles from intermediate energy neutron interactions have effective
stopping powers and projected ranges which differ significantly from the continuous
slowing down approximation (CSDA) values. By incorporating these the basic CSDA
formulae for energy deposition spectra of neutrons could be extended down to intermediate
energy neutrons of about 1 keV.
A prototype co-axial double cylindrical TEPC capable of separating the component of
neutrons (≤ 850 keV) in mixed (n,y) radiation fields was manufactured and tested. The thin
wall dividing the inner and outer counters was fabricated from the standard A-150 TE plastic
with the thickness equivalent to the range of 850 keV protons. The operational characteristics
of the dosimeter were studied to determine its applicability for use in microdosimetry. The gas gain of the inner and outer TEPCs was measured at various simulated mean chord
lengths and applied voltages. The results can be expressed according to Campion's equation
within a given range of the electric field strength. The resolution of the inner TEPC
measured at the operating voltages is in agreement with the theoretical prediction.
A series of microdosimetric experiments were performed with mixed fields of 60Co
gamma-rays and neutrons from the UTR-300 nuclear reactor and from 252Cf and
241Am-Be
radioactive sources. Discrimination against fast neutrons of energy > 850 keV was achieved
using an anti-coincidence unit specially designed for better efficiency of data acquisition.
Discrimination against fast electrons due to photon interactions was also achieved. Spectra
with anti-coincidence are dominated by slow protons and electrons. Their mean lineal
energies are higher than those of spectra without anti-coincidence. The quality factor and
dose equivalent for spectra with anti-coincidence are higher than the spectra without anticoincidence
indicating the importance of intermediate energy neutrons in mixed fields. The
quality factor and the corresponding dose equivalent corrected for saturation of lineal energy
corresponding to 2 nm of ionization spacing is consistently higher than those derived from
the absorbed dose based formulae, the biophysical implications of which are discussed.
Suggestion for future developments for microdosimetry of intermediate energy neutrons in mixed fields are made and discussed
Preparation and characterization of ultrafine nanoparticles of Cu doped lithium tetraborate
This study details an innovative single-step thermal synthesis of nano-sized lithium tetraborate doped with 0.1 %wt copper and its characterization. The heating temperature for the synthesis of the nanoparticle material was optimized by variation between 200 and 850 °C. The optimum amount of polyvinyl pyrrolidone (PVP) the capping agent was determined to be 0.027 mol per 1 g LTB-Cu. The calcination time was 2 h. Characterization of the samples was carried out using Thermogravimetry Analysis (TGA), Derivative Thermogravimetry (DTG), Differential Scanning Calorimetry (DSC), Fourier Transform Infrared (FTIR) Spectroscopy, X-ray diffractometer (XRD), transmission electron microscopy (TEM) and Ultraviolet–Visible (UV–Vis) spectroscopy. The product was thermally stable above 450 °C. FTIR, XRD and TEM results confirmed the formation of pure nano-crystalline copper doped lithium tetraborate between 450 and 750 °C. The optical bandgap was estimated to be 5.02–6.05 eV in the presence of different amounts of PVP at various calcination temperatures
Formation and characterization of ultrafine nanophosphors of lithium tetraborate (Li2B4O7) for personnel and medical dosimetry
The present study demonstrates an innovative single-step thermal synthesis of nano-sized lithium tetraborate dosimeter and its characterization. The optimum calcination temperature and time for the synthesis of the nanoparticles material was 750 °C and 2 h, respectively. Characterization of the samples was carried out using X-ray diffractometry (XRD), Fourier transform infrared (FT-IR) spectroscopy, transmission electron microscopy (TEM), and thermoluminescence (TL). FT-IR, XRD and TEM results confirmed the formation of pure nano-crystalline lithium tetraborate. The product showed a linear response over a wide range of doses from 10−1 to 1.5 × 102 Gy. Moreover, the samples illustrate non-energy dependence among a wide range energy interval from 24 keV up to 1250 keV and almost no fading during one month storage
Determination of heavy metal pollution in depth profile of marine sediment samples from the Strait of Malacca
In this study, four core marine sediment samples from
the Strait of Malacca were collected and analyzed by using
instrumental neutron activation analysis (INAA). This work
was carried out to evaluate the level of heavy metal pollution
in the water-body. In addition, inductively coupled
plasma-mass spectroscopy (ICP-MS) technique was used
for non-measurable elements by INAA. The following
heavy metals (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Sb and Zn)
have been determined in the core sediment samples collected
from the Strait of Malacca. Moreover, the obtained
results were compared to the national studies and the international
guidelines for marine sediments